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Electronic structure of intermetallic B32 type Zintl phases

  • Peter C. Schmidt
Conference paper
Part of the Structure and Bonding book series (STRUCTURE, volume 65)

Abstract

The electronic properties of binary and ternary intermetallic Zintl phases crystallizing in the NaTl type of structure are investigated and reported. The crystal and defect structure, the electronic band structure and density of states, the bonding mechanisms and the charge transfer are discussed. Comparison is made between the electronic states in the B2 and the B32 types of structure. Furthermore, based upon theoretical studies of the electronic valence states the optical properties (imaginary part of the dielectric constant and reflectivity) and the magnetic properties (susceptibility and Knight shift) are considered.

Keywords

Band Structure Fermi Surface Valence Electron Knight Shift Atomic Sphere 
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Copyright information

© Springer-Verlag 1987

Authors and Affiliations

  • Peter C. Schmidt
    • 1
  1. 1.Institut für Physikalische Chemie, Physikalische Chemie IIITechnische Hochschule DarmstadtDarmstadtFederal Republic of Germany

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