Abstract
In this chapter, the solar-thermal energy conversion system is investigated with a particular focus on the characterization of raw materials and the feasibility of the thermal driving system. Lithium orthosilicate (Li4SiO4) was selected as a suitable material for storing thermal energy at approximately 700 °C, and advanced pelletizing methods were proposed for practical applications. Additionally, special lithium orthosilicate-packed bed reactors (LPRs) and zeolite-packed bed reactors (ZPRs) were designed and developed for thermal driving demonstrations at the laboratory scale. The developed Li4SiO4 tablet (K-tablet) with a thermal driving demonstration system showed sufficient potential to be considered for the solar-thermal energy conversion system instead of the existing thermal energy storage (TES) methods.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Nevau P, Castaing J (1993) Solid–gas chemical heat pumps: fields of application and performance of the internal heat of reaction recovery process. Heat Recov Syst CHP 13(3):233–251
Goetz V, Elie F, Spinner B (1993) The structure and performance of single effect solid/gas chemical heat pumps. Heat Recov Syst CHP 13(1):79–96
Li TX, Wang RZ, Kiplagat JK, Chen H, Wang LW (2011) A new target-oriented methodology of decreasing the regeneration temperature of solid–gas thermochemical sorption refrigeration system driven by low-grade thermal energy. Int J Heat Mass Tran 54(21–22):4719–4729
Li TX, Wang RZ, Kiplagat JK, Wang LW (2009) Performance study of a consolidated manganese chloride-expanded graphite compound for sorption deep-freezing processes. Appl Energ 86(7–8):1201–1209
Bao HS, Wang RZ, Wang LW (2011) A resorption refrigerator driven by low grade thermal energy. Energ Convers Manage 52(6):2339–2344
Xu J, Oliveira RG, Wang RZ (2011) Resorption system with simultaneous heat and cold production. Int J Refrig 34(5):1262–1267
Oliveira RG, Wang RZ (2007) A consolidated calcium chloride-expanded graphite compound for use in sorption refrigeration systems. Carbon 45(2):390–396
N’Tsoukpoe KE, Schmidt T, Rammelberg HU, Watts BA, Ruck WKL (2014) A systematic multi-step screening of numerous salt hydrates for low temperature thermochemical energy storage. Appl Energ 124:1–16
Linder M, Mertz R, Laurien E (2010) Experimental results of a compact thermally driven cooling system based on metal hydrides. Int J Hydrogen Energ 35(14):7623–7632
Kato Y, Sasaki Y, Yoshizawa Y (2005) Magnesium oxide/water chemicals heat pump to enhance energy utilization of a cogeneration system. Energy 30(11–12):2144–2155
Ogura H, Ishida H, Yokooji R, Kage H, Matsuno Y, Mujumdar AS (2001) Experimental studies on a novel chemical heat pump dryer using a solid–gas reaction. Dry Technol 19(7):1461–1477
Kato Y, Yamada M, Kanie T, Yoshizawa Y (2011) Calcium oxide/carbon dioxide reactivity in a packed bed reactor of a chemicals heat pump for high temperature gas reactors. Nucl Eng Des 210(1–3):1–8
HSC Chemistry ver. 7.0 (2011) Outotec, Finland
Nakagawa K, Ohashi T (1998) A novel method of CO2 capture from high temperature gases. J Electrochem Soc 145(4):1344–1346
Kato M, Nakagawa K (2001) New series of lithium containing complex oxides, lithium silicates, for application as a high temperature CO2 absorbent. J Ceram Soc Jpn 109(1275):911–914
Barin I, Platzki G (1995) Thermochemical data of pure substances, 3rd edn. Wiley, New York
Takasu H, Ryu J, Kato Y (2017) Application of lithium orthosilicate for high-temperature thermochemical energy storage. Appl Energ 193:74–83
Kim ST, Ryu J, Kato Y (2011) Reactivity enhancement of chemical materials used in packed bed reactor of chemical heat pump. Prog Nucl Energ 53(7):1027–1033
Kousksou T, Bruel P, Jamil A, Rhafiki TE, Zeraouli Y (2014) Energy storage: application and challenges. Sol Energ Mat Sol C 120:59–80
Seggiani M, Puccini M, Vitolo S (2013) Alkali promoted lithium orthosilicate for CO2 capture at high temperature and low concentration. Int J Greenh Gas Con 17:25–31
Wang S, An C, Zhang QH (2013) Syntheses and structures of lithium zirconates for high-temperature CO2 absorption. J Mater Chem A 11:3540–3550
Toshiba Corporation (2005) Carbonic acid gas absorbent, and method and apparatus for separating carbonic acid gas. Japan Patent 2005075139, 16 Mar 2005
Puccini M, Seggiani M, Vitolo S (2013) Lithium silicate pellets for CO2 capture at high temperature. Chem Engineer Trans 35:373–378
Nair BN, Yamaguchi T, Kawamura H, Nakao SI, Nakagawa K (2004) Processing of lithium zirconate for applications in carbon dioxide separations: structure and properties of the powders. J Am Ceram Soc 87(1):68–74
Olivares-Marin M, Castro-Diaz M, Drage TC, Maroto-Valer MM (2010) Use of small-amplitude oscillatory shear rheometry to study the flow properties of pure and potassium-doped Li2ZrO3 sorbents during the sorption of CO2 at high temperatures. Sep Purif Technol 73(3):415–420
Pfeiffer H, Vazquez C, Lara VH, Bosch P (2007) Thermal behavior and CO2 absorption of Li2−xNaxZrO3 solid solutions. Chem Mater 19:922–926
Ida J, Lin YS (2003) Mechanism of high temperature CO2 sorption on lithium zirconate. Environ Sci Technol 37:1999–2004
Wang Q, Luo J, Zhong Z, Borgna A (2011) CO2 capture by solid adsorbents and their applications: current status and new trends. Energy Environ Sci 4:42–55
Ochoa-Fernandez E, Ronning M, Yu X, Grande T, Chen D (2008) Composition effects of nanocrystalline lithium zirconate on its CO2 capture properties. Ind Eng Chem Res 47:434–442
Kim ST, Nihei T, Kurahashi C, Hoshino H, Takasu H, Kato Y (2019) Kinetic study of lithium orthosilicate pellets for high-temperature chemical heat pumps. Energ Storage 1(4):e72
N’Tsoukpoe KE, Liu H, Pierres NL, Luo L (2009) A review on long-term sorption solar energy storage. Renew Sust Energ Rev 13(9):2385–2396
Kim ST, Kurahashi C, Hoshino H, Takahashi C, Tamura Y, Takasu H, Saito S, Kurihara M, Kato Y (2019) Thermal driving demonstration of Li4SiO4/CO2/Zeolite thermochemical energy storage system for efficient high-temperature heat utilizations. ISIJ Int 59(4):721–726
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2023 The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.
About this chapter
Cite this chapter
Kim, S.T., Takasu, H., Kato, Y. (2023). Solar-Thermal Energy Conversion System: Design and Practice. In: Aika, Ki., Kobayashi, H. (eds) CO2 Free Ammonia as an Energy Carrier. Springer, Singapore. https://doi.org/10.1007/978-981-19-4767-4_8
Download citation
DOI: https://doi.org/10.1007/978-981-19-4767-4_8
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-19-4766-7
Online ISBN: 978-981-19-4767-4
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)