Abstract
Carbon dots, an advancing group of zero-dimensional quasi-spherical nanocarbon particles, have received great recognition in the scientific world during recent years. This promising nanomaterial with exceptional features is widely explored in various aspects owing to their excellent optical, structural, and physicochemical properties. Many facile and cost-effective synthetic methodologies such as hydrothermal treatment, microwave pyrolysis, and arc discharge method can be implemented for fabricating these carbon dots. Synthetic methodologies as well as precursor materials determine the applicability, and the use of biomass as a precursor is discussed in detail. They possess superior properties such as tunable photoluminescence, easy functionalization, high crystallization, excellent biocompatibility, and good disperse ability. Functional properties can be enhanced by chemical modification as well as doping on the surface. These multifunctional materials and their nanocomposites find potential applications in the areas of photocatalysis, bioimaging, and sensing. The challenges and future scope of carbon dots in the scientific realm are also discussed in this chapter.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Sun YP et al (2006) Quantum-sized carbon dots for bright and colorful photoluminescence. J Am Chem Soc 128(24):7756–7757
Xu X et al (2004) Electrophoretic analysis and purification of fluorescent single-walled carbon nanotube fragments. J Am Chem Soc 126(40):12736–12737
Fernando KAS et al (2015) Carbon quantum dots and applications in photocatalytic energy conversion. ACS Appl Mater Interfaces 7(16):8363–8376
Lu KQ, Quan Q, Zhang N, Xu YJ (2016) Multifarious roles of carbon quantum dots in heterogeneous photocatalysis. J Energy Chem 25(6):927–935
Shen LM, Liu J (2016) New development in carbon quantum dots technical applications. Talanta 156–157:245–256
Shen J, Zhu Y, Yang X, Li C (2012) Graphene quantum dots: emergent nanolights for bioimaging, sensors, catalysis and photovoltaic devices. Chem Commun 48(31):3686–3699
Wang D et al (2017) Facile and scalable preparation of fluorescent carbon dots for multifunctional applications. Engineering 3(3):402–408
Wang R, Wang X, Sun Y (2017) One-step synthesis of self-doped carbon dots with highly photoluminescence as multifunctional biosensors for detection of iron ions and pH. Sensors Actuators B Chem 241:73–79
Ridha AA, Pakravan P, Azandaryani AH, Zhaleh H (2020) Carbon dots; the smallest photoresponsive structure of carbon in advanced drug targeting. J Drug Deliv Sci Technol 55:101408
Hola K et al (2014) Carbon dots—emerging light emitters for bioimaging, cancer therapy and optoelectronics. Nano Today 9:590–603
Tuerhong M, Xu Y, Yin XB (2017) Review on carbon dots and their applications. Chinese J Anal Chem 45:139–150
Zheng L et al (2009) Electrochemiluminescence of water-soluble carbon nanocrystals released electrochemically from graphite. J Am Chem Soc 131:4564–4565
Peng J, Gao W, Gupta BK et al (2012) Graphene quantum dots derived from carbon fibers. Nano Lett 12:844–849
Lin L, Zhang S (2012) Creating high yield water soluble luminescent graphene quantum dots via exfoliating and disintegrating carbon nanotubes and graphite flakes. Chem Commun 48:10177–10179
Hu C et al (2014) Chemically tailoring coal to fluorescent carbon dots with tuned size and their capacity for Cu(II) detection. Small 10:4926–4933
Xie R et al (2016) Graphene quantum dots as smart probes for biosensing. Anal Methods 8:4001–4016
Dong Y et al (2012) Blue luminescent graphene quantum dots and graphene oxide prepared by tuning the carbonization degree of citric acid. Carbon 50(12):4738–4743
Sahu S, Behera B, Maiti TK, Mohapatra S (2012) Simple one-step synthesis of highly luminescent carbon dots from orange juice: Application as excellent bio-imaging agents. Chem Commun 48:8835–8837
