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Electronic structure of intermetallic B32 type Zintl phases

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Solid State Chemistry

Part of the book series: Structure and Bonding ((STRUCTURE,volume 65))

Abstract

The electronic properties of binary and ternary intermetallic Zintl phases crystallizing in the NaTl type of structure are investigated and reported. The crystal and defect structure, the electronic band structure and density of states, the bonding mechanisms and the charge transfer are discussed. Comparison is made between the electronic states in the B2 and the B32 types of structure. Furthermore, based upon theoretical studies of the electronic valence states the optical properties (imaginary part of the dielectric constant and reflectivity) and the magnetic properties (susceptibility and Knight shift) are considered.

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  1. Institut für Physikalische Chemie, Physikalische Chemie III, Technische Hochschule Darmstadt, Petersenstr. 20, D-6100, Darmstadt, Federal Republic of Germany

    Peter C. Schmidt

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© 1987 Springer-Verlag

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Schmidt, P.C. (1987). Electronic structure of intermetallic B32 type Zintl phases. In: Solid State Chemistry. Structure and Bonding, vol 65. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0004459

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  • DOI: https://doi.org/10.1007/BFb0004459

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  • Print ISBN: 978-3-540-17581-0

  • Online ISBN: 978-3-540-47464-7

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