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Fracture Micro Mechanism of Cryogenically Treated Ledeburitic Tool Steel

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Proceedings of the 9th International Conference on Fracture, Fatigue and Wear (FFW 2021 2021)

Abstract

Fracture micro mechanism of cryogenically treated Cr-V ledeburitic tool steel was studied on fracture toughness testing specimens, by using the scanning electron microscopy and microanalysis. Experimental steel has been processed at different combinations of cryogenic temperatures (from the range −75 to −269 °C) and tempering regimes, producing different microstructures (martensite, retained austenite, carbides), hardness- and fracture toughness values (from the ranges 700–1000 HV and 13–20 MPa × m1/2, respectively). Conventionally quenched the same steel was considered as a reference. Generally, the obtained fracture surfaces manifest combined low-energetic ductile/cleavage crack propagation mode. The low-energetic ductile mode is associated with the presence of small globular carbides (size < 0.3 μm) that are produced by cryogenic treatments. On the other hand, cleavage mode is more pronounced with increased matrix stiffness, which is caused by the precipitation of nano-scaled transient carbides within the martensite. Also, differences in role of crack propagation between various carbides were determined. These differences are caused by crystallography of these phases as well as by their size. While small globular carbides (cementite) and dominant amount of the eutectic carbides (cubic MC-phase) assist more probably (by 50–60%) in ductile micro mechanism the coarser secondary particles (hexagonal M7C3-phase) are much more prone to cleavage cracking. This tendency increases with decreasing steel hardness since the matrix becomes more plastic, and the carbides cannot deform together with the matrix as they are much more brittle.

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References

  1. Das D, Ray KK (2012) Structure-property correlation of sub-zero treated AISI D2 steel. Mater Sci Eng A 541:45–60

    Article  Google Scholar 

  2. Das D, Ray KK, Dutta AK (2009) Influence of temperature of sub-zero treatments on the wear behaviour of die steel. Wear 267:1361–1370

    Article  Google Scholar 

  3. Amini K, Akhbarizadeh A, Javadpour S (2012) Investigating the effect of holding duration on the microstructure of 1.2080 tool steel during the deep cryogenic treatment. Vacuum 86:1534–1540

    Google Scholar 

  4. Akhbarizadeh A, Javadpour S, Amini K, Yaghtin AH (2013) Investigating the effect of ball milling during the deep cryogenic heat treatment of the 1.2080 tool steel. Vacuum 90:70–74

    Google Scholar 

  5. Yarasu V, Janka L, Jurči P (2020) Začiatok formulára Spodná časť formulára Dry sliding wear behaviour of sub-zero processed Cr-V ledeburitic steel Vanadis 6 against three counterpart types. Int J Mater Res 111:894–907

    Article  Google Scholar 

  6. Berns H (1974) Restaustenit in ledeburitischen Chromstählen und seine Umwandlung durch Kaltumformen, Tiefkühlen und Anlassen. HTM J Heat Treat Mater 29:236–247 (in German)

    Article  Google Scholar 

  7. Surberg CH, Stratton P, Lingenhöle K (2008) The effect of some heat treatment parameters on the dimensional stability of AISI D2. Cryogenics 48:42–47

    Article  Google Scholar 

  8. Bartkowska A, Jurči P (2019) Corrosion resistance of vanadis 6 steel after conventional heat treatment and sub-zero treatment in cold nitrogen gas followed by tempering. Defect Diffus Forum 395:16–29

    Article  Google Scholar 

  9. Shinde T (2020) Failure analysis of cryogenically treated H13 specimen in rotating bending fatigue. Eng Fail Anal 113, Article number 104535

    Google Scholar 

  10. Korade D, Ramana KV, Jagtap K (2020) Effect of carbide density on fatigue limit of H21 die steel. J Mater Eng Perform 29:230–241

    Article  Google Scholar 

  11. Collins DN, Dormer J (1997) Deep cryogenic treatment of a D2 cold-work tool steel. Heat Treat Meals 3:71–74

    Google Scholar 

  12. Wierszyllowski I (2006) The influence of post-quenching deep cryogenic treatment on tempering processes and properties of D2 tool steel. Studies of Structure, XRD, Dilatometry, Hardness and Fracture Toughness. Defect and Diffusion Forum 258–260, 415–420

    Google Scholar 

  13. Das D, Sarkar R, Dutta AK, Ray KK (2010) Influence of sub-zero treatments on fracture toughness of AISI D2 steel. Mater Sci Eng A 528:589–603

    Article  Google Scholar 

  14. Rhyim YM, Han SH, Na YS, Lee JH (2006) Effect of deep cryogenic treatment on carbide precipitation and mechanical properties of tool steel. Solid State Phenom 118:9–14

    Article  Google Scholar 

  15. Kumar S, Nahraj M, Bongale A, Khedkar NK (2019) Effect of deep cryogenic treatment on the mechanical properties of AISI D3 tool steel. Int J Mater Eng Innov 10:98–113

    Article  Google Scholar 

  16. Molinari A, Pellizzari M, Gialanella S, Straffelini G, Stiasny KH (2001) Effect of deep cryogenic treatment on the mechanical properties of tool steels. J Mater Process Technol 118:350–355

