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A Review on Soil Remediation by Fenton Process

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Advances in Geotechnics and Structural Engineering

Abstract

As the development and population of a country grow, its industrialization and other modern techniques also increase to meet the growing demand of the people. These technologies, as progress, directly and indirectly, are affecting our environment in many ways. These effects include the vitiating the ambient air quality due to the emission of the harmful gases from various industrial and human activities; water is being polluted by so many toxic matters and contamination of the soil by various degradable and non-degradable matter is also becoming very common. The contaminated soil may have so many adverse effects on our environment like polluting the groundwater, harmful for vegetation, other lives, etc. However, many methods are being adopted by researchers and engineers for the making such soil free of contamination but among all methods of treatment advanced oxidation process(AOP) is one of a favorable method for the soil that is contaminated with highly and non-easily removing pollutants. There are many methods of AOP itself that are used for this purpose like photocatalysis (TiO2), Fenton processes, ozonation and plasma oxidation, etc. that have their characteristics and effectiveness. The present study only focuses on the Fenton process and its mechanism for the treatment of the soil. Also, this paper reviews the performance of modified Fenton processes for removal of highly stabilize pollutants from the soil.

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References

  1. Ashraf M, Ozturk M, Ahmad MSA, Aksoy A (Eds) (2012) Crop production for agricultural improvement. Productivity. Springer, 796 pp

    Google Scholar 

  2. Phytotech (2000) Phytoremediation technology. https://cluin.org/PRODUCTS/SITE/ongoing/demoong/phytotec.htm

  3. Pierzynski GM, Sims JT, Vance GF (2000) Soils and environmental quality, 2nd edn. CRC Press, London, UK

    Google Scholar 

  4. Jian C, Ji-Zhong DU, Yang Z, Hong-Wei MA, Xiao LI (2011) Characteristics of soil organic pollution in Shenyang suburbs of Liaoning Province, Northeast China. Chin J Ecol 30:2472–2477

    Google Scholar 

  5. Terrado M, Barceló D, Tauler R (2010) Multivariate curve resolution of organic pollution patterns in the Ebro River surface water-groundwater-sediment-soil system. Anal Chim Acta 657:19–22

    Article  Google Scholar 

  6. Tsitonaki A, Petri B, Crimi M, MosbÆk H, Siegrist RL, Bjerg PL (2010) In situ chemical oxidation ofcontaminated soil and groundwater using persulfate: a review. Crit Rev Environ Sci Technol 40:55–91

    Article  Google Scholar 

  7. U.E.P.A. (USEPA) (2006) In situ treatment technologies for contaminated soil- engineering forum issue paper. In: U.E.P.A. (USEPA) (Ed.)

    Google Scholar 

  8. USEPA (1996) Report: recent developments for in situ treatment of metals contaminated soils. U.S. Environmental Protection Agency, Office of Solid Waste and Emergency Response

    Google Scholar 

  9. Villa RD, Trovó AG, Nogueira RFP (2008) Environmental implications of soil remediation using the Fenton process. Chemosphere 71:43–50

    Article  Google Scholar 

  10. He X, de la Cruz AA, O’Shea KE, Dionysiou DD (2014) Kinetics and mechanisms of cylindrospermopsin destruction by sulfate radical-based advanced oxidation processes. Water Res 63:168–178

    Article  Google Scholar 

  11. Watts RJ, Stanton PC, Howsawkeng J, Teel AL (2002) Mineralization of a sorbed polycyclic aromatic hydrocarbon in two soils using catalyzed hydrogen peroxide. Water Res 36:4283–4292

    Article  Google Scholar 

  12. Andreozzi R, Caprio V, Insola A, Marotta R (1999) Advanced oxidation processes (AOP) for water purification and recovery. Catal Today 53:51–59

    Article  Google Scholar 

  13. Ayoub K, van Hullebusch ED, Cassir M, Bermond A (2010) Application of advanced oxidation processes for TNT removal: a review. J Hazard Mater 178:10–28

    Article  Google Scholar 

  14. Esplugas S, Yue PL, Pervez MI (1994) Degradation of 4-chlorophenol by photolytic oxidation. Water Res 28:1323–1328

    Article  Google Scholar 

  15. Masten SJ, Davies SH (1994) The use of ozonation to degrade organic contaminants in wastewaters. Environ Sci Technol 28:180A-185A

    Article  Google Scholar 

  16. Hoigné J, Bader H (1983) Rate constants of reactions of ozone with organic and inorganic compounds in water—II: dissociating organic compounds. Water Res 17:185–194

