Abstract
Treatment of dye wastewaters is important to recover and reuse the water in order to mitigate the impending freshwater crisis precipitated by a growing population, industrialization and declining freshwater reserves. Photocatalysis is very effective in complete mineralization of the different pollutants present, but the complex design, construction and scale-up of photocatalytic reactors for industrial-scale applications is still an open problem. Among the different configurations of reactors studied, the work on multiphase photocatalytic reactors is comparatively less. In this chapter, after a brief look at the basic fundamentals, a comprehensive review of the different multiphase photocatalytic reactors is presented with the aim of showing why this type could be a better option for the degradation of toxic dyes. The important operational parameters are discussed followed by an overview of the issues encountered in scale-up. Finally, the future aspects concerning the use of multiphase reactors for photocatalytic treatment of dye wastewaters are given.
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References
Angel J, Loftus A (2019) With-against-and-beyond the human right to water. Geoforum 98:206–213. https://doi.org/10.1016/j.geoforum.2017.05.002
Zhao F, Zhou X, Liu Y et al (2019) Super Moisture-absorbent gels for all-weather atmospheric water harvesting. Adv Mater 31:1806446. https://doi.org/10.1002/adma.201806446
Zhang Q, Xu P, Qian H (2020) Groundwater quality assessment using improved Water Quality Index (WQI) and Human Health Risk (HHR) evaluation in a semi-arid region of Northwest China. Expo Heal 12:487–500. https://doi.org/10.1007/s12403-020-00345-w
Zhang Z, Shi M, Chen KZ et al (2021) Water scarcity will constrain the formation of a world-class megalopolis in North China. npj Urban Sustain 1:13. https://doi.org/10.1038/s42949-020-00012-8
Griffiths JK (2017) Waterborne diseases. In: International encyclopedia of public health. Elsevier, pp 388–401
Lellis B, Fávaro-Polonio CZ, Pamphile JA, Polonio JC (2019) Effects of textile dyes on health and the environment and bioremediation potential of living organisms. Biotechnol Res Innov 3:275–290. https://doi.org/10.1016/j.biori.2019.09.001
Han Y, Li H, Liu M et al (2016) Purification treatment of dyes wastewater with a novel micro-electrolysis reactor. Sep Purif Technol 170:241–247. https://doi.org/10.1016/j.seppur.2016.06.058
Rodriguez Couto S, Rodriguez A, Paterson RRM et al (2006) Laccase activity from the fungus Trametes hirsuta using an air-lift bioreactor. Lett Appl Microbiol 060316073800005. https://doi.org/10.1111/j.1472-765X.2006.01879.x
Sridewi N, Lee Y-F, Sudesh K (2011) Simultaneous adsorption and photocatalytic degradation of malachite green using electrospun P(3HB)-TiO2 nanocomposite fibers and films. Int J Photoenergy 2011:1–11. https://doi.org/10.1155/2011/597854
Jo W-K, Park GT, Tayade RJ (2015) Synergetic effect of adsorption on degradation of malachite green dye under blue LED irradiation using spiral-shaped photocatalytic reactor. J Chem Technol Biotechnol 90:2280–2289. https://doi.org/10.1002/jctb.4547
Selvakumar S, Manivasagan R, Chinnappan K (2013) Biodegradation and decolourization of textile dye wastewater using Ganoderma lucidum. 3 Biotech 3:71–79. https://doi.org/10.1007/s13205-012-0073-5
Rajeshwar K, Osugi ME, Chanmanee W et al (2008) Heterogeneous photocatalytic treatment of organic dyes in air and aqueous media. J Photochem Photobiol C Photochem Rev 9:171–192. https://doi.org/10.1016/j.jphotochemrev.2008.09.001
Asghar A, Ramzan N, Jamal BU et al (2020) Low frequency ultrasonic‐assisted Fenton oxidation of textile wastewater: process optimization and electrical energy evaluation. Water Environ J 34:523–535. https://doi.org/10.1111/wej.12482
