Abstract
Lithium metal is one of the most promising negative electrodes for high-energy-density rechargeable batteries, but its critical problem is low Coulombic efficiency resulting from the reductive decomposition of an electrolyte thereon, which has hampered its commercial applications. Various electrolytes and additives have been proposed to form a stable interphase between Li metal and electrolyte. Among them, salt-concentrated electrolytes have been most extensively studied, which create a unique anion-derived interphase that can highly stabilize the Li metal/electrolyte interface. The optimization of the salt–solvent combinations as well as the salt concentration enables us to achieve high Coulombic efficiency of over 99%. Herein the unique interphasial properties of concentrated electrolytes, as well as other beneficial interfacial/bulk properties such as extended potential windows, prevented metal corrosion, accelerated electrode reactions, increased transference number and decreased volatility/flammability, are discussed with a focus on their peculiar coordination structures.
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References
Yamada, Y., Takazawa, Y., Miyazaki, K., & Abe, T. (2010). Journal of Physical Chemistry C, 114, 11680.
Yamada, Y., Furukawa, K., Sodeyama, K., Kikuchi, K., Yaegashi, M., Tateyama, Y., et al. (2014). Journal of the American Chemical Society, 136, 5039.
Yoshida, K., Nakamura, M., Kazue, Y., Tachikawa, N., Tsuzuki, S., Seki, S., et al. (2011). Journal of the American Chemical Society, 133, 13121.
Matsumoto, K., Inoue, K., Nakahara, K., Yuge, R., Noguchi, T., & Utsugi, K. (2013). Journal of Power Sources, 231, 234.
McOwen, D. W., Seo, D. M., Borodin, O., Vatamanu, J., Boyle, P. D., & Henderson, W. A. (2014). Energy & Environmental Science, 7, 416.
Yamada, Y., Yaegashi, M., Abe, T., & Yamada, A. (2013). Chemical Communications, 49, 11194.
Suo, L., Hu, Y.-S., Li, H., Armand, M., & Chen, L. (2013). Nature Communications, 4, 1481.
Wang, J., Yamada, Y., Sodeyama, K., Chiang, C. H. C. H., Tateyama, Y., & Yamada, A. (2016). Nature Communications, 7, 12032.
Jeong, S. K., Inaba, M., Iriyama, Y., Abe, T., & Ogumi, Z. (2003). Electrochemical and Solid-State Letters, 6, A13.
Jeong, S. K., Seo, H. Y., Kim, D. H., Han, H. K., Kim, J. G., Lee, Y. B., et al. (2008). Electrochemistry Communications, 10, 635.
Togasaki, N., Momma, T., & Osaka, T. (2016). Journal of Power Sources, 307, 98.
Liu, B., Xu, W., Yan, P., Kim, S. T., Engelhard, M. H., Sun, X., et al. (2017). Advanced Energy Matericals, 7, 1602605.
Qian, J., Henderson, W. A., Xu, W., Bhattacharya, P., Engelhard, M., Borodin, O., et al. (2015). Nature Communications, 6, 6362.
Liu, P., Ma, Q., Fang, Z., Ma, J., Hu, Y. S., Bin, Z., et al. (2016). Chinese Physics B, 25, 7.
Fan, X., Chen, L., Ji, X., Deng, T., Hou, S., Chen, J., et al. (2018). Chem, 4, 174.
Alvarado, J., Schroeder, M. A., Zhang, M., Borodin, O., Gobrogge, E., Olguin, M., et al. (2018). Materials Today, 21, 341.
Maeyoshi, Y., Ding, D., Kubota, M., Ueda, H., Abe, K., Kanamura, K., et al. (2019). ACS Applied Materials & Interfaces, 11, 25833.
Suo, L., Xue, W., Gobet, M., Greenbaum, S. G., Wang, C., Chen, Y., et al. (2018). Proceedings of National Academy of Sciences, 115, 1156.
Yamada, Y., Wang, J., Ko, S., Watanabe, E., & Yamada, A. (2019). Nature Energy, 4, 269.
Dokko, K., Tachikawa, N., Yamauchi, K., Tsuchiya, M., Yamazaki, A., Takashima, E., et al. (2013). Journal of the Electrochemical Society, 160, A1304.
Chen, S., Zheng, J., Mei, D., Han, K. S., Engelhard, M. H., Zhao, W., et al. (2018). Advanced Materials, 30, 1706102.
Ren, X., Chen, S., Lee, H., Mei, D., Engelhard, M. H., Burton, S. D., et al. (2018). Chem, 4, 1877.
Chen, S., Zheng, J., Yu, L., Ren, X., Engelhard, M. H., Niu, C., et al. (2018). Joule, 2, 1548.
Sodeyama, K., Yamada, Y., Aikawa, K., Yamada, A., & Tateyama, Y. (2014). Journal of Physical Chemistry C, 118, 14091.
Wang, J., Yamada, Y., Sodeyama, K., Watanabe, E., Takada, K., Tateyama, Y., et al. (2018). Nature Energy, 3, 22.
Ueno, K., Murai, J., Ikeda, K., Tsuzuki, S., Tsuchiya, M., Tatara, R., et al. (2016). Journal of Physical Chemistry C, 120, 15792.
Takada, K., Yamada, Y., & Yamada, A. (2019). ACS Applied Materials & Interfaces, 11, 35770.
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Yamada, Y. (2021). Concentrated Electrolytes for Lithium Metal Negative Electrodes. In: Kanamura, K. (eds) Next Generation Batteries. Springer, Singapore. https://doi.org/10.1007/978-981-33-6668-8_3
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DOI: https://doi.org/10.1007/978-981-33-6668-8_3
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