Abstract
Lubricating machines with mineral-based lubricants have become a major cause of pollution now. To use natural oils for making lubricants instead of petroleum is something mainstream researchers have been looking at for a few decades. Though vegetable oils show excellent biodegradability, their cold flow properties are poor compared to functional lubricants. Biodegradable lubricant oils must have excellent cold flow properties as well as competitive costs in order to be accepted widely as usable base stock to industrially usable lubricants. Cold flow characteristics of natural oils are generally subpar to industrial lubricants. This is one major drawback that limits the usage of otherwise abundant vegetable oil. Though vegetable oils show excellent biodegradability, their cold flow properties are poor compared to functional lubricants. In this present study, three vegetable oils have been synthesized to obtain their estolides, they are coconut, sunflower and karanja oils, to analyze the variations. SPARTAN molecular dynamics software is utilized in parallel to understand the molecular structure of products.
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References
Cermak SC, Bredsguard JW, Dunn RO, Thompson T, Feken KA, Roth KL, Kenar JA, Isbell TA, Murray RE (2014) Comparative Assay of Antioxidant Packages for Dimer of Estolide Esters. J Am Oil Chem Soc
Ho CK, McAuley KB, Peppley BA (2019) Biolubricants through renewable hydrocarbons: a perspective for new opportunities. Renew Sustain Energy Rev
Bin X, Ding R, Yang Z, Sun Y, Zhang J, Kaiji L, Cao D, Gao A (2023) Investigation on performance of mineral-oil-based rejuvenating agent for aged high viscosity modified asphalt of porous asphalt pavement. J Clean Prod 395:136285
Garcia-Zapateiro LA, Franco JM, Valencia C, Delgado MA, Gallegos C (2013) Viscous, thermal and tribological characterization of oleic and ricinoleic acids-derived estolides and their blends with vegetable oils. J Indus Eng Chem
Cermak SC (2001) Synthesis of estolides from oleic and saturated fatty acids. J Am Oil Chem Soc 06
Ajithkumar G (2009) Analysis of the pour point of coconut oil as a lubricant base stock using differential scanning calorimetry. Lubric Sci 01
Greco-Duarte J, Collaço ACA, Costa AMM, Silva LO, Da Silva JAC, Torres AG, Fernandez-Lafuente R, Freire DMG (2019) Understanding the degree of estolide enzymatic polymerization and the effects on its lubricant properties. Fuel
Isbell TA, Edgcomb MR, Lowery BA (2001) Physical properties of estolides and their ester derivatives. Indus Crops Prod
Ray AK, Stark RE (1998) Isolation and molecular structure of an oligomer produced enzymatically from the cuticle of lime fruit. Phytochemistry 48(8):1313–1320
Perera M, Yan J, Xu L, Yang M, Yan Y (2022) Bioprocess development for biolubricant production using non-edible oils, agro-industrial byproducts and wastes. J Clean Prod 357:131956
Åkermana CO, Gaber Y, Abd Ghani N, Lämsä M, Hatti-Kaul R (2011) Clean synthesis of biolubricants for low temperature applications using heterogeneous catalysts. J Mol Catal B Enzym 72:263–269
Bantchev GB, Cermak SC (2022) Correlating viscosity of 2-ethylhexyl oleic estolide esters to their molecular weight. Fuel 309:122190
de Haro JC, del Prado Garrido M, Perez A, Carmona M, RodrÃguez JF (2018) Full conversion of oleic acid to estolides esters, biodiesel and choline carboxylates in three easy steps. J Clean Prod 184:579–585
Smith PC, Ngothai Y, Nguyen QD, O’Neill BK (2010) Improving the low-temperature properties of biodiesel: methods and consequences. Renew Energy 35:1145–1151
Sierra-Cantora JF, Guerrero-Fajardo CA (2017) Methods for improving the cold flow properties of biodiesel with high saturated fatty acids content: a review. Renew Sustain Energy Rev 72:774–790
Zhang C, Garrison TF, Madbouly SA, Kessler MR (2017) Recent advances in vegetable oil-based polymers and their composites. Prog Polym Sci 71:91–143
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Maneesh Kumar, P.V., Jagadeesha, T. (2023). Synthesis of Estolides from Coconut, Sunflower and Karanja Oils. In: Bindhu, V., Tavares, J.M.R.S., Talu, S. (eds) Proceedings of Sixth International Conference on Inventive Material Science Applications. ICIMA 2023. Advances in Sustainability Science and Technology. Springer, Singapore. https://doi.org/10.1007/978-981-99-4189-6_5
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DOI: https://doi.org/10.1007/978-981-99-4189-6_5
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