Patil S (2019) Synthesis and optical properties of Near-Infrared (NIR) absorbing azo dyes. Curr Trends Fash Technol Text Eng 4. https://doi.org/10.19080/CTFTTE.2019.04.555649
Gregory P (2003) Metal complexes as speciality dyes and pigments. In: Comprehensive coordination chemistry II. Elsevier, pp 549–579
Marchis T, Avetta P, Bianco-Prevot A et al (2011) Oxidative degradation of Remazol Turquoise Blue G 133 by soybean peroxidase. J Inorg Biochem 105:321–327. https://doi.org/10.1016/j.jinorgbio.2010.11.009
Riaz M, Ijaz B, Riaz A, Amjad M (2018) Improvement of waste water quality by application of mixed algal inocula. Bangladesh J Sci Ind Res 53:77–82. https://doi.org/10.3329/bjsir.v53i1.35913
Javaid R, Qazi UY (2019) Catalytic oxidation process for the degradation of synthetic dyes: an overview. Int J Environ Res Public Health 16:2066. https://doi.org/10.3390/ijerph16112066
Hussain SN, Asghar HMA, Sattar H et al (2015) Free chlorine formation during electrochemical regeneration of a graphite intercalation compound adsorbent used for wastewater treatment. J Appl Electrochem 45:611–621. https://doi.org/10.1007/s10800-015-0814-3
Pagga U, Brown D (1986) The degradation of dyestuffs: Part II behaviour of dyestuffs in aerobic biodegradation tests. Chemosphere 15:479–491. https://doi.org/10.1016/0045-6535(86)90542-4
Pang YL, Abdullah AZ (2013) Current status of textile industry wastewater management and research progress in Malaysia: a review. Clean Soil Air Water 41:751–764. https://doi.org/10.1002/clen.201000318
Senthil Kumar P, Saravanan A (2017) Sustainable wastewater treatments in textile sector. In: Sustainable fibres and textiles. Elsevier, pp 323–346
Shang N-C, Chen Y-H, Yang Y-P et al (2006) Ozonation of dyes and textile wastewater in a rotating packed bed. J Environ Sci Heal Part A 41:2299–2310. https://doi.org/10.1080/10934520600873043
Vacchi FI, Albuquerque AF, Vendemiatti JA et al (2013) Chlorine disinfection of dye wastewater: implications for a commercial azo dye mixture. Sci Total Environ 442:302–309. https://doi.org/10.1016/j.scitotenv.2012.10.019
Abid MF, Zablouk MA, Abid-Alameer AM (2012) Experimental study of dye removal from industrial wastewater by membrane technologies of reverse osmosis and nanofiltration. Iranian J Environ Health Sci Eng 9:17. https://doi.org/10.1186/1735-2746-9-17
Hassan MM, Carr CM (2018) A critical review on recent advancements of the removal of reactive dyes from dyehouse effluent by ion-exchange adsorbents. Chemosphere 209:201–219. https://doi.org/10.1016/j.chemosphere.2018.06.043
Jiang M, Ye K, Deng J et al (2018) Conventional ultrafiltration as effective strategy for dye/salt fractionation in textile wastewater treatment. Environ Sci Technol 52:10698–10708. https://doi.org/10.1021/acs.est.8b02984
Kandisa RV, Saibaba KV N (2016) Dye removal by adsorption: a review. J Bioremediation Biodegrad 07. https://doi.org/10.4172/2155-6199.1000371
Buthiyappan A, Abdul Aziz AR, Wan Daud WMA (2016) Recent advances and prospects of catalytic advanced oxidation process in treating textile effluents. Rev Chem Eng 32:1–47. https://doi.org/10.1515/revce-2015-0034
Arslan İ, Akmehmet Balcioǧlu I, Tuhkanen T (1999) Oxidative treatment of simulated dyehouse effluent by UV and near-UV light assisted Fenton’s reagent. Chemosphere 39:2767–2783. https://doi.org/10.1016/S0045-6535(99)00211-8
Ghaly MY, Farah JY, Fathy AM (2007) Enhancement of decolorization rate and COD removal from dyes containing wastewater by the addition of hydrogen peroxide under solar photocatalytic oxidation. Desalination 217:74–84. https://doi.org/10.1016/j.desal.2007.01.013
Sarto S, Paesal P, Tanyong IB et al (2019) Catalytic degradation of textile wastewater effluent by peroxide oxidation assisted by UV light irradiation. Catalysts 9:509. https://doi.org/10.3390/catal9060509
