Abstract
Gaseous pollutants emitted from human activities, such as the use of fossil fuels, smelting ferrous/nonferrous metals, and producing and using chemicals, pose a severe threat to humans and the environment. Absorption is commonly used to reduce the emission of gaseous pollutants by absorbing harmful components of a gas stream into an absorbent. Despite mature industrial applications, further improvements to absorption technology are required. In this chapter, the principles of pollution control by absorption are introduced in detail. First, the fundamentals and key factors of SO2 absorption are discussed, including process chemistry, mass transfer, and reaction kinetics. Based on the influence of these factors, SO2 absorption enhancement methods, such as pH adjustment, desulfurization additives, and scrubber optimization, are demonstrated in the second section. In light of the urgent need for multi-pollutant control, technologies for simultaneous control of other pollutants, such as NOx and Hg, in the SO2 absorption process are introduced.
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References
Toprac A, Rochelle G (1982) Limestone dissolution in stack gas desulfurization. Environ Prog Sustainable Energy 1(1):52–58
Pan D, Wu H, Yang L (2017) Investigation on the relationship between the fine particle emission and crystallization characteristics of gypsum during wet flue gas desulfurization process. J Environ Sci 55(005):303–310
Rezaei F et al (2015) SOx/NOx removal from flue gas streams by solid adsorbents: a review of current challenges and future directions. Energy Fuels 29(9):5467–5486
Zhou J, Wang H (2020) Study on efficient removal of SOx and NOx from marine exhaust gas by wet scrubbing method using urea peroxide solution. Chem Eng J 390:124567
Ding J, Zhong Q, Zhang S et al (2014) Simultaneous removal of NOx and SO2 from coal-fired flue gas by catalytic oxidation-removal process with H2O2. Chem Eng J 243:176–182
Zhao Yi et al (2010) Simultaneous removal of SO2 and NO using M/NaClO2 complex absorbent. Chem Eng J 160(1):42–47
Zhu J, Ye S, Bai J et al (2015) A concise algorithm for calculating absorption height in spray tower for wet limestone–gypsum flue gas desulfurization. Fuel Process Technol 129:15–23
Tian H et al (2021) Simultaneous magnesia regeneration and sulfur dioxide generation in magnesium-based flue gas desulfurization process. J Cleaner Prod 284:124720
Andreasen A, Mayer S (2007) Use of seawater scrubbing for SO2 removal from marine engine exhaust gas. Energy Fuels 21(6):3274–3279
Gao X, Ding H, Du Z et al (2010) Gas–liquid absorption reaction between (NH4)2SO3 solution and SO2 for ammonia-based wet flue gas desulfurization. Appl Energy 87(8):2647–2651
Kallinikos L et al (2010) Simulation of the operation of an industrial wet flue gas desulfurization system. Fuel Process Technol 91(12):1794–1802
Sander R (2015) Compilation of Henry’s law constants (version 4.0) for water as solvent. Atmos Chem Phys 15(8):4399–4981
Whiteman W (1923) The two-film theory of gas absorption. Chem Metal Eng 29(1):147–157
Higbie R (1935) The rate of absorption of a pure gas into still liquid during short periods of exposure. Am Inst Chem Eng 31:365–389
Danckwerts P (1970) Gas-liquid reaction. McGraw-Hill Press, New York
Zhao Z, Zhang Y, Gao W et al (2021) Simulation of SO2 absorption and performance enhancement of wet flue gas desulfurization system. Process Saf Environ Prot. https://doi.org/10.1016/j.psep.2021.04.032
Gao X, Guo R, Ding H et al (2009) Dissolution rate of limestone for wet flue gas desulfurization in the presence of sulfite. J Hazard Mater 168(2–3):1059–1064
