Abstract
The performance of energy storage devices and sensors is predominantly influenced by the microstructure and composition of the electrode materials. The two-dimensional (2D) structure of graphene has attracted significant attention in the research of supercapacitors and wearable sensors due to its remarkable electrical conductivity, mechanical properties, and large surface area surpassing that of carbon nanotubes. The inherent porous structure of graphene provides ample space for the storage and transportation of electrolyte ions, enabling fast charge/discharge kinetics. The human body is a complex system abundant with sensory organs such as fingers, nose, mouth, and more. Numerous physiological signals are continuously generated, which can reflect the body's condition. However, the interface between commercial rigid sensors and the skin is often inadequate, resulting in suboptimal signal quality. In this chapter, our objective is to review the recent advancements in graphene research and development for the applications of supercapacitors and wearable sensors. We will provide an overview of various synthesis strategies for graphene and explore their potential utilization in both asymmetric/symmetric supercapacitors and wearable sensors.
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References
Ameri SK, Wang L (2020) Graphene electronic tattoo sensors for point-of-care personal health monitoring and human–machine interfaces In: Emerging 2D materials and devices for the internet of things. Elsevier, pp 59–86
Annett J, Cross GL (2016) Self-assembly of graphene ribbons by spontaneous self-tearing and peeling from a substrate. Nature 535(7611):271–275
Bepete G, Anglaret E, Ortolani L, Morandi V, Huang K, Pénicaud A et al (2017) Surfactant-free single-layer graphene in water. Nat Chem 9(4):347–352
Biswas S, Drzal LT (2010) Multilayered nanoarchitecture of graphene nanosheets and polypyrrole nanowires for high performance supercapacitor electrodes. Chem Mater 22(20):5667–5671
Bose S, Kim NH, Kuila T, Lau K-T, Lee JH (2011) Electrochemical performance of a graphene–polypyrrole nanocomposite as a supercapacitor electrode. Nanotechnology 22(29):295202
Brodie BC (1860) Sur le poids atomique du graphite. Ann Chim Phys 59(466):e472
Chen J-H, Jang C, Xiao S, Ishigami M, Fuhrer MS (2008) Intrinsic and extrinsic performance limits of graphene devices on SiO 2. Nat Nanotechnol 3(4):206–209
Chen W, Yan L, Bangal PR (2010) Preparation of graphene by the rapid and mild thermal reduction of graphene oxide induced by microwaves. Carbon 48(4):1146–1152
Cheng Q, Tang J, Ma J, Zhang H, Shinya N, Qin L-C (2011) Graphene and carbon nanotube composite electrodes for supercapacitors with ultra-high energy density. Phys Chem Chem Phys 13(39):17615–17624
Edwards RS, Coleman KS (2013) Graphene synthesis: relationship to applications. Nanoscale 5(1):38–51
El-Kady MF, Strong V, Dubin S, Kaner RB (2012) Laser scribing of high-performance and flexible graphene-based electrochemical capacitors. Science 335(6074):1326–1330
Golparvar AJ, Yapici MK (2018) Electrooculography by wearable graphene textiles. IEEE Sens J 18(21):8971–8978
Hernandez Y, Nicolosi V, Lotya M, Blighe FM, Sun Z, De S et al (2008) High-yield production of graphene by liquid-phase exfoliation of graphite. Nat Nanotechnol 3(9):563–568
Hsu H-C, Wang C-H, Nataraj S, Huang H-C, Du H-Y, Chang S-T et al (2012) Stand-up structure of graphene-like carbon nanowalls on CNT directly grown on polyacrylonitrile-based carbon fiber paper as supercapacitor. Diam Relat Mater 25:176–179
Hummers WS Jr, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80(6):1339–1339
Kim SJ, Cho KW, Cho HR, Wang L, Park SY, Lee SE et al (2016) Stretchable and transparent biointerface using cell-sheet–graphene hybrid for electrophysiology and therapy of skeletal muscle. Adv Func Mater 26(19):3207–3217
Kuzmenko AB, Van Heumen E, Carbone F, Van Der Marel D (2008) Universal optical conductance of graphite. Phys Rev Lett 100(11):117401
