Skip to main content
SpringerLink
Log in

Nanoscopic Pd(II)-Based Complexes with Poly-Ether Functionalized Ligand: The Crown Ether Analog

  • Conference paper
  • First Online:
Advanced Nanomaterials and Their Applications (ICANA 2022)

Part of the book series: Springer Proceedings in Materials ((SPM,volume 22))

  • 121 Accesses

  • The original version of this chapter has been revised: The affiliation of the authors “Srabani Srotwosini Mishra and Dillip Kumar Chand” has been updated. The correction to this chapter is available at https://doi.org/10.1007/978-981-99-1616-0_22

Abstract

Mononuclear cis-protected Pd(II) complexes 1–4 with general formula [Pd(N-N)L](NO3)2 ((N-N) is cis-protecting units such as en, tmeda, bpy, and phen) were synthesized by combining pyridine appended poly-ether functionalized ligand (1,11-bis(4-pyridylcarboxy)-3,6,9-trioxaundecane) L with suitable palladium(II) components. These assemblies were characterized by NMR and ESI-MS. DFT calculation was undertaken to establish structure of these complexes. A clear concentration-dependent dynamic equilibrium in the solution state was observed. The existence of dynamic equilibrium was supplemented by variable concentration 1H NMR study. DNA binding potential of these complexes was studied using molecular docking tool.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 189.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 249.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Free shipping worldwide - see info
Hardcover Book
USD 249.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Supplementary Data

Supplementary data (NMR and ESI MS) associated with this article can be found, in the online version.

Change history

  • 17 August 2023

    A correction has been published.

References

  1. Pullen S, Tessarolo J, Clever GH (2021) Increasing structural and functional complexity in self-assembled coordination cages. Chem Sci 12:7269–7293

    Article  CAS  Google Scholar 

  2. Debata NB, Tripathy D, Sahoo HS (2019) Development of coordination driven self-assembled discrete spherical ensembles. Coord Chem Rev 387:273–298

    Article  CAS  Google Scholar 

  3. Roberts DA, Pilgrim BS, Nitschke JR (2018) Covalent post-assembly modification in metallosupramolecular chemistry. Chem Soc Rev 47:626–644

    Article  CAS  Google Scholar 

  4. Pullen S, Clever GH (2018) Mixed-ligand metal-organic frameworks and heteroleptic coordination cages as multifunctional scaffolds—a comparison. Acc Chem Res 51:3052–3064

    Article  CAS  Google Scholar 

  5. Lewis JEM, Beer PD, Loeb SJ, Goldup SM (2017) Metal ions in the synthesis of interlocked molecules and materials. Chem Soc Rev 46:2577–2591

    Article  CAS  Google Scholar 

  6. Chen L-J, Yang H-B, Shionoya M (2017) Chiral metallosupramolecular architectures. Chem Soc Rev 46:2555–2576

    Article  CAS  Google Scholar 

  7. He Z, Jiang W, Schalley CA (2015) Integrative self-sorting: a versatile strategy for the construction of complex supramolecular architecture. Chem Soc Rev 44:779–789

    Article  CAS  Google Scholar 

  8. Yoshizawa M, Klosterman JK (2014) Molecular architectures of multi-anthracene assemblies. Chem Soc Rev 43:1885–1898

    Article  CAS  Google Scholar 

  9. Percástegui EG, Ronson TK, Nitschke JR (2020) Design and applications of water-soluble coordination cages. Chem Rev 120:13480–13544

    Article  Google Scholar 

  10. Fang Y, Powell JA, Li E, Wang Q, Perry Z, Kirchon A, Yang X, Xiao Z, Zhu C, Zhang L, Huang F, Zhou HC (2019) Catalytic reactions within the cavity of coordination cages. Chem Soc Rev 48:4707–4730

    Article  CAS  Google Scholar 

  11. Zhang D, Ronson TK, Nitschke JR (2018) Functional capsules via subcomponent self-assembly. Acc Chem Res 51:2423–2436

    Article  CAS  Google Scholar 

  12. Wang W, Wanga YX, Yang HB (2016) Supramolecular transformations within discrete coordination-driven supramolecular architectures. Chem Soc Rev 45:2656–2693

