Abstract
This chapter discusses one engineering application of polybenzoxazines as a highly thermally conductive electronic packaging encapsulant. The combination of various useful properties of benzoxazine resins and their resulting polymers has been demonstrated to render a very high thermally conductive polymer composite. Thermal conductivity value as high as 32.5 W/mK in hexagonal boron nitride-filled polybenzoxazine, up to present, remains the highest reported thermal conductivity value in the literature. Other outstanding properties of the resulting composites as an electronic packaging encapsulant are also discussed in this chapter.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Kroschwitz JI, editor-in-chief (1985) Encyclopedia of polymer science and engineering. Wiley Interscience, New York
Godovsky YK (1992) Thermophysical properties of polymers. Verlag, New York
Werdecker W, Aldinger F, Heraeus WC (1984) IEEE 1984 electronic components conference. New Orleans, 14–16 May 1984, pp 402
Lau JH, Wong CP, Price JL, Nakayama W (1998) Electronic packaging: design, materials process, and reliability. McGraw-Hill, New York
Ishida H, Rimdusit S (1998) Very high thermal conductivity obtained by boron nitride-filled polybenzoxazine. Thermochim Acta 320:177–186
Rimdusit S (2000) Development of high reliability and high processability thermosets for electronic packaging applications based on ternary systems of benzoxazine, epoxy, and phenolic resins. Doctoral Dissertation, Case Western Reserve University, Ohio
Ishida H, Agag T (2011) Handbook of benzoxazine resins. Elsevier, New York
Kumar KSS, Nair CPR (2010) Polybenzoxazine: chemistry and properties. iSmith Rapra Publishing, UK
Ishida H (1999) US Patent 5,900,447
Ishida H, Rimdusit S (2001) US Patent 6,207,786
Song-Hua S, Lejun W, Tian-An C (2007) US Patent 7,179,684
Hyoung-Juhn K, Yeong-Chan E, Sung-Yong C, Ho-Jin K, Jin-Kyoung M, Dong-Hun L, Ju-Yong K, Seong-Jin A (2009) US Patent 7,510,678
Seong-Woo C, Jung-Ock P (2012) US Patent 8,323,849
Kuihara S, Idei H, Aoyagi Y, Kuroe M (2012) US Patent 8,227,390
Tanaka T, Kuzako M, Okamoto K (2012) Toward high thermal conductivity nano micro epoxy composites with sufficient endurance voltage. J Intern Counc Elect Eng 2:90–98
Berman R (1973) Heat conductivity of non-metallic crystals. Contemporary Physics, vol 14, pp 101
Ruth R, Donaldson KY, Hasselman DPH (1992) Thermal conductivity of boron carbide–boron nitride composites. J Am Ceram Soc 75:2887
Pettersson S, Mahan GD (1990) Theory of the thermal boundary resistance between dissimilar lattices. Phys Rev B 42:7386
German RM (1989) Particle packing characteristics. Metal powders industries federation. Princeton, New Jersey
Ishida H, Allen DJ (1996) Gelation behavior of near-zero shrinkage polybenzoxazines. J Polym Sci Phys Ed 34:1019
Bujard P (1988) Thermal conductivity of boron nitride filled epoxy resins: temperature dependence and influence of sample preparation. In: thermal phenomena in the fabrication and operation of electronic components. Proceedings of I-THERM, May 1988, IEEE, Los Angles, p 41
Ruschau GR, Newnham RE (1992) Critical volume fractions in conductive composites. J Compos Mater 26:2727
Ruschau GR, Yoshikawa S, Newnham RE (1992) Percolation constraints in the use of conductor-filled polymers for interconnects. In: 42nd electronic components and technology conference, proceedings IEEE, May 1992, IEEE, Piscataway, p 481
Schroder J (1963) Apparatus for determining the thermal conductivity of solids in the temperature range from 20 to 200 °C. Rev Sci Instrum 34:615
Padilla A, Sanchez-Solis A, Manero O (1988) A note on the thermal conductivity of filled polymers. J Compos Mater 22:616
Bujard P, Kuhnlein G, Ino S, Shiobara T (1994) Thermal conductivity of molding compounds for plastic packaging. IEEE Trans Compn Packg Manu Tech Part A 17:527
Agari Y, Uno T (1985) Thermal conductivity of polymer filled with carbon materials: effect of conductive particle chains on thermal conductivity. J Appl Polym Sci 30:2225
Agari Y, Ueda A, Nagai S (1994) Electrical and thermal conductivities of polyethylene composites filled with biaxial oriented short-cut carbon fibers. J Appl Polym Sci 52:1223
Sahimi M (1994) Applications of percolation theory. Taylor and Francis, London
Neogi P (ed) (1996) Diffusion in polymers. Marcel Dekker, New York
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2013 Springer Science+Business Media Singapore
About this chapter
Cite this chapter
Rimdusit, S., Jubsilp, C., Tiptipakorn, S. (2013). High Thermal Conductivity of BN-Filled Polybenzoxazines. In: Alloys and Composites of Polybenzoxazines. Engineering Materials. Springer, Singapore. https://doi.org/10.1007/978-981-4451-76-5_4
Download citation
DOI: https://doi.org/10.1007/978-981-4451-76-5_4
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-4451-75-8
Online ISBN: 978-981-4451-76-5
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)