Ding H et al (2017) Facile synthesis of red-emitting carbon dots from pulp-free lemon juice for bioimaging. J Mater Chem B 5:5272–5277
Wang J, Wang CF, Chen S (2012) Amphiphilic egg-derived carbon dots: rapid plasma fabrication, pyrolysis process, and multicolor printing patterns. Angew Chemie Int Ed 51:9297–9301
Zhu H et al (2009) Microwave synthesis of fluorescent carbon nanoparticles with electrochemiluminescence properties. Chem Commun 34:5118–5120. https://doi.org/10.1039/B907612C
Yang Y et al (2011) One-step synthesis of amino-functionalized fluorescent carbon nanoparticles by hydrothermal carbonization of chitosan. Chem Commun 48:380–382
Sun X, Lei Y (2017) Fluorescent carbon dots and their sensing applications. TrAC Trends Anal Chem C 89:163–180
Shuaib EP et al (2019) Carbon nanoparticles synthesized by laser ablation of coconut shell charcoal in liquids for glucose sensing applications. Mater Res Express (6)11:115610
Xiao J, Liu P, Wang CX, Yang GW (2017) External field-assisted laser ablation in liquid: an efficient strategy for nanocrystal synthesis and nanostructure assembly. Prog Mater Sci 87:140–222
Yu H, Li X, Zeng X, Lu Y (2020) Preparation of carbon dots by non-focusing pulsed laser irradiation in toluene. Chem Commun 56:5194–5194
Xu ZQ et al (2014) Low temperature synthesis of highly stable phosphate functionalized two color carbon nanodots and their application in cell imaging. Carbon 66:351–360
Ventrella A, Camisasca A, Fontana A, Giordani S (2020) Synthesis of green fluorescent carbon dots from carbon nano-onions and graphene oxide. RSC Adv 10:36404–36412
Sun D et al (2013) Hair fiber as a precursor for synthesizing of sulfur- and nitrogen-co-doped carbon dots with tunable luminescence properties. Carbon 64:424–434
Bao L, Liu C, Zhang ZL, Pang DW (2015) Photoluminescence-tunable carbon nanodots: surface-state energy-gap tuning. Adv Mater 27:1663–1667
Hu Q et al (2014) Green synthesis of fluorescent nitrogen/sulfur-doped carbon dots and investigation of their properties by HPLC coupled with mass spectrometry. RSC Adv 4:18065–18073
Devi R, Vignesh Kumar TH, Sundramoorthy AK (2018) Electrochemically exfoliated carbon quantum dots modified electrodes for detection of dopamine neurotransmitter. J Electrochem Soc (165)12:G3112
Zhou J et al (2007) An electrochemical avenue to blue luminescent nanocrystals from multiwalled carbon nanotubes (MWCNTs). J Am Chem Soc 129(4):744–745
Liu M et al (2016) Carbon quantum dots directly generated from electrochemical oxidation of graphite electrodes in alkaline alcohols and the applications for specific ferric ion detection and cell imaging. Analyst 141:2657–2664
Bao L et al (2011) Electrochemical tuning of luminescent carbon nanodots: from preparation to luminescence mechanism. Adv Mater 23:5801–5806
Peng H, Travas-Sejdic J (2009) Simple aqueous solution route to luminescent carbogenic dots from carbohydrates. Chem Mater 21:5563–5565
Hou Y et al (2015) One-pot electrochemical synthesis of functionalized fluorescent carbon dots and their selective sensing for mercury ion. Anal Chim Acta 866:69–74
Wang F, Wang S, Sun Z, Zhu H (2015) Study on ultrasonic single-step synthesis and optical properties of nitrogen-doped carbon fluorescent quantum dots. Fuller Nanotub 23(9):769–776
Guo Y, Wang Z, Shao H, Jiang X (2013) Hydrothermal synthesis of highly fluorescent carbon nanoparticles from sodium citrate and their use for the detection of mercury ions. Carbon 52:583–589
Liu H et al (2014) A multifunctional ribonuclease A-conjugated carbon dot cluster nanosystem for synchronous cancer imaging and therapy. Nanoscale Res Lett 9:1–11
Dang H et al (2016) Large-scale ultrasonic fabrication of white fluorescent carbon dots. Ind Eng Chem Res 55:5335–5341
He C, Yan H, Li X, Wang X (2019) In situ fabrication of carbon dots-based lubricants using a facile ultrasonic approach. Green Chem 21:2279–2285