    Article  CAS  Google Scholar 

  13. Galan A, Ballester P (2016) Stabilization of reactive species by supramolecular encapsulation. Chem Soc Rev 45:1720–1737

    Article  CAS  Google Scholar 

  14. Ahmad N, Younus HA, Chughtai AH, Verpoort F (2015) Metal–organic molecular cages: applications of biochemical implications. Chem Soc Rev 44:9–25

    Article  CAS  Google Scholar 

  15. Debata NB, Tripathy D, Chand DK (2012) Self-assembled coordination complexes from various palladium(II) components and bidentate or polydentate ligands. Coord Chem Rev 256:1831–1945

    Article  CAS  Google Scholar 

  16. Tripathy D, Debata NB, Naik KC, Sahoo HS (2022) Coordination driven discrete metallopolygons and cages from unsymmetric bidentate ligands. Coord Chem Rev 456:214396

    Article  CAS  Google Scholar 

  17. Dürr H, Kilburg H, Bossmann S (1990) Efficient synthesis of crown ester-linked ruthenium complexes. A new class of a supramolecular sensitizer-crown ester assembly for electron transfer. Synthesis 773–778

    Google Scholar 

  18. Ramakrishna B, Ashok Kumar C, Logesh TJ, Manimaran B (2017) Oxamidato pillared heteroligated dirhenium(I) metallacrown ethers: synthesis, spectroscopic and structural characterization. J Organomet Chem 828:116–121

    Article  CAS  Google Scholar 

  19. Bélanger S, Gilbertson M, Yoon DI, Stern CL, Dang X, Hupp JT (1999) A luminescent tricarbonylchlororhenium(I) complex featuring a flexible “crown ether” ligand. Manipulation of photoexcited state properties via binding of small cations. J Chem Soc Dalton Trans 3407–3412

    Google Scholar 

  20. Chevrier I, Sagué JL, Brunetto PS, Khanna N, Rajacic Z, Fromm KM (2013) Rings, chains and helices: new antimicrobial silver coordination compounds with (iso-)nicotinic acid derivatives. Dalton Trans 42:217–231

    Article  CAS  Google Scholar 

  21. Ashok Kumar C, Nagarajaprakash R, Victoria W, Veena V, Sakthivel N, Manimaran B (2016) Synthesis, characterisation and cytotoxicity studies of manganese(I) and rhenium(I) based metallacrown ethers. Inorg Chem Commun 64:39–44

    Article  Google Scholar 

  22. Fromm KM, Sagué Doimeadios JL, Robin AY (2005) Concomitant crystallization of two polymorphs—a ring and a helix: concentration effect on supramolecular isomerism. Chem Commun 4548–4550

    Google Scholar 

  23. Sagué JL, Fromm KM (2006) The first two-dimensional polycatenane: a new type of robust network obtained by Ag-connected one-dimensional polycatenanes. Cryst Growth Des 6:1566–1568

    Google Scholar 

  24. Song LC, Zhang WX, Hu QM, Zhao LQ (2004) Synthesis and characterization of a novel bicyclic dimer [CuBr(pcadgd)]2 formed via self-assembly of 4-pyridinecarboxylic acid diethylene glycol diester (pcadgd) with copper(I) bromide. Transit Met Chem 29:603–606

    Article  CAS  Google Scholar 

  25. Dürr H, Kilburg H, Bossmann S (1990) Efficient synthesis of crown ester-linked ruthenium complexes. A new class of a supramolecular sensitizer-crown ester assembly for electron transfer. Synthesis 9:773–778

    Article  Google Scholar 

  26. Sahoo HS, Tripathy D, Chakrabortty S, Bhat S, Kumbhar A, Chand DK (2013) Self-assembled mononuclear palladium(II) based molecular loops. Inorg Chim Acta 400:42–50

    Article  CAS  Google Scholar 

  27. Ganta S, Jagan R, Chand DK (2019) Crystal engineering with palladium(II)-based self-assembled binuclear complexes as tectons. Inorg Chim Acta 484:33–41

    Article  CAS  Google Scholar 

  28. Tripathy D, Ramkumar V, Chand DK (2013) Toppled molecular-domino sets by self-assembly of self-assembly: the π-polymers. Cryst Growth Des 13:3763–3772

