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Abstract

Today, there is a huge necessity to replace petrochemical-derived products by its biobased counterparts, being biomass a renewable alternative for sustainable goods production. Among different potential possibilities, the production of renewable chemical precursors has great interest at global scale. Especially, biomass-derived sugar-based platforms can provide widely employed renewable chemical precursors, such as organic acids, which are useful for obtaining many different industrial products: plastics, biofuels, surfactants, coatings, etc. These new bioproducts could promote the transition of the actual fuel-based economy to a new biobased economy. This chapter summarizes the knowledge in the fractionation of biomass polysaccharides, especially cellulose and hemicellulose, and reviews the procedures employed for the production of organic acids from these biomass polymers. Furthermore, the global value of the most commonly employed organic acids is summarized.

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Abbreviations

2-FA:

2-Furaldehyde

AGR:

Annual growth rate

AMIMCl:

1-Allyl-3-methylimidazolium chloride

BMIMCl:

1-Butyl-3-methylimidazolium chloride

[C4mim]Cl:

1-Butyl-3-methylimidazolium chloride

CAGR:

Compound annual growth rate

DMF:

2,5-Dimethylfuran

DPA:

Diphenolic acid

[DPDIm]I:

1,3-Dipropyl-2-(2-propoxyphenyl)-4,5-diphenylimidazolium iodide

FA:

Formic acid

GVL:

γ-Valerolactone

HAc:

Acetic acid

HMF:

Hydroxymethyl furfural

ILs:

Ionic liquids

LA:

Lactic acid

LEA:

Levulinic acid

MD-CIB:

Mechanocatalytically depolymerized citric acid impregnated biomass

PA:

Propionic acid

PLA:

Polylactic acid

PVA:

Polyvinyl acetate

PVC:

Polyvinyl chloride

PVOH:

Polyvinyl alcohol

SA:

Succinic acid

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Acknowledgments

The authors would like to thank the European project “BIODEST” financed by Marie Skłodowska-Curie Actions (RISE-2017 Call).

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Correspondence to Itziar Egüés .

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© 2023 The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.

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Dávila, I., Martín, A., Egüés, I. (2023). Biomass Polysaccharides to Building Blocks: Obtaining Renewable Organic Acids. In: Pathak, P.D., Mandavgane, S.A. (eds) Biorefinery: A Sustainable Approach for the Production of Biomaterials, Biochemicals and Biofuels. Springer, Singapore. https://doi.org/10.1007/978-981-19-7481-6_2

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