Yuan F et al (2016) Shining carbon dots: synthesis and biomedical and optoelectronic applications. Nano Today 11:565–586
Namdari P, Negahdari B, Eatemadi A (2017) Synthesis, properties and biomedical applications of carbon-based quantum dots: an updated review. Biomed Pharmacother 87:209–222
Wang J, Wei J, Su S, Qiu J (2014) Novel fluorescence resonance energy transfer optical sensors for vitamin B12 detection using thermally reduced carbon dots. New J Chem 39:501–507
Zhang B, Liu CY, Liu Y (2010) A novel one-step approach to synthesize fluorescent carbon nanoparticles. Eur J Inorg Chem 2010:4411–4414
Wang H et al (2016) High fluorescence S, N co-doped carbon dots as an ultra-sensitive fluorescent probe for the determination of uric acid. Talanta 155:62–69
Yang ZC et al (2011) Intrinsically fluorescent carbon dots with tunable emission derived from hydrothermal treatment of glucose in the presence of monopotassium phosphate. Chem Commun 47:11615–11617
Mehta VN et al (2015) One-step hydrothermal approach to fabricate carbon dots from apple juice for imaging of mycobacterium and fungal cells. Sensors Actuators B Chem 213:434–443
Wang L, Zhou HS (2014) Green synthesis of luminescent nitrogen-doped carbon dots from milk and its imaging application. Anal Chem 86:8902–8905
Shi J et al (2017) Green synthesis of fluorescent carbon dots for sensitive detection of Fe2+ and hydrogen peroxide. J Nanoparticle Res 19:209
Bhunia SK et al (2013) Carbon nanoparticle-based fluorescent bioimaging probes. Sci Rep 3:1473–1479
Han C et al (2016) Highly fluorescent carbon dots as selective and sensitive “on-off-on” probes for iron(III) ion and apoferritin detection and imaging in living cells. Biosens Bioelectron 83:229–236
Ding H et al (2019) Highly fluorescent near-infrared emitting carbon dots derived from lemon juice and its bioimaging application. J Lum 211:298–304
Jiang Y et al (2015) A fluorescence turn-off chemosensor based on N-doped carbon quantum dots for detection of Fe3+ in aqueous solution. Mater Lett C 141:366–368
Tang L et al (2012) Deep ultraviolet photoluminescence of water-soluble self-passivated graphene quantum dots. ACS Nano 6:5102–5110
Campos BB et al (2016) Carbon dots on based folic acid coated with PAMAM dendrimer as platform for Pt(IV) detection. J Colloid Interface Sci 465:165–173
Dai H et al (2014) A carbon dot based biosensor for melamine detection by fluorescence resonance energy transfer. Sensors Actuators, B Chem 202:201–208
Qu K, Wang J, Ren J, Qu X (2013) Carbon dots prepared by hydrothermal treatment of dopamine as an effective fluorescent sensing platform for the label-free detection of Iron(III) ions and dopamine. Chem A Eur J 19:7243–7249
Li Z et al (2015) Highly luminescent nitrogen-doped carbon quantum dots as effective fluorescent probes for mercuric and iodide ions. J Mater Chem C 3:1922–1928
Wang W et al (2014) Facile synthesis of water-soluble and biocompatible fluorescent nitrogen-doped carbon dots for cell imaging. Analyst 139:1692–1696
Zhu S, Meng Q et al (2013) Highly photoluminescent carbon dots for multicolor patterning, sensors, and bioimaging. Angew Chem Int Ed Engl 52:3953–3957
Li M et al (2018) Facile microwave assisted synthesis of N-rich carbon quantum dots/dual-phase TiO2 heterostructured nanocomposites with high activity in CO2 photoreduction. Appl Catal B 231:269–276
Wang Q et al (2014) Fluorescent carbon dots as an efficient siRNA nanocarrier for its interference therapy in gastric cancer cells. J Nanobiotechnology 12:1–12
El-Shabasy RM et al (2021) Recent developments in carbon quantum dots: properties, fabrication techniques, and bio-applications. Process 9:388
Zhao C, Li X, Cheng C, Yang Y (2019) Green and microwave-assisted synthesis of carbon dots and application for visual detection of cobalt(II) ions and pH sensing. Microchem J 147:183–190
Wang J, Qiu J (2016) A review of carbon dots in biological applications. J Mater Sci 51:4728–4738