    Article  CAS  Google Scholar 

  29. Sautter A, Schmid DG, Jung G, Würthner F (2001) A triangle–square equilibrium of metallosupramolecular assemblies based on Pd(II) and Pt(II) corners and diazadibenzoperylene bridging ligands. J Am Chem Soc 123:5424–5430

    Article  CAS  Google Scholar 

  30. Ferrer M, Mounir M, Rossell O, Ruiz E, Maestro MA (2003) Equilibria between metallosupramolecular squares and triangles with the new rigid linker 1,4-bis(4-pyridyl)tetrafluorobenzene. Experimental and theoretical study of the structural dependence of NMR data. Inorg Chem 42:5890–5899

    Google Scholar 

  31. Uehara K, Kasai K, Mizuno N (2007) Syntheses and characterizations of palladium-based molecular triangle/square compounds and hybrid composites with polyoxometalates. Inorg Chem 46:2563–2570

    Article  CAS  Google Scholar 

  32. Debata NB, Tripathy D, Ramkumar V, Chand DK (2010) Coordination-driven self-assembly in a single pot. Tetrahedron Lett 51:4449–4451

    Article  CAS  Google Scholar 

  33. Tripathy D, Pal AK, Rath SL, Panda BB, Hanan GS, Chand DK (2021) Synthesis, characterization and molecular docking study of nitro(4′-(2-pyridyl)-2,2′:6′,2″-terpyridyl) palladium(II) nitrate. Inorg Chem Commun 126:108494

    Article  CAS  Google Scholar 

  34. Ekennia AC, Osowole AA, Olasunkanmi LO, Onwudiwe DC, Olubiyi OO, Ebenso EE (2017) Synthesis, characterization, DFT calculations and molecular docking studies of metal (II) complexes. J Mol Struct 1150:279–292

    Article  CAS  Google Scholar 

  35. El-Deen IM, Shoair AF, El-Bindary MA (2018) Synthesis, structural characterization, molecular docking and DNA binding studies of copper complexes. J Mol Liq 249:533–545

    Article  CAS  Google Scholar 

  36. The PyMOL molecular graphics system. Version 1.2r3pre. Schrödinger, LLC

    Google Scholar 

Download references

Acknowledgements

DT thanks CSIR for a fellowship. DT, SSM, and DKC thank IIT Madras for the infrastructure facility. SLR thanks NITW for research seed grant P1131.

Author information

Authors and Affiliations

  1. Department of Chemistry, School of Advanced Sciences, VIT-AP University, Amaravati, Andhra Pradesh, 522237, India

    Debakanta Tripathy

  2. Department of Chemistry, Indian Institute of Technology Madras, Chennai, 600036, India

    Debakanta Tripathy, Srabani Srotwosini Mishra & Dillip Kumar Chand

  3. Department of Biotechnology, National Institute of Technology Warangal, Hanamkonda, Telangana, 506004, India

    Soumya Lipsa Rath

Authors
  1. Debakanta Tripathy
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Soumya Lipsa Rath
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Srabani Srotwosini Mishra
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Dillip Kumar Chand
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

The authors have no competing interests to declare that are relevant to the content of this article.

Corresponding author

Correspondence to Debakanta Tripathy .

Editor information

Editors and Affiliations

  1. School of Advanced Sciences, VIT-AP University, Amaravati, Andhra Pradesh, India

    N. Madhusudhana Rao

  2. Department of Polymers and Functional Materials, CSIR-Indian Institute of Chemical Technology, Hyderabad, India

    Giribabu Lingamallu

  3. Department of Mechanical and Energy Engineering, Indiana University-Purdue University Indianapolis, Indianapolis, IN, USA

    Mangilal Agarwal

Rights and permissions

Reprints and permissions

Copyright information

© 2023 The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Tripathy, D., Rath, S.L., Mishra, S.S., Chand, D.K. (2023). Nanoscopic Pd(II)-Based Complexes with Poly-Ether Functionalized Ligand: The Crown Ether Analog. In: Rao, N.M., Lingamallu, G., Agarwal, M. (eds) Advanced Nanomaterials and Their Applications. ICANA 2022. Springer Proceedings in Materials, vol 22. Springer, Singapore. https://doi.org/10.1007/978-981-99-1616-0_4

Download citation

Publish with us

Policies and ethics

Search

Navigation