Al-Mamun MR, Kader S, Islam MS, Khan MZH (2019) Photocatalytic activity improvement and application of UV-TiO2 photocatalysis in textile wastewater treatment: a review. J Environ Chem Eng 7:103248. https://doi.org/10.1016/j.jece.2019.103248
Chimupala Y, Phromma C, Yimklan S et al (2020) Dye wastewater treatment enabled by piezo-enhanced photocatalysis of single-component ZnO nanoparticles. RSC Adv 10:28567–28575. https://doi.org/10.1039/D0RA04746E
Singh S, Mahalingam H, Singh PK (2013) Polymer-supported titanium dioxide photocatalysts for environmental remediation: a review. Appl Catal A Gen 462–463:178–195. https://doi.org/10.1016/j.apcata.2013.04.039
Zhang J, Tian B, Wang L et al (2018) Mechanism of photocatalysis, pp 1–15
Ashar A, Bhatti IA, Ashraf M et al (2020) Fe3+ @ ZnO/polyester based solar photocatalytic membrane reactor for abatement of RB5 dye. J Clean Prod 246:119010. https://doi.org/10.1016/j.jclepro.2019.119010
Pelizzetti E, Serpone N (eds) (1986) Homogeneous and heterogeneous photocatalysis. Springer, Netherlands, Dordrecht
Loddo V, Bellardita M, Camera-Roda G et al (2018) Heterogeneous photocatalysis. In: Current trends and future developments on (bio-) membranes. Elsevier, pp 1–43
Tan HL, Abdi FF, Ng YH (2019) Heterogeneous photocatalysts: an overview of classic and modern approaches for optical, electronic, and charge dynamics evaluation. Chem Soc Rev 48:1255–1271. https://doi.org/10.1039/C8CS00882E
Vaiano V, Sannino D, Sacco O (2020) Heterogeneous photocatalysis. In: Nanomaterials for the detection and removal of wastewater pollutants. Elsevier, pp 285–301
Nakata K, Fujishima A (2012) TiO2 photocatalysis: design and applications. J Photochem Photobiol C Photochem Rev 13:169–189. https://doi.org/10.1016/j.jphotochemrev.2012.06.001
Saeed K, Khan I, Gul T, Sadiq M (2017) Efficient photodegradation of methyl violet dye using TiO2/Pt and TiO2/Pd photocatalysts. Appl Water Sci 7:3841–3848. https://doi.org/10.1007/s13201-017-0535-3
Tran Thi Thuong H, Tran Thi Kim C, Nguyen Quang L, Kosslick H (2019) Highly active brookite TiO2-assisted photocatalytic degradation of dyes under the simulated solar−UVA radiation. Prog Nat Sci Mater Int 29:641–647. https://doi.org/10.1016/j.pnsc.2019.10.001
Molinari R, Lavorato C, Argurio P (2020) Visible-light photocatalysts and their perspectives for building photocatalytic membrane reactors for various liquid phase chemical conversions. Catalysts 10:1334. https://doi.org/10.3390/catal10111334
Ohtani B (2011) Photocatalysis by inorganic solid materials, pp 395–430
Cates EL (2017) Photocatalytic water treatment: so where are we going with this? Environ Sci Technol 51:757–758. https://doi.org/10.1021/acs.est.6b06035
Chong MN, Jin B, Chow CWKK, Saint C (2010) Recent developments in photocatalytic water treatment technology: a review. Water Res 44:2997–3027. https://doi.org/10.1016/j.watres.2010.02.039
Ahmed SN, Haider W (2018) Heterogeneous photocatalysis and its potential applications in water and wastewater treatment: a review. Nanotechnology 29:342001. https://doi.org/10.1088/1361-6528/aac6ea
Yashni G, Al-Gheethi A, Mohamed R, Al-Sahari M (2021) Reusability performance of green zinc oxide nanoparticles for photocatalysis of bathroom greywater. Water Pract Technol 16:364–376. https://doi.org/10.2166/wpt.2020.118
Zhou L, Zhang H, Sun H et al (2016) Recent advances in non-metal modification of graphitic carbon nitride for photocatalysis: a historic review. Catal Sci Technol 6:7002–7023. https://doi.org/10.1039/C6CY01195K
Serpone N (1997) Relative photonic efficiencies and quantum yields in heterogeneous photocatalysis. J Photochem Photobiol A Chem 104:1–12. https://doi.org/10.1016/S1010-6030(96)04538-8