Feng T et al (2016) Charge-convertible carbon dots for imaging-guided drug delivery with enhanced in vivo cancer therapeutic efficiency. ACS Nano 10:4410–4420
Dager A, Uchida T, Maekawa T, Tachibana M (2019) Synthesis and characterization of mono-disperse carbon quantum dots from fennel seeds: Photoluminescence analysis using machine learning. Sci Reports 9:1–12
Mehta VN, Jha S, Kailasa SK (2014) One-pot green synthesis of carbon dots by using Saccharum officinarum juice for fluorescent imaging of bacteria (Escherichia coli) and yeast (Saccharomyces cerevisiae) cells. Mater Sci Eng C Mater 38:20–27
Arumugam N, Kim J (2018) Synthesis of carbon quantum dots from Broccoli and their ability to detect silver ions. Mater Lett 219:37–40
Zhao S et al (2015) Green synthesis of bifunctional fluorescent carbon dots from garlic for cellular imaging and free radical scavenging. ACS Appl Mater Interfaces 7:17054–17060
Bano D, Kumar V, Singh VK, Hasan SH (2018) Green synthesis of fluorescent carbon quantum dots for the detection of mercury(II) and glutathione. New J Chem 42:5814–5821
Zhou J et al (2012) Facile synthesis of fluorescent carbon dots using watermelon peel as a carbon source. Mater Lett 66:222–224
Liu W et al (2017) Green synthesis of carbon dots from rose-heart radish and application for Fe3+ detection and cell imaging. Sensors Actuators B Chem 241:190–198
Gedda G, Lee CY, Lin YC, Wu HF (2016) Green synthesis of carbon dots from prawn shells for highly selective and sensitive detection of copper ions. Sensors Actuators B Chem 224:396–403
Liang Q et al (2013) Easy synthesis of highly fluorescent carbon quantum dots from gelatin and their luminescent properties and applications. Carbon 60:421–428
Yang X et al (2014) Novel and green synthesis of high-fluorescent carbon dots originated from honey for sensing and imaging. Biosens Bioelectron 60:292–298
Kumar A et al (2017) Green synthesis of carbon dots from Ocimum sanctum for effective fluorescent sensing of Pb2+ ions and live cell imaging. Sensors Actuators B Chem 242:679–686
Thambiraj S, Shankaran DR (2016) Green synthesis of highly fluorescent carbon quantum dots from sugarcane bagasse pulp. Appl Surf Sci 390:435–443
Sun X et al (2017) Green synthesis of carbon dots originated from Lycii Fructus for effective fluorescent sensing of ferric ion and multicolor cell imaging. J Photochem Photobiol B Biol 175:219–225
Xu H et al (2015) Green synthesis of fluorescent carbon dots for selective detection of tartrazine in food samples. J Agric Food Chem 63:6707–6714
Du W et al (2015) Green synthesis of fluorescent carbon quantum dots and carbon spheres from pericarp. Sci China Chem 58:863–870
Shen J et al (2017) Facile synthesis of fluorescence carbon dots from sweet potato for Fe3+ sensing and cell imaging. Mater Sci Eng C Mater Biol Appl 76:856–864
Gu D, Shang S, Yu Q, Shen J (2016) Green synthesis of nitrogen-doped carbon dots from lotus root for Hg(II) ions detection and cell imaging. Appl Surf Sci 390:38–42
Roy P et al (2015) Photoluminescent carbon nanodots: synthesis, physicochemical properties and analytical applications. Mater Today 18:447–458
Zhang J et al (2015) Scale-up synthesis of fragrant nitrogen-doped carbon dots from bee pollens for bioimaging and catalysis. Adv Sci (4)2:1500002
Liu S et al (2012) Hydrothermal treatment of grass: a low-cost, green route to nitrogen-doped, carbon-rich, photoluminescent polymer nanodots as an effective fluorescent sensing platform for label-free detection of Cu(II) ions. Adv Mater 24:2037–2041
Lu W et al (2012) Economical, green synthesis of fluorescent carbon nanoparticles and their use as probes for sensitive and selective detection of mercury(II) ions. Anal Chem 84:5351–5357
Yang S et al (2014) Large-scale fabrication of heavy doped carbon quantum dots with tunable-photoluminescence and sensitive fluorescence detection. J Mater Chem A 2:8660–8667