Chen Y (2012) Experimental study on the promoting dissolution of limestone and strengthening SO2 absorption by WFGD additives. Zhejiang University, China (in Chinese)
Guo R (2008) Study on the effects of limestone reactivity and flow field on wet flue gas desulfurization efficiency. Zhejiang University, China (in Chinese)
Guo R, Gao X, Wang J et al (2007) Reactivity of limestone in wet flue gas desulfurization system. J Combust Sci Technol 06:485–490 (in Chinese)
Yue L, Jin D, Xu Z (2003) Transition of shape and crystallization type of CaCO3 composite synthesized by co-precipitation method. Acta Chim Sinica 61(10):1587–1591 (in Chinese)
Hong Y (2020) Study on wet flue gas desulfurization based on pH control technology. Zhejiang University, China (in Chinese)
Mori T, Matsuda S, Nakajima F et al (1981) Effect of Al3+ and F− on desulfurization reaction in the limestone slurry scrubbing process. Ind Eng Chem Process Des Dev 20(1):144–147
Electric utility engineer’s FGD manual. Volume 1: FGD process design. Final report, 4 Mar 1996, United States. https://digital.library.unt.edu/ark:/67531/metadc695907/
Liu C, Zhao Z, Gao W et al (2021) Process optimization of S (IV) oxidation in flue gas desulfurization scrubbers. Process Saf Environ Prot 149(3):610–618
Huo W (2009) Mechanism research on the absorption, oxidation and crystallization in the process of limestone-gypsum WFGD. Zhejiang University, China (in Chinese)
Gerbec M, Stergarsek A, Kocjancic R (1995) Simulation model of wet flue gas desulphurization plant. Comput Chem Eng 19(Supplement 1):283–286
Fick’s LM, Law G-K (2000) Formula, and Heisenberg’s equation of motion. Phys Rev Lett 85(12):2422–2425
Fuller E, Schettler P, Giddings J (1966) New method for prediction of binary gas-phase diffusion coefficients. Ind Eng Chem 58(5):18–27
Gao X, Huo W, Zhong Y et al (2008) Effects of magnesium and ferric ions on crystallization of calcium sulfate dihydrate under the simulated conditions of wet flue-gas desulfurization. Chem Res Chin Univ 24(6):688–693
Zhong Y, Gao X, Huo W et al (2008) A model for performance optimization of wet flue gas desulfurization systems of power plants. Fuel Process Technol 89(11):1025–1032
Stefan O et al (1993) A model for the absorption of sulphur dioxide into a limestone slurry. Chem Eng J 51(2):99–108
Tseng P, Rochelle G (1986) Calcium sulfite hemihydrate: crystal growth rate and crystal habit. Environ Prog 5(1):5–11
Pasiuk-Bronikowska W, Rudziński KJ (1991) Absorption of SO2 into aqueous systems. Chem Eng Sci 46(9):2281–2291
Li C, Zhang J, Zhang Y et al (2015) Removal efficiency of high sulfur dioxide in WFGD based on dual-pH value control. Acta Sci Circum 35(12):4081–4087
Frandsen JB, Kiil S et al (2001) Optimization of a wet FGD pilot plant using fine limestone and organic acids. Chem Eng Sci 56(10):3275–3287
Xu C, Wu C, Duan S et al (2014) Research of composite additive on high efficient desulfurization. Energy Eng 4:53–58 (in Chinese)
Pan S et al (2017) Development of high-gravity technology for removing particulate and gaseous pollutant emissions: principles and applications. J Clean Prod 149:540–556
Lin Y (2006) Study on large scale limestone-gypsum spraying desulphurization technology and project application. Zhejiang University, China (in Chinese)
Chen X (2008) Experimental study on desulfurization and nitrification in spray scrubber. Zhejiang University, China (in Chinese)
Zhong Y (2008) Theoretical and experimental study of simultaneous removal of sulfur, nitrogen and mercury pollutant in WFGD system. Zhejiang University, China (in Chinese)