Krishna R, Sie ST (1994) Strategies for multiphase reactor selection. Chem Eng Sci 49:4029–4065. https://doi.org/10.1016/S0009-2509(05)80005-3
Peschel A, Hentschel B, Freund H, Sundmacher K (2012) Design of optimal multiphase reactors exemplified on the hydroformylation of long chain alkenes. Chem Eng J 188:126–141. https://doi.org/10.1016/j.cej.2012.01.123
Pangarkar VG (2014) Multiphase reactors. Design of multiphase reactors. Wiley, Hoboken, NJ, pp 47–86
Alalm MG, Djellabi R, Meroni D et al (2021) Toward scaling-up photocatalytic process for multiphase environmental applications. Catalysts 11:562. https://doi.org/10.3390/catal11050562
Teekateerawej S, Nishino J, Nosaka Y (2006) TiO2 photocatalytic micro-channel reactors using capillary plates. Adv Mater Res 11–12:303–306. https://doi.org/10.4028/www.scientific.net/AMR.11-12.303
Das S, Mahalingam H (2019) Exploring the synergistic interactions of TiO2, rGO, and g-C3N4 catalyst admixtures in a polystyrene nanocomposite photocatalytic film for wastewater treatment: unary, binary and ternary systems. J Environ Chem Eng 7. https://doi.org/10.1016/j.jece.2019.103246
Liu L, Liu Z, Bai H, Sun DD (2012) Concurrent filtration and solar photocatalytic disinfection/degradation using high-performance Ag/TiO2 nanofiber membrane. Water Res 46:1101–1112. https://doi.org/10.1016/j.watres.2011.12.009
Miranda-Garcia N, Suarez S, Sanchez B et al (2011) Photocatalytic degradation of emerging contaminants in municipal wastewater treatment plant effluents using immobilized TiO2 in a solar pilot plant. Appl Catal B Environ 103:294–301. https://doi.org/10.1016/j.apcatb.2011.01.030
Ehrampoush MH, Moussavi GR, Ghaneian MT et al (2011) Removal of methylene blue dye from textile simulated sample using tubular reactor and TiO2/UV-C photocatalytic process. Iran J Environ Heal Sci Eng 8:35–40
Rao NN, Chaturvedi V, Li Puma G (2012) Novel pebble bed photocatalytic reactor for solar treatment of textile wastewater. Chem Eng J 184:90–97. https://doi.org/10.1016/j.cej.2012.01.004
Baghbani Ghatar S, Allahyari S, Rahemi N, Tasbihi M (2018) Response surface methodology optimization for photodegradation of methylene blue in a ZnO coated flat plate continuous photoreactor. Int J Chem React Eng 16. https://doi.org/10.1515/ijcre-2017-0221
Sutisna RM, Wibowo E et al (2017) Novel solar photocatalytic reactor for wastewater treatment. IOP Conf Ser Mater Sci Eng 214:012010. https://doi.org/10.1088/1757-899X/214/1/012010
Sacco O, Sannino D, Vaiano V (2019) Packed bed photoreactor for the removal of water pollutants using visible light emitting diodes. Appl Sci 9:472. https://doi.org/10.3390/app9030472
Li F, Szeto W, Huang H et al (2017) A Photocatalytic rotating disc reactor with TiO2 nanowire arrays deposited for industrial wastewater treatment. Molecules 22:337. https://doi.org/10.3390/molecules22020337
Zhang Z, Wu H, Yuan Y et al (2012) Development of a novel capillary array photocatalytic reactor and application for degradation of azo dye. Chem Eng J 184:9–15. https://doi.org/10.1016/j.cej.2011.02.057
Vaiano V, Sacco O, Pisano D et al (2015) From the design to the development of a continuous fixed bed photoreactor for photocatalytic degradation of organic pollutants in wastewater. Chem Eng Sci 137:152–160. https://doi.org/10.1016/j.ces.2015.06.023
Di Capua G, Femia N, Migliaro M et al (2017) Intensification of a flat-plate photocatalytic reactor performances by innovative visible light modulation techniques: A proof of concept. Chem Eng Process Process Intensif 118:117–123. https://doi.org/10.1016/j.cep.2017.05.004
Claes T, Dilissen A, Leblebici ME, Van Gerven T (2019) Translucent packed bed structures for high throughput photocatalytic reactors. Chem Eng J 361:725–735. https://doi.org/10.1016/j.cej.2018.12.107
