Abstract
No single material or a class of material meets the diverse set of properties required for different applications. Inherent advantages and disadvantages of metals, ceramics, or polymers have made it necessary to develop combinatorial approaches, wherein their functional advantages are maximized and drawbacks are abridged. Composites are the materials comprising two or more constituent materials with significantly different physical, mechanical, electrical, or thermal attributes. Composites offer material characteristics that are different from the individual components and can be engineered to entail synergistic advantages such as high strength, corrosion resistance, electrical or thermal conductivity, and low cost. Notably, in composites, the individual components may remain separate and distinct within the finished structure. The composite material is generally defined by the matrix such as metal-matrix composite, ceramic-matrix composites, and polymer-matrix composites, or by the type and morphological arrangement of the filler such as particle reinforced, fiber reinforced, unidirectional, random, laminates, or honeycombs. Fabrication of composite materials is accomplished by a wide variety of techniques such as melt compounding, in situ polymerization, tufting, tailored fiber placement and filament winding. Depending on the matrix and the filler, different synthetic strategies are adopted. Further with the advent of nano-sized fillers, new class of composites has emerged which have significant important advantages over the conventional composites. This chapter provides details on the synthesis strategies of different polymer-matrix composite materials. A detailed account of the strategies to tailor interfacial adhesion, dispersion, filler asymmetry, filler orientation, and high loading is made, and specific details on the synthesis of nanocomposites and the morphology-interface-property correlation are presented. Recent advances in the theoretical frameworks and the specific applications of the composites are also discussed.
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Abbreviations
- 3D:
-
Three dimensional
- AlN:
-
Aluminum nitride
- BS:
-
Barium sulfate
- BT:
-
Barium titanate
- CaCO3:
-
Calcium carbonate
- CF:
-
Carbon fiber
- CNF:
-
Conducting nano-fiber
- CNT:
-
Carbon nanotube
- CPC:
-
Conducting polymer composites
- DVB:
-
Divinylbenzene
- EB:
-
Electron beam
- EPDM:
-
Ethylene propylene diene monomer
- EPR:
-
Electron paramagnetic resonance
- Epoxy-Br:
-
Brominated epoxy
- ER:
-
Epoxy resin
- EVA:
-
Ethylene vinyl acetate
- FCE:
-
Fluorocarbon elastomer
- FRPs:
-
Fiber-reinforced plastics
- GO:
-
Graphene oxide
- MA:
-
Maleic anhydride
- MCFs:
-
Microcrystalline cellulose fibers
- MMT:
-
Montmorillonite
- MWCNT:
-
Multi-walled carbon nanotube
- NCB:
-
Nano carbon black
- NR:
-
Natural rubber
- PAN-g-PDMS:
-
Polyacrylonitrile-graft-poly(dimethyl siloxane)
- PB:
-
Polybutadiene
- PBA:
-
Poly(butyl acrylate)
- PC:
-
Polymer composites
- PDMS:
-
Poly(dimethyl siloxane)
- PP:
-
Polypropylene
- PTFE:
-
Poly(tetra fluoro ethylene)
- PVDF:
-
Polyvinylidene fluoride
- PVP:
-
Poly(vinyl pyrrolidone)
- SBR:
-
Styrene-butadiene rubber
- SEM:
-
Scanning electron microscopy
- SWCNT:
-
Single-walled carbon nanotube
- T g :
-
Glass transition temperature
- TPC:
-
Thermoplastic composites
- TSCs:
-
Thermoset composites
- TiO2:
-
Titanium dioxide
- TMPTA:
-
Trimethylolpropane triacrylate
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Acknowledgements
The authors sincerely thank Dr. P. K. Pujari, Director, Radiochemistry and Isotope Group, for his constant encouragement and a keen interest in this work.
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Dubey, K.A., Bhardwaj, Y.K. (2021). High-Performance Polymer-Matrix Composites: Novel Routes of Synthesis and Interface-Structure-Property Correlations. In: Tyagi, A.K., Ningthoujam, R.S. (eds) Handbook on Synthesis Strategies for Advanced Materials. Indian Institute of Metals Series. Springer, Singapore. https://doi.org/10.1007/978-981-16-1892-5_1
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