Abstract
In reality, all production processes proceed with the generation of entropy and destruction of useful energy of resource inputs. In view of this, the second law of thermodynamics can be directly linked with sustainability and sustainable development. Estimation of a system’s exergy status in order to know the distribution of energy and matter, especially emissions, would help identify the efficiency of the system, hence improving it for sustainable development. In this chapter, the thermodynamic sustainability of biodiesel, bioethanol, biogas, and briquettes production from oil palm biomass are investigated via exergy analysis. Most studies on exergy analysis of biofuels production systems do not consider the production of the feedstocks though these stages are materials and energy intensive. The production of oil palm biomass for palm biofuels is assessed for thermodynamic feasibility in this study in order to give a complete overview of the contributions of every single unit within the palm biofuels production systems. Aspen Plus software was used for the mathematical modeling for all the case studies considered in this chapter. Potential causes and improvement options are also discussed in this chapter for sustainable palm biofuels production.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsNotes
- 1.
In a dead state system, the exergy of the stream or system is always zero due to the attainment of equilibrium with the reference environment (Ahrendts 1980).
- 2.
This makes the use of the phrase ‘energy consumption’ so ambiguous in that energy can never be destroyed according to the first law of thermodynamics. What is actually consumed is exergy hence, ‘exergy consumption.’
- 3.
c is the velocity relative to Earth’s surface.
- 4.
g is the constant of gravitational acceleration and x is the height.
- 5.
Examples of interactions in a system which lead to irreversibilities are heat and momentum transfers through a finite temperature difference, mixing of matter at different compositions or states, unrestrained expansion, and friction.
References
Abuadala A, Dincer I, Naterer GF (2010) Exergy analysis of hydrogen production from biomass gasification. Int J Hydrogen Energy 34:4981–4990
Ahrendts J (1980) Reference states. Energy 8:667–677
Aspen Technology (1988) Aspen plus user guide. Aspen Technology, Cambridge
Aspen Technology (2004) Aspen engineering suite. www.aspentech.com
Ayres RU, Ayres LW (1998) Accounting for resources 1: economy-wide applications of mass-balance principles to materials and waste. Edward Elgar, Cheltenham
Ayres RU, Turton H, Casten T (2007) Energy efficiency, sustainability and economic growth. Energy 32(634):648
Begum S, Saad MFM (2013) Techno-economic analysis of electricity generation from biogas using palm oil waste. Asian J Sci Res 6:290–298
Berglund M, Börjesson P (2006) Assessment of energy performance in the life-cycle of biogas production. Biomass Bioenergy 30:254–266
Bejan A, Tsatsaronis G, Moran M (1996) Thermal design and optimization. Wiley-IEEE, New York
Benjaminsson J, Goldschmidt B, Uddgren R (2010) Optimal integration of energy at the combined energy plant in Norrköping—integration of steam, hot water and district heat to biogas plants (Rapport 1149). VÄRMEFORSK Service AB, Stockholm
Bockari-Gevao SM, Wan Ishak WI, Azmi Y, Chan CW (2005) Analysis of energy consumption in lowland rice-based cropping system of Malaysia. Sci Technol 27:819–826
Börjesson P, Berglund M (2007) Environmental systems analysis of biogas systems-Part II: the environmental impact of replacing various reference systems. Biomass Bioenergy 31:326–344
Carnot S (1978) Reflections on the motive power of fire: a critical edition with the surviving scientific manuscript. Manchester University Press ND, Manchester, p 230
Choo YM, Muhamad H, Hashim Z, Subramaniam V, Puah CW, Tan Y (2011) Determination of GHG contributions by subsystems in the oil palm supply chain using the LCA approach. Int J Life Cycle Assess 16:669–681
Cornelisse R (1997) The method of exergy analysis. Ph D Dissertation, University of Twente, The Netherlands
de Almeida SCA, Carlos RB, Marcos VGN, dos Leonardo SRV, Guilherme F (2002) Performance of a diesel generator fuelled with palm oil. Fuel 81:2097–2102
De Meester B, Dewulf J, Janssens A, Van Langenhove H (2006) An improved calculation of the exergy of natural resources for exergetic life cycle assessment (ELCA). Environ Sci Technol 40:6844–6851