Jiang H, Zhang G, Huang T et al (2010) Photocatalytic membrane reactor for degradation of acid red B wastewater. Chem Eng J 156:571–577. https://doi.org/10.1016/j.cej.2009.04.011
Sacco O, Vaiano V, Sannino D (2020) Main parameters influencing the design of photocatalytic reactors for wastewater treatment: a mini review. J Chem Technol Biotechnol jctb.6488. https://doi.org/10.1002/jctb.6488
Braham RJ, Harris AT (2009) Review of Major Design and scale-up considerations for solar photocatalytic reactors. Ind Eng Chem Res 48:8890–8905. https://doi.org/10.1021/ie900859z
Lindstrom H, Wootton R, Iles A (2007) High surface area titania photocatalytic microfluidic reactors. AIChE J 53:695–702. https://doi.org/10.1002/aic.11096
Regmi C, Lotfi S, Espíndola JC et al (2020) Comparison of photocatalytic membrane reactor types for the degradation of an organic molecule by TiO2-coated PES membrane. Catalysts 10:725. https://doi.org/10.3390/catal10070725
Ling CM, Mohamed AR, Bhatia S (2004) Performance of photocatalytic reactors using immobilized TiO2 film for the degradation of phenol and methylene blue dye present in water stream. Chemosphere 57:547–554. https://doi.org/10.1016/j.chemosphere.2004.07.011
Manassero A, Satuf ML, Alfano OM (2017) Photocatalytic reactors with suspended and immobilized TiO2: comparative efficiency evaluation. Chem Eng J 326:29–36. https://doi.org/10.1016/j.cej.2017.05.087
Adams M, Campbell I, McCullagh C et al (2013) From ideal reactor concepts to reality: the novel drum reactor for photocatalytic wastewater treatment. Int J Chem React Eng 11:621–632. https://doi.org/10.1515/ijcre-2012-0012
Vaiano V, Sacco O, Stoller M et al (2014) Influence of the photoreactor configuration and of different light sources in the photocatalytic treatment of highly polluted wastewater. Int J Chem React Eng 12:63–75. https://doi.org/10.1515/ijcre-2013-0090
Boyjoo Y, Ang M, Pareek V (2013) Light intensity distribution in multi-lamp photocatalytic reactors. Chem Eng Sci 93:11–21. https://doi.org/10.1016/j.ces.2012.12.045
Pareek V, Chong S, Tadé M, Adesina AA (2008) Light intensity distribution in heterogenous photocatalytic reactors. Asia-Pacific J Chem Eng 3:171–201. https://doi.org/10.1002/apj.129
Amano F, Nogami K, Tanaka M, Ohtani B (2010) Correlation between surface area and photocatalytic activity for acetaldehyde decomposition over bismuth tungstate particles with a hierarchical structure. Langmuir 26:7174–7180. https://doi.org/10.1021/la904274c
Mazinani B, Masrom AK, Beitollahi A, Luque R (2014) Photocatalytic activity, surface area and phase modification of mesoporous SiO2–TiO2 prepared by a one-step hydrothermal procedure. Ceram Int 40:11525–11532. https://doi.org/10.1016/j.ceramint.2014.03.071
Li Q, Zhang N, Yang Y et al (2014) High Efficiency photocatalysis for pollutant degradation with MoS 2 /C 3 N 4 heterostructures. Langmuir 30:8965–8972. https://doi.org/10.1021/la502033t
Lv P, Xu C, Peng B (2020) Design of a silicon photocatalyst for high-efficiency photocatalytic water splitting. ACS Omega 5:6358–6365. https://doi.org/10.1021/acsomega.9b03755
Rajamanickam D, Shanthi M (2016) Photocatalytic degradation of an organic pollutant by zinc oxide—solar process. Arab J Chem 9:S1858–S1868. https://doi.org/10.1016/j.arabjc.2012.05.006
Santhosh C, Malathi A, Daneshvar E et al (2018) Photocatalytic degradation of toxic aquatic pollutants by novel magnetic 3D-TiO2@HPGA nanocomposite. Sci Rep 8:15531. https://doi.org/10.1038/s41598-018-33818-9
Fathinia M, Khataee AR (2013) Residence time distribution analysis and optimization of photocatalysis of phenazopyridine using immobilized TiO2 nanoparticles in a rectangular photoreactor. J Ind Eng Chem 19:1525–1534. https://doi.org/10.1016/j.jiec.2013.01.019