Lin F, Wang Z, Zhang Z et al (2020) Flue gas treatment with ozone oxidation: an overview on NOx, organic pollutants, and mercury. Chem Eng J 382:123030
Dora J, Gostomczyk M, Jakubiak M et al (2009) Parametric studies of the effectiveness of NO oxidation process by ozone. Chem Process Eng 30(4):621–633
Wang Z, Zhou J, Zhu Y et al (2007) Simultaneous removal of NOx, SO2 and Hg in nitrogen flow in a narrow reactor by ozone injection: experimental results. Fuel Process Technol 88(8):817–823
Zheng C, Xu C, Zhang Y et al (2014) Nitrogen oxide absorption and nitrite/nitrate formation in limestone slurry for WFGD system. Appl Energy 129(Sept 15):187–194
Gao X, Du Z, Ding H et al (2010) Kinetics of NOx absorption into (NH4)2SO3 solution in an ammonia-based wet flue gas desulfurization process. Chem Commun 24(11):3996–4015
Karkront H, Rosenberg H (1984) Flue gas denitrification. Selective catalytic oxidation of nitric oxide to nitrous oxide. Ind Eng Chem Res 23(4):808–814
Corro G, Elizalde M, Velasco A (2002) Promotional effect of Sn on NO oxidation over Pt/Al2O3 as promising gas exhaust catalytic converter. Selective Pt and Sn dispersion determination. React Kinet Catal Lett 76(1):117–122
Ichiura H, Kitaoka T, Tanaka H (2003) Photocatalytic oxidation of NOx using composite sheets containing TiO2 and a metal compound. Chemosphere 51(9):855–860
Kim H, Han J, Kawaguchi I et al (2007) Simultaneous removal of NOx and SO2 by a nonthermal plasma hybrid reactor. Energy Fuels 21(1):141–144
Li K, Tang X, Yi H et al (2011) Mechanism of catalytic oxidation of NO over Mn–Co–Ce–Ox catalysts with the aid of nonthermal plasma at low temperature. Ind Eng Chem Res 50(19):11023–11028
Mok Y (2004) Oxidation of NO to NO2 using the ozonization method for the improvement of selective catalytic reduction. J Chem Eng Jpn Off Publ Soc Chem Eng 37(11):1337–1344
Zheng C, Xu C, Gao X et al (2014) Simultaneous absorption of NOx and SO2 in oxidant-enhanced limestone slurry. Environ Prog Sustainable Energy 33(4):1171–1179
Sada E, Kumazawa H, Hayakawa N et al (1977) Absorption of NO in aqueous solutions of KMnO4. Chem Eng Sci 32(10):1171–1175
Xu C (2014) Experimental study on the integrated and intensive absorption of NOx/SO2 from coal-fired flue gas. Zhejiang University, China (in Chinese)
He S, Zhou J, Zhu Y et al (2010) Effect of vanadium-based selective catalytic reduction catalysts on mercury speciation transformation. J Zhejiang Univ (Eng Sci) 44(09):1773–1780 (in Chinese)
Zheng C, Wang L, Zhang Y et al (2017) Partitioning of hazardous trace elements among air pollution control devices in ultra-low-emission coal-fired power plants. Energy Fuels 31(6):6334–6344
Zheng C, Xu L, Liu S et al (2018) Speciation and thermal stability of mercury in solid products from ultra-low emission air pollution control devices. Energy Fuels 32(12):12655–12664
Sui Z, Zhang Y, Li W et al (2015) Partitioning effect of mercury content and speciation in gypsum slurry as a function of time. J Therm Anal Calorim 119(3):1611–1618
Lin F (2018) Basic characteristics study on NOx deep removal in the flue gas by active molecules (ozone)-catalytic method. Zhejiang University, China (in Chinese)
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Gao, X., Zheng, C., Chiang, PC., Cen, K. (2021). Pollutant Control by Absorption Methods. In: Multi-Pollutant Control for Flue Gases. Advanced Topics in Science and Technology in China, vol 63. Springer, Singapore. https://doi.org/10.1007/978-981-16-1518-4_4
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DOI: https://doi.org/10.1007/978-981-16-1518-4_4
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