Le LT, Ervin MH, Qiu H, Fuchs BE, Lee WY (2011) Graphene supercapacitor electrodes fabricated by inkjet printing and thermal reduction of graphene oxide. Electrochem Commun 13(4):355–358
Lee H, Choi TK, Lee YB, Cho HR, Ghaffari R, Wang L et al (2016) A graphene-based electrochemical device with thermoresponsive microneedles for diabetes monitoring and therapy. Nat Nanotechnol 11(6):566–572
Li Z, Xu Z, Liu Y, Wang R, Gao C (2016) Multifunctional non-woven fabrics of interfused graphene fibres. Nat Commun 7(1):1–11
Liang Y, Xu C, Liu F, Du S, Li G, Wang X (2019) Eliminating heat injury of zeolite in hemostasis via thermal conductivity of graphene sponge. ACS Appl Mater Interfaces 11(27):23848–23857
Lin S-Y, Zhang T-Y, Lu Q, Wang D-Y, Yang Y, Wu X-M et al (2017) High-performance graphene-based flexible heater for wearable applications. RSC Adv 7(43):27001–27006
Liu Q, Tai H, Yuan Z, Zhou Y, Su Y, Jiang Y (2019) A high-performances flexible temperature sensor composed of polyethyleneimine/reduced graphene oxide bilayer for real-time monitoring. Adv Mater Technol 4(3):1800594
Liu Y, Deng R, Wang Z, Liu H (2012) Carboxyl-functionalized graphene oxide–polyaniline composite as a promising supercapacitor material. J Mater Chem 22(27):13619–13624
Lotya M, Hernandez Y, King PJ, Smith RJ, Nicolosi V, Karlsson LS et al (2009) Liquid phase production of graphene by exfoliation of graphite in surfactant/water solutions. J Am Chem Soc 131(10):3611–3620
Marsh H, Reinoso FR (2006) Activated carbon. Elsevier
Nakajima T, Matsuo Y (1994) Formation process and structure of graphite oxide. Carbon 32(3):469–475
Novoselov KS, Geim AK, Morozov SV, Jiang D, Zhang, Y., Dubonos SV et al (2004) Electric field effect in atomically thin carbon films.Science 306(5696):666–669
Park J, Kim M, Lee Y, Lee HS, Ko H (2015) Fingertip skin–inspired microstructured ferroelectric skins discriminate static/dynamic pressure and temperature stimuli. Sci Adv 1(9):e1500661
Park S, Ruoff RS (2009) Chemical methods for the production of graphenes. Nat Nanotechnol 4(4):217–224
Qiao Y, Wang Y, Tian H, Li M, Jian J, Wei Y et al (2018) Multilayer graphene epidermal electronic skin. ACS Nano 12(9):8839–8846
Ramaprabhu S (2012) Poly (p-phenylenediamine)/graphene nanocomposites for supercapacitor applications. J Mater Chem 22(36):18775–18783
Ren X, Pei K, Peng B, Zhang Z, Wang Z, Wang X et al (2016) A low-operating-power and flexible active-matrix organic-transistor temperature-sensor array. Adv Mater 28(24):4832–4838
Seredych M, Koscinski M, Sliwinska-Bartkowiak M, Bandosz TJ (2012) Active pore space utilization in nanoporous carbon-based supercapacitors: effects of conductivity and pore accessibility. J Power Sources 220:243–252
Sha J, Li Y, Villegas Salvatierra R, Wang T, Dong P, Ji Y et al (2017) Three-dimensional printed graphene foams. ACS Nano 11(7):6860–6867
Shi J, Li X, Cheng H, Liu Z, Zhao L, Yang T et al (2016) Graphene reinforced carbon nanotube networks for wearable strain sensors. Adv Func Mater 26(13):2078–2084
Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhammes A, Jia Y et al (2007) Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon 45(7):1558–1565
Staudenmaier L (1898) Verfahren zur darstellung der graphitsäure. Ber Dtsch Chem Ges 31(2):1481–1487
Sun B, McCay RN, Goswami S, Xu Y, Zhang C, Ling Y et al (2018) Gas-permeable, multifunctional on-skin electronics based on laser-induced porous graphene and sugar-templated elastomer sponges. Adv Mater 30(50):1804327
Tan YB, Lee J-M (2013) Graphene for supercapacitor applications. J Mater Chem A 1(47):14814–14843
Tao L-Q, Sun H, Liu Y, Ju Z-Y, Yang Y, Ren T-L (2017a) Flexible graphene sound device based on laser reduced graphene. Appl Phys Lett 111(10):103104
Tao L-Q, Wang D-Y, Tian H, Ju Z-Y, Liu Y, Pang Y et al (2017b) Self-adapted and tunable graphene strain sensors for detecting both subtle and large human motions. Nanoscale 9(24):8266–8273
Tao L-Q, Zhang K-N, Tian H, Liu Y, Wang D-Y, Chen Y-Q et al (2017c) Graphene-paper pressure sensor for detecting human motions. ACS Nano 11(9):8790–8795