Visan A, van Ommen JR, Kreutzer MT, Lammertink RGH (2019) Photocatalytic reactor design: guidelines for kinetic investigation. Ind Eng Chem Res 58:5349–5357. https://doi.org/10.1021/acs.iecr.9b00381
Moon J, Lee K, Kim S (2015) A study of the temperature dependency for photocatalytic VOC degradation chamber test under UVLED irradiations. Korean Chem Eng Res 53:755–761. https://doi.org/10.9713/kcer.2015.53.6.755
Serpone N (2018) Heterogeneous photocatalysis and prospects of TiO2-based photocatalytic DeNOxing the atmospheric environment. Catalysts 8:553. https://doi.org/10.3390/catal8110553
Fanourakis SK, Peña-Bahamonde J, Bandara PC, Rodrigues DF (2020) Nano-based adsorbent and photocatalyst use for pharmaceutical contaminant removal during indirect potable water reuse. npj Clean Water 3:1. https://doi.org/10.1038/s41545-019-0048-8
Lavand AB, Malghe YS (2015) Synthesis, characterization, and visible light photocatalytic activity of nanosized carbon doped zinc oxide. Int J Photochem 2015:1–9. https://doi.org/10.1155/2015/790153
Cho Y, Yamaguchi A, Uehara R et al (2020) Temperature dependence on bandgap of semiconductor photocatalysts. J Chem Phys 152:231101. https://doi.org/10.1063/5.0012330
Meng F, Liu Y, Wang J et al (2018) Temperature dependent photocatalysis of g-C3N4, TiO2 and ZnO: differences in photoactive mechanism. J Colloid Interface Sci 532:321–330. https://doi.org/10.1016/j.jcis.2018.07.131
Porley V, Robertson N (2020) Substrate and support materials for photocatalysis. In: Nanostructured photocatalysts. Elsevier, pp 129–171
Lopez L, Daoud WA, Dutta D et al (2013) Effect of substrate on surface morphology and photocatalysis of large-scale TiO2 films. Appl Surf Sci 265:162–168. https://doi.org/10.1016/j.apsusc.2012.10.156
Yang Z, Liu M, Wang X (2018) Experiment study and modeling of novel mini-bubble column photocatalytic reactor with multiple micro-bubbles. Chem Eng Process Process Intensif 124:269–281. https://doi.org/10.1016/j.cep.2018.01.019
Bessegato GG, Cardoso JC, Zanoni MVB (2015) Enhanced photoelectrocatalytic degradation of an acid dye with boron-doped TiO2 nanotube anodes. Catal Today 240:100–106. https://doi.org/10.1016/j.cattod.2014.03.073
Geng Q, Cui W (2010) Adsorption and photocatalytic degradation of reactive brilliant red K-2BP by TiO2/AC in bubbling fluidized bed photocatalytic reactor. Ind Eng Chem Res 49(22):11321–11330. https://doi.org/10.1021/ie101533x
Das S, Mahalingam H (2019) Dye degradation studies using immobilized pristine and waste polystyrene-TiO2/rGO/g-C3N4 nanocomposite photocatalytic film in a novel airlift reactor under solar light. J Environ Chem Eng 7:103289. https://doi.org/10.1016/j.jece.2019.103289
Das S, Mahalingam H (2020) Novel immobilized ternary photocatalytic polymer film based airlift reactor for efficient degradation of complex phthalocyanine dye wastewater. J Hazard Mater 383. https://doi.org/10.1016/j.jhazmat.2019.121219
Desa AL, Hairom NHH, Sidik DAB et al (2019) A comparative study of ZnO-PVP and ZnO-PEG nanoparticles activity in membrane photocatalytic reactor (MPR) for industrial dye wastewater treatment under different membranes. J Environ Chem Eng 7:103143. https://doi.org/10.1016/j.jece.2019.103143
Esquivel K, Arriaga LG, Rodríguez FJ et al (2009) Development of a TiO2 modified optical fiber electrode and its incorporation into a photoelectrochemical reactor for wastewater treatment. Water Res 43:3593–3603. https://doi.org/10.1016/j.watres.2009.05.035
Kim S, Kim M, Lim SK, Park Y (2017) Titania-coated plastic optical fiber fabrics for remote photocatalytic degradation of aqueous pollutants. J Environ Chem Eng 5:1899–1905. https://doi.org/10.1016/j.jece.2017.03.036