Fan Z et al (2014) Surrounding media sensitive photoluminescence of boron-doped graphene quantum dots for highly fluorescent dyed crystals, chemical sensing and bioimaging. Carbon 70:149–156
Tan Q et al (2019) Crystallization of zinc oxide quantum dots on graphene sheets as an anode material for lithium ion batteries. Cryst Eng Comm 22:320–329
Iravani S, Varma RS (2020) Green synthesis, biomedical and biotechnological applications of carbon and graphene quantum dots. A review. Environ Chem Lett 18:703–727
Gu C et al (2019) Bimetallic ZrHf-based metal-organic framework embedded with carbon dots: ultra-sensitive platform for early diagnosis of HER2 and HER2-overexpressed living cancer cells. Biosens Bioelectron 134:8–15
Xie Z et al (2018) Construction of carbon dots modified MoO3/g-C3N4 Z-scheme photocatalyst with enhanced visible-light photocatalytic activity for the degradation of tetracycline. Appl Catal B Environ 229:96–104
Pan L et al (2016) Near-infrared emissive carbon dots for two-photon fluorescence bioimaging. Nanoscale 8:17350–17356
Sun Z, Luo Q, Ran W (2015) Preparation and characterization of amine modified carbon quantum dots from mesoporous carbon. 383–386
Xie YF et al (2019) Metal-mediated gold nanospheres assembled for dark-field microscopy imaging scatterometry. Talanta 201:280–285
Wang J, Gao M, Ho GW (2014) Bidentate-complex-derived TiO2/carbon dot photocatalysts: in situ synthesis, versatile heterostructures, and enhanced H2 evolution. J Mater Chem A 2:5703–5709
Guo F et al (2017) Fabrication of a CuBi2O4/g-C3N4 p–n heterojunction with enhanced visible light photocatalytic efficiency toward tetracycline degradation. Inorg Chem Front 4:1714–1720
Ni T et al (2020) N, Fe-doped carbon dot decorated gear-shaped WO3 for highly efficient UV-Vis-NIR-driven photocatalytic performance. Catal 10:416
Liu R et al (2014) Metal nanoparticle/carbon quantum dot composite as a photocatalyst for high-efficiency cyclohexane oxidation. ACS Catal 4:328–336
Han Y et al (2014) Carbon quantum dots with photoenhanced hydrogen-bond catalytic activity in aldol condensations. ACS Catal 4:781–787
Han X et al (2013) Synthesis of carbon quantum dots/SiO2 porous nanocomposites and their catalytic ability for photo-enhanced hydrocarbon selective oxidation. Dalt Trans 42:10380–10383
Wang B et al (2018) Synthesis of catalytically active multielement-doped carbon dots and application for colorimetric detection of glucose. Sens Actuators B Chem 255:2601–2607
Du J et al (2017) Difunctional Cu-doped carbon dots: catalytic activity and fluorescence indication for the reduction reaction of p-nitrophenol. RSC Adv 7:33929–33936
Hu S et al (2016) A facile and green method towards coal-based fluorescent carbon dots with photocatalytic activity. Appl Surf Sci 378:402–407
Wen X et al (2021) Carbon dots for specific “off-on” sensing of Co2+ and EDTA for in vivo bioimaging. Mater Sci Eng C 123:112022
Ding H, Yu SB, Wei JS, Xiong HM (2016) Full-color light-emitting carbon dots with a surface-state-controlled luminescence mechanism. ACS Nano 10:484–491
Cao L et al (2007) Carbon dots for multiphoton bioimaging. J Am Chem Soc 129:11318–11319
Conflicts of Interest
The authors have declared no conflicts of interest.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2023 The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.
About this chapter
Cite this chapter
Paul, A., Mohan, A. (2023). Photoluminescent Carbon Dots: A New Generation Nanocarbon Material. In: Grace, A.N., Sonar, P., Bhardwaj, P., Chakravorty, A. (eds) Handbook of Porous Carbon Materials. Materials Horizons: From Nature to Nanomaterials. Springer, Singapore. https://doi.org/10.1007/978-981-19-7188-4_9
Download citation
DOI: https://doi.org/10.1007/978-981-19-7188-4_9
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-19-7187-7
Online ISBN: 978-981-19-7188-4
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)