    Article  Google Scholar 

  17. Zhang Y, Han C, Zhang G, Dionysiou DD, Nadagouda MN (2015) PEG-assisted synthesis of crystal TiO2 nanowires with high specific surface area for enhanced photocatalytic degradation of atrazine. Chem Eng J 268:170–179

    Article  Google Scholar 

  18. Andreozzi R, Caprio V, Insola A, Marotta R (1999) Advanced oxidation processes (AOP) for water purification and recovery. Catal Today 53(1):51–59

    Article  Google Scholar 

  19. Parsons SA (ed) (2004) Advanced oxidation processes for water and wastewater treatment. IWA Publishing, Alliance House, London

    Google Scholar 

  20. Deng Y, Zhao R (2015) Advanced oxidation processes (AOPs) in wastewater treatment, pp 167–176

    Google Scholar 

  21. Haber F, Weiss J (1934) The catalytic decomposition of hydrogen peroxide by iron salts. In: Proceedings of the Royal Society of London A: Mathematical, Physical and Engineering Sciences, The Royal Society, pp 332–351

    Google Scholar 

  22. Flotron V, Delteil C, Padellec Y, Camel V (2005) Removal of sorbed polycyclic aromatic hydrocarbons from soil, sludge and sediment samples using the Fenton’s reagent process. Chemosphere 59:1427–1437

    Article  Google Scholar 

  23. De Laat J, Gallard H (1999) Catalytic decomposition of hydrogen peroxide by Fe (III) in homogeneous aqueous solution: mechanism and kinetic modeling. Environ Sci Technol 33:2726–2732

    Article  Google Scholar 

  24. Burbano AA, Dionysiou DD, Suidan MT, Richardson TL (2005) Oxidation kinetics and effect of pH on the degradation of MTBE with Fenton reagent. Water Res 39:107–118

    Article  Google Scholar 

  25. Matta R, Hanna K, Kone T, Chiron S (2008) Oxidation of 2,4,6-trinitrotoluene in the presence of different iron-bearing minerals at neutral pH. Chem Eng J 144:453–458

    Article  Google Scholar 

  26. Yap CL, Gan S, Ng HK (2011) Fenton based remediation of polycyclic aromatic hydrocarbons-contaminated soils. Chemosphere 83:1414–1430

    Article  Google Scholar 

  27. Quiroga J, Riaza A, Manzano M (2009) Chemical degradation of PCB in the contaminated soils slurry: Direct Fenton oxidation and desorption combined with the photo-Fenton process. J Environ Sci Heal Part A 44:1120–1126

    Article  Google Scholar 

  28. Zepp RG, Faust BC, Hoigne J (1992) Hydroxyl radical formation in aqueous reactions (pH 3–8) of iron (II) with hydrogen peroxide: the photo-Fenton reaction. Environ Sci Technol 26:313–319

    Article  Google Scholar 

  29. Khataee A, Salahpour F, Fathinia M, Seyyedi B, Vahid B (2015) Iron rich laterite soil with mesoporous structure for heterogeneous Fenton-like degradation of an azo dye under visible light. J Ind Eng Chem 26:129–135

    Article  Google Scholar 

  30. Huston PL, Pignatello JJ (1999) Degradation of selected pesticide active ingredients andcommercial formulations in water by the photo-assisted Fenton reaction. Water Res 33:1238–1246

    Article  Google Scholar 

  31. Mousset E, Oturan MA, Van Hullebusch ED, Guibaud G, Esposito G (2014) Soil washing/flushing treatments of organic pollutants enhanced by cyclodextrins and integrated treatments: state of the art. Crit Rev Environ Sci Technol 44:705–795

    Article  Google Scholar 

  32. Cheng M, Zeng GM, Huang DL, Lai C, Xu P, Zhang C, Liu Y (2016) Hydroxyl radicals based advanced oxidation processes (AOPs) for remediation of soils contaminated with organic compounds: a review. Chem Eng J 284:582–598

    Article  Google Scholar 

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Correspondence to Atif Husain .

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Anwer, M., Husain, A., Zafar, T. (2021). A Review on Soil Remediation by Fenton Process. In: Kumar Shukla, S., Raman, S.N., Bhattacharjee, B., Bhattacharjee, J. (eds) Advances in Geotechnics and Structural Engineering. Lecture Notes in Civil Engineering, vol 143. Springer, Singapore. https://doi.org/10.1007/978-981-33-6969-6_16

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  • DOI: https://doi.org/10.1007/978-981-33-6969-6_16

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  • Publisher Name: Springer, Singapore

  • Print ISBN: 978-981-33-6968-9

  • Online ISBN: 978-981-33-6969-6

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