    Article  Google Scholar 

  17. Pérez M, Rodríguez C, Belzunce FJ (2014) The use of cryogenic thermal treatments to increase the fracture toughness of a hot work tool steel used to make forging dies. Proc Mater Sci 3:604–609

    Article  Google Scholar 

  18. Sobotová J, Jurči P, Dlouhý I (2016) The effect of sub-zero treatment on microstructure, fracture toughness, and wear resistance of Vanadis 6 tool steel. Mater Sci Eng A 652:192–204

    Article  Google Scholar 

  19. Ptačinová J, Sedlická V, Hudáková M, Dlouhý I, Jurči P (2017) Microstructure Toughness relationships in sub-zero treated and tempered Vanadis 6 steel compared to conventional treatment. Mater Sci Eng A 702:241–258

    Article  Google Scholar 

  20. Jurči P, Ďurica J, Dlouhý I, Horník J, Planieta R, Kralovič D (2019) Appl Metallurg Mater Trans 50A:2413–2434

    Google Scholar 

  21. Kusy M, Rizekova-Trnkova L, Krajcovic J, Dlouhy I, Jurči P (2019) Can sub-zero treatment at −75 degrees C bring any benefits to tools manufacturing? Materials 12, Article number 3827

    Google Scholar 

  22. Jurči P, Ptačinová J, Dlouhý I (20199) Cryogenic treatment of Cr-V die steel in liquid helium—effect on mechanical properties. In: METAL 2019—28th International conference on metallurgy and materials, pp 562–568, Tanger, Ltd., Brno, Czech Republic

    Google Scholar 

  23. ISO 12137 (2010) Metallic materials—determination of plane strain fracture toughness

    Google Scholar 

  24. Ďurica J, Ptačinová J, Dománková M, Čaplovič L, Čaplovičová M, Hrušovská L, Malovcová V, Jurči P (2019) Changes in microstructure of ledeburitic tool steel due to vacuum austenitizing and quenching, sub-zero treatments at −140°C and tempering. Vacuum 170. https://doi.org/10.1016/j.vacuum.2019.108977

  25. Jurči P, Dománková M, Hudáková M, Ptačinová J, Pašák M, Palček P (2017) Characterization of microstructure and tempering response of conventionally quenched, short- and long-time sub-zero treated PM Vanadis 6 ledeburitic tool steel. Mater Charact 134:398–415

    Article  Google Scholar 

  26. ASTM E975-13 (2004) Standard practice for X-ray determination of retained austenite in steel with near random crystallographic orientation. ASTM book of standards, vol 3.01. West Conshohocken, PA, USA

    Google Scholar 

  27. Putatunda SK (2001) Fracture toughness of a high carbon and high silicon steel. Mater Sci Eng A 297:31–43

    Article  Google Scholar 

  28. Berns H, Broeckmann C (1997) Fracture of hot formed ledeburitic chromium steels. Eng Fract Mech 58:311–325

    Article  Google Scholar 

  29. Hansen N (2004) Hall-Petch relation and boundary strengthening. Scripta Mater 51:801–806

    Article  Google Scholar 

  30. Bhadeshia HKDH (2019) Cementite. Int Mater Rev. https://doi.org/10.1080/09506608.2018.1560984

    Article  Google Scholar 

  31. Coronado JJ, Rodriguez SA (2015) Cementite characterization with chromium and vanadium contents using indentation technique. J Iron Steel Res Int 22:366–370

    Article  Google Scholar 

  32. Casellas D, Caro J, Molas S, Prado JM, Valls I (2007) Fracture toughness of carbides in tool steels evaluated by nanoindentation. Acta Mater 55:4277–4286

    Article  Google Scholar 

  33. Fukaura K, Yokoyama Y, Yokoi D, Tsuji N, Ono K (2004) Fatigue of cold-work tool steels: effect of heat treatment and carbide morphology on fatigue crack formation, life, and fracture surface observations. Metallurg Mater Trans 35A:1289–1300

    Article  Google Scholar 

  34. Večko Pirtovšek T, Kugler G, Terčelj M (2013) The behaviour of the carbides of ledeburitic AISI D2 tool steel during multiple hot deformation cycles. Mater Charact 83:97–108

    Article  Google Scholar 

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Acknowledgements

The authors would like to acknowledge that the article is an outcome implementation of the following two projects: scientific project VEGA 1/0112/20 and APRODIMET, ITMS: 26220120048, supported by the Research and Development Operational Programme funded by the European Regional Development Fund.

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Jurči, P., Ptačinová, J., Dlouhý, I. (2022). Fracture Micro Mechanism of Cryogenically Treated Ledeburitic Tool Steel. In: Abdel Wahab, M. (eds) Proceedings of the 9th International Conference on Fracture, Fatigue and Wear . FFW 2021 2021. Lecture Notes in Mechanical Engineering. Springer, Singapore. https://doi.org/10.1007/978-981-16-8810-2_6

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  • DOI: https://doi.org/10.1007/978-981-16-8810-2_6

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