Gallo JC, Mariano MB, Lucanas AD et al (2015) Photocatalytic degradation of turquoise blue dye using immobilized AC/TiO2: optimization of process parameters and pilot plant investigation. J Eng Sci Technol 10:64–73
Das S, Mahalingam H (2019) Reusable floating polymer nanocomposite photocatalyst for the efficient treatment of dye wastewaters under scaled-up conditions in batch and recirculation modes. J Chem Technol Biotechnol 94:2597–2608. https://doi.org/10.1002/jctb.6069
Meng Z, Zhang X, Qin J (2013) A high efficiency microfluidic-based photocatalytic microreactor using electrospun nanofibrous TiO2 as a photocatalyst. Nanoscale 5:4687. https://doi.org/10.1039/c3nr00775h
He Z, Li Y, Zhang Q, Wang H (2010) Capillary microchannel-based microreactors with highly durable ZnO/TiO2 nanorod arrays for rapid, high efficiency and continuous-flow photocatalysis. Appl Catal B Environ 93:376–382. https://doi.org/10.1016/j.apcatb.2009.10.011
Katayama K, Takeda Y, Kuwabara K, Kuwahara S (2012) A novel photocatalytic microreactor bundle that does not require an electric power source. Chem Commun 48:7368. https://doi.org/10.1039/c2cc33525e
Nair VR, Shetty Kodialbail V (2020) Floating bed reactor for visible light induced photocatalytic degradation of Acid Yellow 17 using polyaniline-TiO2 nanocomposites immobilized on polystyrene cubes. Environ Sci Pollut Res 27:14441–14453. https://doi.org/10.1007/s11356-020-07959-2
Neolaka YAB, Ngara ZS, Lawa Y et al (2019) Simple design and preliminary evaluation of continuous submerged solid small-scale laboratory photoreactor (CS4PR) using TiO2/NO3-@TC for dye degradation. J Environ Chem Eng 7:103482. https://doi.org/10.1016/j.jece.2019.103482
Akram T, Ahmad N, Sheikh I (2016) Photocatalytic degradation of synthetic textile effluent by modified sol-gel, synthesized mobilized and immobilized TiO2, and Ag-doped TiO2. Polish J Environ Stud 25:1391–1402. https://doi.org/10.15244/pjoes/62102
Hamal DB, Haggstrom JA, Marchin GL, et al (2010) A multifunctional biocide/sporocide and photocatalyst based on titanium dioxide (TiO2) codoped with silver, carbon, and sulfur. Langmuir 26. https://doi.org/10.1021/la902844r
Khenniche L, Favier L, Bouzaza A et al (2015) Photocatalytic degradation of bezacryl yellow in batch reactors—feasibility of the combination of photocatalysis and a biological treatment. Environ Technol 36:1–10. https://doi.org/10.1080/09593330.2014.934740
Mohammed Redha Z, Abdulla Yusuf H, Amin R, Bououdina M (2020) The study of photocatalytic degradation of a commercial azo reactive dye in a simple design reusable miniaturized reactor with interchangeable TiO2 nanofilm. Arab J Basic Appl Sci 27:287–298. https://doi.org/10.1080/25765299.2020.1800163
Mosleh S, Rahimi MR, Ghaedi M et al (2016) Photocatalytic degradation of binary mixture of toxic dyes by HKUST-1 MOF and HKUST-1-SBA-15 in a rotating packed bed reactor under blue LED illumination: central composite design optimization. RSC Adv 6:17204–17214. https://doi.org/10.1039/C5RA24564H
Sauer T, Cesconeto Neto G, José H, Moreira RFP (2002) Kinetics of photocatalytic degradation of reactive dyes in a TiO2 slurry reactor. J Photochem Photobiol A Chem 149:147–154. https://doi.org/10.1016/S1010-6030(02)00015-1
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Das, S., Mahalingam, H. (2022). Multiphase Reactors in Photocatalytic Treatment of Dye Wastewaters: Design and Scale-Up Considerations. In: Muthu, S.S., Khadir, A. (eds) Advanced Oxidation Processes in Dye-Containing Wastewater. Sustainable Textiles: Production, Processing, Manufacturing & Chemistry. Springer, Singapore. https://doi.org/10.1007/978-981-19-0987-0_10
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DOI: https://doi.org/10.1007/978-981-19-0987-0_10
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