De Swaan AJ, Van der Kooi HJ (1993) Exergy analysis, adding insight and precision to experience and intuition. In: Weynen MPC, Drinkenburg AAH (eds) Precision process technology. Kluwer Academic Publishers, Dordrecht, pp 89–113
De Swaan AJ, Van der Kooi H, Sankaranarayanan K (2004) Efficiency and sustainability in the energy and chemical industries. Marcel Dekker, New York
Dewar R (2005) Maximum entropy production and the fluctuation theorem. J Phys 38(371):381
Dhar BR, Kirtania K (2009) Excess methanol recovery in biodiesel production process using a distillation column: a simulation study. Chem Eng Res Bull 13:55–60
Doherty W, Reynolds A, Kennedy D (2010) Computer simulation of a biomass gasification-solid oxide fuel cell power system using aspen plus. Energy 35:4545–4555
Fiorini P, Sciubba E (2005) Thermoeconomic analysis of a MSF desalination plant. Desalin 182:39–51
Gámez S, Gonzalez-Cabriales JJ, Ramirez JA, Garrote G, Vazquez M (2006) Study of the hydrolysis of sugar cane bagasse using phosphoric acid. J Food Eng 74:78–88
Goh CS, Tan HT, Lee KT (2012) Pretreatment of oil palm frond using hot compressed water: evaluation of compositional changes and pulp digestibility using severity factors. Bioresour Technol 110:662–669
Gómez-Castro FI, Segovia-Hernández JG, Hernández S, Gutiérrez-Antonio C, Briones-Ramírez A (2008) Dividing wall distillation columns: optimization and control properties. Chem Eng Technol 31:1246–1260
Gómez-Castro FI, Rico-Ramirez V, Segovia-Hernández JG, Hernandez-Castro S (2010) Feasibility study of a thermally coupled reactive distillation process for biodiesel production. Chem Eng Process Process Intensif 49:262–269
Halimah M, Ismail BS, Salmijah S, Tan YA, Choo YM (2012) A Gate-to-gate Case Study of the Life Cycle Assessment of an Oil Palm Seedling. Tropic Life Sci Res 23:15–23
Halimahton M, Abdul RA (1990) Carbohydrates in the oil palm stem and their potential use. J Trop Forest Sci 2:220–226
Hamelinck CN, Hooijdonk GV, Faaij A (2005) Ethanol from lignocellulosic biomass: techno-economic performance in short-, middle- and long-term. Biomass Bioenergy 28:384–410
Hermann WA (2006) Quantifying global exergy resources. Energy 31:1685–1702
Hosseini SE, Abdul Wahid M (2013) Feasibility study of biogas production and utilization as a source of renewable energy in Malaysia. Renew Sustain Energy Rev 19:454–462
Jaimes W, Acevedo P, Kafarov V (2010) Exergy analysis of palm oil biodiesel production. Chem Eng Trans 21:1345–1350
Joanta HG (1996) Renewable energy systems in Southeast Asia. PennWell Publishing Company, Tulsa, p 167
Jørgensen SE, Svirezhev YM (2004) Application of exergy as ecological indicator and goal function in ecological modeling, towards a thermodynamic theory for ecological systems. Proceedings of ecological indicators. Elsevier, Amsterdam, pp 325–349
Keey RB (1978) Introduction to industrial drying operations. Pergamon Press, New York
Kotas TJ (1985) The exergy method of thermal plant analysis. Butterworths, London
Van Krevelen DW, Chermin HAG (1952) Erratum: estimation of the free enthalpy (Gibbs free energy of formation of organic compounds from group contribution). Chem Eng Sci 1:238
Lantz M, Svensson M, Björnsson L, Börjesson P (2007) The prospects for an expansion of biogas systems in Sweden-incentives, barriers and potentials. Energy Policy 35:1830–1843
Leites IL, Sama DA, Lior N (2003) The theory and practice of energy saving in the chemical industry: some methods for reducing thermodynamic irreversibilities in chemical technology processes. Energy 28:55–97
Linnhoff B (1983) New concepts in thermodynamics for better chemical process design. Chem Eng Res Des 61:207–222
Ma AN, Ong ASH (1985) Pollution control in palm oil mills in Malaysia. JAOCS 62(2):261–266
Ma AN (1999) The planters, Kuala Lumpur Innovations in Management of Palm Oil MillEffluent. Palm Oil Research Institute of Malaysia (PORIM), Kuala Lumpur, Malaysia
Martin M, Parsapour A (2012) Upcycling wastes with biogas production: an exergy and economic analysis. In: Proceedings of the fourth international symposium on energy from biomass and waste, Venice
Millati R, Niklasson C, Taherzadeh MJ (2002) Effect of pH, time and temperature of overliming on detoxification of dilute-acid hydrolysates for fermentation by Saccharomyces cerevisiae. Process Biochem 38:515–522
Moiser N, Wyman C, Dale B, Elander R, Lee Y, Holtzapple M, Ladisch M (2005) Features of promising technologies for pretreatment of lignocellulosic biomass. Bioresour Technol 96:673–686
