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Thermoelectric Properties of Β-FeSi2 Thermoelectric Module Utilizing Cast-Iron Scrap Chips

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Proceeding of 5th International Conference on Advances in Manufacturing and Materials Engineering

Abstract

Semiconducting β-FeSi2 has been considered one of the most promising thermoelectric materials among numerous innovative thermoelectric materials due to its inexpensive cost and exceptional oxidation resistance up to 900 °C. Thermoelectric generation modules consisting of pairs of p-type 0.94C.I.-0.06Co-1.86Si and n-type 0.92C.I.-0.08Mn-1.86Si have been fabricated using Cu sheets as electrodes and Ag paste as bonding material. In an experiment, the maximum power density is measured by using a variable resistor range of 10 Ω—10 kohm. Two different temperatures that are tested in this project are 40 and 60 °C. A rectangle and a trapezoid as the thermoelectric leg shape geometry are compared. The percentage difference for voltage is around 21% while the power shows a 41 and 65% difference depending on the temperature difference. The latter percentage difference is possessed by higher T. Based on the comparison with the reference, thermoelectric module from cast iron scrap chips was comparable and better than the reference. Trapezoid shows better geometry than rectangular shape in terms of thermoelectric power density. At 40 ℃, the maximum power output are 21.89 and 21.91 μW whilst the maximum power for 60 ℃ are 28.13 μW and 28.42 μW for rectangle and trapezoid respectively.

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References

  1. Patidar S (2018) Applications of thermoelectric energy: a review. Int J Res Appl Sci Eng Technol 6(5):1992–1996

    Article  Google Scholar 

  2. Espinosa N, Lazard M, Aixala L, Scherrer H (2010) Modeling a thermoelectric generator applied to diesel automotive heat recovery. J Electron Mater 39(9):1446–1455

    Article  Google Scholar 

  3. Mori M, Yamagami T, Sorazawa M, Miyabe T, Takahashi S, Haraguchi T (2011) Simulation of fuel economy effectiveness of exhaust heat recovery system using thermoelectric generator in a series hybrid. SAE Int J Mater Manuf 4(1):1268–1276

    Article  Google Scholar 

  4. Hussain QE, Brigham DR, Maranville CW (2009) Thermoelectric exhaust heat recovery for hybrid vehicles. SAE Int J Engines 2(1):1132–1142

    Article  Google Scholar 

  5. He R, Schierning G, Nielsch K (2018) Thermoelectric devices: thermoelectric devices: a review of devices, architectures, and contact optimization (adv. mater. technol. 4/2018). Adv Mater Technol 3(4):1870016

    Google Scholar 

  6. Soleimani Z, Zoras S, Ceranic B, Shahzad S, Cui Y (2020) A review on recent developments of thermoelectric materials for room-temperature applications. Sustain Energy Technol Assess 37:100604

    Google Scholar 

  7. Zhao XB, Zhu TJ, Hu SH, Zhou BC, Wu ZT (2000) Transport properties of rapid solidified Fe–Si–Mn–Cu thermoelectric alloys. J Alloy Compd 306(1–2):303–306

    Article  Google Scholar 

  8. Granath E, James L (2021) Understanding the difference between N- and p-type semiconductors. Power and Beyond, November 19. Retrieved December 16, 2021, from https://www.power-and-beyond.com/understanding-the-difference-between-n-and-p-type-semiconductors-a-905805/

  9. Dąbrowski F, Ciupiński Ł, Zdunek J, Kruszewski J, Zybała R, Michalski A, Jan Kurzydłowski K (2019) Microstructure and thermoelectric properties of P and N type doped β-fesi2 fabricated by mechanical alloying and Pulse Plasma Sintering. Mater Today: Proc 8:531–539

    Google Scholar 

  10. Umemoto M (1995) Preparation of Thermoelectric β-fesi2 doped with al and Mn by mechanical alloying (overview). Mater Trans, JIM 36(2):373–383

    Article  Google Scholar 

  11. Laila A, Nanko M, Takeda M (2014) Upgrade recycling of cast iron scrap chips towards β-fesi2 thermoelectric materials. Materials 7(9):6304–6316

    Article  Google Scholar 

  12. Singh R (2012) Cast iron. Appl Welding Eng 57–64

    Google Scholar 

  13. Nogi K, Kita T, Yan X-Q (2001) Production of iron-disilicide thermoelectric devices and thermoelectric module by the slip casting method. Mater Sci Eng, A 307(1–2):129–133

    Article  Google Scholar 

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Correspondence to Assayidatul Laila Nor Hairin .

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Hairin, A.L.N., Jailani, M.H.H., Hasnan, M.M.I.M. (2023). Thermoelectric Properties of Β-FeSi2 Thermoelectric Module Utilizing Cast-Iron Scrap Chips. In: Maleque, M.A., Ahmad Azhar, A.Z., Sarifuddin, N., Syed Shaharuddin, S.I., Mohd Ali, A., Abdul Halim, N.F.H. (eds) Proceeding of 5th International Conference on Advances in Manufacturing and Materials Engineering. Lecture Notes in Mechanical Engineering. Springer, Singapore. https://doi.org/10.1007/978-981-19-9509-5_85

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  • DOI: https://doi.org/10.1007/978-981-19-9509-5_85

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  • Publisher Name: Springer, Singapore

  • Print ISBN: 978-981-19-9508-8

  • Online ISBN: 978-981-19-9509-5

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