Titirici M-M, White RJ, Brun N, Budarin VL, Su DS, Del Monte F et al (2015) Sustainable carbon materials. Chem Soc Rev 44(1):250–290
Trung TQ, Le HS, Dang TML, Ju S, Park SY, Lee NE (2018) Freestanding, fiber-based, wearable temperature sensor with tunable thermal index for healthcare monitoring. Adv Healthc Mater 7(12):1800074
Trung TQ, Ramasundaram S, Hwang BU, Lee NE (2016) An all-elastomeric transparent and stretchable temperature sensor for body-attachable wearable electronics. Adv Mater 28(3):502–509
Vecera P, Holzwarth J, Edelthalhammer KF, Mundloch U, Peterlik H, Hauke F et al (2016) Solvent-driven electron trapping and mass transport in reduced graphites to access perfect graphene. Nat Commun 7(1):1–7
Wang Y, Wang L, Yang T, Li X, Zang X, Zhu M et al (2014) Wearable and highly sensitive graphene strain sensors for human motion monitoring. Adv Func Mater 24(29):4666–4670
Wei Y, Qiao Y, Jiang G, Wang Y, Wang F, Li M et al (2019) A wearable skinlike ultra-sensitive artificial graphene throat. ACS Nano 13(8):8639–8647
Xiao-Ya Y (2011) Progress in preparation of graphene. J Inorg Mater 26(6):561–570
Xie X, Chen M, Liu P (2017) High hydrogen desorption properties of Mg-based nanocomposite at moderate temperatures: the effects of multiple catalysts in situ formed by adding nickel sulfides/graphene. J Power Sources 371:112–118
Xu J, Hu J, Li Q, Wang R, Li W, Guo Y et al (2017) Fast batch production of high‐quality graphene films in a sealed thermal molecular movement system. Small 13(27):1700651
Xu X, Zhang Z, Qiu L, Zhuang J, Zhang L, Wang H et al (2016) Ultrafast growth of single-crystal graphene assisted by a continuous oxygen supply. Nat Nanotechnol 11(11):930–935
Yan J, Fan Z, Sun W, Ning G, Wei T, Zhang Q et al (2012) Advanced asymmetric supercapacitors based on Ni (OH) 2/graphene and porous graphene electrodes with high energy density. Adv Func Mater 22(12):2632–2641
Yang D, Velamakanni A, Bozoklu G, Park S, Stoller M, Piner RD et al (2009) Chemical analysis of graphene oxide films after heat and chemical treatments by X-ray photoelectron and Micro-Raman spectroscopy. Carbon 47(1):145–152
Yang Z, Pang Y, Han X, Yang Y, Ling J, Jian M et al (2018) Graphene textile strain sensor with negative resistance variation for human motion detection. ACS Nano 12(9):9134–9141
Yapici MK, Alkhidir T, Samad YA, Liao K (2015) Graphene-clad textile electrodes for electrocardiogram monitoring. Sens Actuators B Chem 221:1469–1474
Yong K, Ashraf A, Kang P, Nam S (2016) Rapid stencil mask fabrication enabled one-step polymer-free graphene patterning and direct transfer for flexible graphene devices. Sci Rep 6(1):1–8
Yun YJ, Ju J, Lee JH, Moon SH, Park SJ, Kim YH et al (2017) Highly elastic graphene-based electronics toward electronic skin. Adv Func Mater 27(33):1701513
Zhao H, Lin Y-C, Yeh C-H, Tian H, Chen Y-C, Xie D et al (2014) Growth and Raman spectra of single-crystal trilayer graphene with different stacking orientations. ACS Nano 8(10):10766–10773
Zheng G, Chen Y, Huang H, Zhao C, Lu S, Chen S et al (2013) Improved transfer quality of CVD-grown graphene by ultrasonic processing of target substrates: applications for ultra-fast laser photonics. ACS Appl Mater Interfaces 5(20):10288–10293
Zhou W, Liu J, Chen T, Tan KS, Jia X, Luo Z et al (2011) Fabrication of Co 3 O 4-reduced graphene oxide scrolls for high-performance supercapacitor electrodes. Phys Chem Chem Phys 13(32):14462–14465
Acknowledgements
This work was supported by the project “Graphene / graphite-filled carbon fiber-reinforced composite designed especially for battery protection boxes in electric cars” (Reg. No. TM03000010), Technology Agency of Czech Republic (TAČR).
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Peng, Q., Tan, X., Venkataraman, M., Militký, J. (2023). Application of Graphene in Supercapacitor and Wearable Sensor. In: Militký, J., Venkataraman, M. (eds) Advanced Multifunctional Materials from Fibrous Structures. Advanced Structured Materials, vol 201. Springer, Singapore. https://doi.org/10.1007/978-981-99-6002-6_3
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