Murphy JD, McCarthy K (2005) The optimal production of biogas for use as a transport fuel in Ireland. Renew Energy 30:2111–2127
Nikander S (2008) Greenhouse gas and energy intensity of product chain: case transport biofuel. MSc thesis, Helsinki University of Technology, Helsinki, Finland
NKEA (National Key Economic Areas) (2011) Biogas capture and CDM project implementation for palm oil mills. NKEA: National Biogas Implementation (EPP5), Malaysia, pp. 1–28
Ofori-Boateng C, Lee KT, JitKang L (2012a) Feasibility study of microalgal and jatropha biodiesel production plants: exergy analysis approach. Appl Therm Eng 36:141–151
Ofori-Boateng C, Lee KT, JitKang L (2012b) Comparative exergy analyses of Jatropha curcas oil extraction methods: solvent and mechanical extraction processes. Energy Conversat Manag 55:164–171
Ofori-Boateng C, Lee KT, JitKang L (2012c) Sustainability assessment of microalgal biodiesel production processes: an exergetic analysis approach with aspen plus. Int J Exergy 10:400–416
Ofori-Boateng C, Lee KT (2013) Comparative Thermodynamic Sustainability Assessment of lignocellulosic pretreatment methods for bioethanol production via exergy analysis. Chem Eng J 228:162–171
Ojeda K, Kafarov V (2009) Exergy analysis of enzymatic hydrolysis reactors for transformation of lignocellulosic biomass to bioethanol. Chem Eng 154:390–395
Ojeda K, Sánchez E, El-Halwagi M, Kafarov V (2011) Exergy analysis and process integration of bioethanol production from acid pre-treated biomass: comparison of SHF, SSF and SSCF pathways. Chem Eng 176–177:195–201
Olawale AS, Adefila SS (1998) Improved energy efficiency in absorption heat pump through process modification. Part II: thermodynamic potential of liquid–liquid extraction of ammonia-water mixtures. Energy Conversat Manag 39:1027–1044
O-Thong S, Boe K, Angelidaki I (2012) Thermophilic anaerobic co-digestion of oil palm empty fruit bunches with palm oil mill effluent for efficient biogas production. Appl Energy 93:648–654
Palmqvist E, Hahn-Hagerdal B (2000) Fermentation of lignocellulosic hydrolysates II: inhibitors and mechanisms of inhibition. Bioresour Technol 74:25–33
Pellegrini LF, Silvio de Oliveira J (2007) Exergy analysis of sugarcane bagasse gasification. Energy 32:314–327
Peralta Y, Sanchez E, Kafarov V (2010) Exergy analysis for third generation biofuel production from microalgae biomass. Chem Eng Trans 21:1363–1368
Prausnitz JM, Lichtenthaler RN, Azevedo EG (1999) Molecular Thermodynamics of Fluid-Phase Equilibria, 3rd ed, Prentice-Hall, Englewood Cliffs, NJ, USA
Prausnitz JM, Anderson TF, Grens EA, Eckert CA, Hsieh R, O’Conell JP (1980) Computer calculations for multicomponent vapor–liquid and liquid–liquid equilibria. Prentice-Hall, Englewood Cliffs
Ptasinski KJ, Hamelinck C, Kerkhof PJAM (2002) Exergy analysis of methanol from the sewage sludge process. Energy Conversat Manag 43:1445–1457
Ptasinski KJ, Prins MJ, Pierik A (2007) Exergetic evaluation of biomass gasification. Energy 32:568–574
Quah SK (1987) Chan Wing palm oil mill effluent treatment and by-product utilization—a case study. In: Lecture notes for training course on biogas reactor design and development, vol II. King Mongkut’s Institute of Technology Thonburi, Bangkok, pp 562–584
Reid RC, Prausnitz JM, Sherwood TK (1977) The properties of gases and liquids, 3rd edn. McGraw-Hill, New York, p 688
Rivero R (2002) Application of the exergy concept in the petroleum refining and petrochemical industry. Energy Conversat Manag 43:1199–1220
Rivero R, Rendon C, Monroy L (1999) The exergy of crude oil mixtures and petroleum fractions: calculation application. Int J Appl Thermodyn 2:115–123
Rivero R, Garfias M (2006) Standard chemical exergy of elements updated. Energy 31:3310–3326
Rosen MA, Dincer I (1997) Sectoral energy and exergy modeling of Turkey. ASME-J Energy Resour Technol 119:200–204
Rucker A, Gruhn G (1999) Exergetic criteria in process optimization and process synthesis- opportunities and limitations. Comput Chem Eng 23:109–112
Sama DA, Qian S, Gaggioli R (1989) A common-sense Second Law approach for improving process efficiencies. In: Proceedings of the International Symposium on Thermodynamic Analysis and Improvement of Energy Systems. International Academic Publishers (Pergamon Press), Beijing, China, p. 520-531
Sato N (2004) Chemical Energy and Exergy: an Introduction to Chemical Thermodynamics for Engineers. Elsevier BV, Amsterdam, Netherlands.
Schenk M (2001) Towards a more sustainable food protein production chain. Department of Chemical Engineering, Technical University Delft, the Netherlands. Available at http://edepot.wur.nl/121798. Accessed on 4th March 2011
Schmidt JH (2007) Life assessment of rapeseed oil and palm oil. Part 3: Lifecycle inventory of rapeseed oil and palm oil. Ph.D. Thesis, Department of Development and Planning, Aalborg University, Aalborg
Sciubba E, Wall G (2007) A brief commented history of exergy from the beginnings to 2004. Int J Thermodyn 10:1–26
Sežun M, Grilc V, Logar RM (2010) Anaerobic digestion of mechanically and chemically pretreated lignocellulosic substrate. CISA, Environmental Sanitary Engineering Center, Third international symposium on energy from biomass and waste, Venice, Italy
Shieh JH, Fan LT (1983) Energy and exergy estimation using the group contribution method: In Gaggioli RA (ed) Efficiency and costing. ACS symposium series No. 235. American Chemical Society, Washington, DC, pp 351–371
Sorguven E, Ozilgen M (2010) Thermodynamic assessment of algal biodiesel utilization. Renew Energy 9:1956–1966
Szargut J (1989) Chemical exergies of the elements. Appl Energy 32: 269–286.
Szargut J, David R, Frank R (1988) Exergy analysis of thermal, chemical and metallurgical processes. Hemisphere Publishing Corporation, New York
Szargut J (2005) Exergy method: technical and ecological applications. WIT Press, Southampton
Talens PL, Gara VA, Xavier GAB (2007) Exergy analysis applied to biodiesel production. Resour Conserv Recycl 51:397–407
Talens PL, Villalba MG, Sciubba E, Gabarrelli DX (2010) Extended exergy accounting applied to biodiesel production. Energy 35:2861–2869
Triantafyllou C, Smith R (1992) The design and optimization of fully thermally coupled distillation columns. Trans IChemE 70A:118–132
Tsatsaronis G, Kelly S, Morosuk T (2006) Endogenous and exogenous exergy destruction in thermal systems, In: Proceedings of the ASME international mechanical engineering congress and exposition, 5–10 Nov, Chicago, USA, CD-ROM, file 2006-13675
Utlu Z, Hepbasli A (2007) Parametrical investigation of the effect of dead (reference) state on energy and exergy utilization efficiencies of residential–commercial sectors: a review and an application. Renew Sustain Energy Rev 11:603–634
Valero A, Lozano MA, Muñoz M (1986) A general theory of exergy saving. ASME Book No. H0 341A, WAM AES, ASME, New York, vol 2–3, pp 1–22
Wall G (2010) On exergy and sustainable development in environmental engineering. Open Environ Eng 3:21–32
Wan Zahari M, Sato J, Furuichi S, Sukri IM, Bakar CA, Yunus I (2004) Recent development on the processing and utilisation of complete feed based on oil palm fronds (OPF) for ruminant feeding in Malaysia. In: Tanaka R, Cheng LH (eds) Lignocellulose: materials for the future from the tropics. JIRCAS working report, 39. Proceedings of 3rd USM-JIRCAS joint international symposium, Penang, Malaysia, pp 125–129
West AH, Posarac D, Ellis N (2008) Assessment of four biodiesel production processes using HYSYS. Bioresour Technol 99:6587–6601
Wooley R, Putsche V (1996) Development of an ASPEN PLUS physical property database for biofuels components. National Renewable Energy Laboratory, NREL/MP-425-20685
Yejian Z, Hairen Y, Xiangyong Z, Zhenjia Z, Li Y (2011) High-rate mesophilic anaerobic digestion of Palm Oil Mill effluent (POME) in Expanded Granular Sludge Bed (EGSB) reactor. Adv Biomed Eng 3–5:214–219
Yusoff S (2006) Renewable energy from palm oil—innovation on effective utilization of waste. J Cleaner Prod 14:87–93
Zhang XP, Solli C, Hertwich EG et al (2009) Exergy analysis of the process for dimethyl ether production through biomass steam gasification. Ind Eng Chem Res 48:10976–10985
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2013 Springer Science+Business Media Singapore
About this chapter
Cite this chapter
Lee, K.T., Ofori-Boateng, C. (2013). Thermodynamic Sustainability Assessment of Biofuel Production from Oil Palm Biomass. In: Sustainability of Biofuel Production from Oil Palm Biomass. Green Energy and Technology. Springer, Singapore. https://doi.org/10.1007/978-981-4451-70-3_7
Download citation
DOI: https://doi.org/10.1007/978-981-4451-70-3_7
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-4451-69-7
Online ISBN: 978-981-4451-70-3
eBook Packages: EnergyEnergy (R0)