Abstract
In the present era, vehicles on road are increasing day by day and its demand is bouncing. The world’s fossil fuel reserves are limited so there is scope to have intensive research to develop and use non-fossil fuels in vehicles. Methanol is the best-suited candidate to fulfil this crisis. Methanol has lots of supporting characteristics to be used in the engine; lower production costs, high octane number, impressive cold working temperature, good emission characteristics, high latent heat of vapourization, enhancing thermal efficiency, high flame speed, low combustion temperature are a few of them. This fuel can be used directly and with blending with conventional fuel in engines. Methanol can be produced from a variety of feedstock such as coal, natural gas, CO2, biomass, etc. through various processes like reforming the gas with steam, production with methanotrophic Bacteria, gasification process, carbon dioxide hydrogenation, synthesis through Syngas, direct oxidation of methane, etc. Although methanol has many adaptive properties to be used as a fuel individual and with levels of blending however there are many challenges too with methanol used as a fuel; its toxicity, fire safety concern, low cetane number, lower heating value, higher kinematic viscosity, low lubricity, high corrosive in nature are a few of them. This chapter deals with various aspects from scopes to limitations of methanol to be used in Internal Combustion Engines.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Abbreviations
- IC:
-
Internal Combustion
- ON:
-
Octane Number
- CN:
-
Cetane Number
- CO:
-
Carbon Monoxide
- HC:
-
Hydrocarbons
- STP:
-
Standard temperature and pressure
- GEM:
-
Gasoline–ethanol–methanol
References
Central intelligence agency. https://www.cia.gov/library/publications/the-world-factbook/geos/xx.html
Kim S, Dale BE (2005) Environmental aspects of ethanol derived from no-tilled corn grain: nonrenewable energy consumption and greenhouse gas emissions. Biomass Bioenerg 28(5):475–489
Methanol Economy (2018) NITI Aayog working on roadmap for India onWorld Environment Day. https://pib.nic.in/newsite/PrintRelease.aspx?relid=179785
Verhelst S, Turner JW, Sileghem L, Vancoillie J (2019) Methanol as a fuel for internal combustion engines. Prog Energy Combust Sci 70:43–88
Vancoillie J (2013) Modeling the combustion of light alcohols in spark-ignition engines (Doctoral dissertation, Ghent University)
Vancoillie J, Verhelst S (2010) Modeling the combustion of light alcohols in SI engines: a preliminary study. In: FISITA 2010 World Automotive Congress. International Federation of Automotive Engineering Societies
De Cuyper T, Demuynck J, Broekaert S, De Paepe M, Verhelst S (2016) Heat transfer in premixed spark ignition engines part II: Systematic analysis of the heat transfer phenomena. Energy 116:851–860
Aasberg-Petersen K, Nielsen CS, Dybkjær I, Perregaard J (2008) Large scale methanol production from natural gas. Haldor Topsoe, p 22
van Sint Annaland MM, Gallucci IFF, de Groot IMT, Spallina IVV (2017) Techno-economic analysis of methanol production using chemical looping reformin
Valera H, Agarwal AK (2019) Methanol as an alternative fuel for diesel engines. In: Methanol and the alternate fuel economy. Springer, Singapore, pp 9–33
Trop P, Anicic B, Goricanec D (2014) Production of methanol from a mixture of torrefied biomass and coal. Energy 77:125–132
Matzen M, Alhajji M, Demirel Y (2015) Chemical storage of wind energy by renewable methanol production: Feasibility analysis using a multi-criteria decision matrix. Energy 93:343–353
Trudewind CA, Schreiber A, Haumann D (2014) Photocatalytic methanol and methane production using captured CO2 from coal-fired power plants. Part I–a Life Cycle Assessment. J Clean Prod 70:27–37
Rathod VP, Bansal P, Bhale PV (2015) Analytical and experimental investigations for hydrogen rich syngas production by biogas reforming processes. Energy Procedia 75:728–733
Ryi SK, Park JS, Kim DK, Kim TH, Kim SH (2009) Methane steam reforming with a novel catalytic nickel membrane for effective hydrogen production. J Membr Sci 339(1–2):189–194
Tsolakis A, Golunski SE (2006) Sensitivity of process efficiency to reaction routes in exhaust-gas reforming of diesel fuel. Chem Eng J 117(2):131–136
Tomishige K, Matsuo Y, Sekine Y, Fujimoto K (2001) Effective methane reforming with CO2 and O2 under pressurized condition using NiO–MgO and fluidized bed reactor. Catal Commun 2(1):11–15
Brown LF (2001) A comparative study of fuels for on-board hydrogen production for fuel-cell-powered automobiles. Int J Hydrogen Energy 26(4):381–397
Klier K (1982) Methanol synthesis. In: Advances in catalysis, vol. 31. Academic Press, pp 243–313
Brynolf S, Fridell E, Andersson K (2014) Environmental assessment of marine fuels: liquefied natural gas, liquefied biogas, methanol and bio-methanol. J Clean Prod 74:86–95
Andersson J, Lundgren J, Marklund M (2014) Methanol production via pressurized entrained flow biomass gasification–Techno-economic comparison of integrated vs. stand-alone production. Biomass Bioenerg 64:256–268
Räuchle K, Plass L, Wernicke HJ, Bertau M (2016) Methanol for renewable energy storage and utilization. Energy Technol 4(1):193–200
Minutillo M, Perna A (2010) A novel approach for treatment of CO2 from fossil fired power plants. Part B: the energy suitability of integrated tri-reforming power plants (ITRPPs) for methanol production. Int J Hydrogen Energy 35(13):7012–7020
Binder H, Köhling A, Sandstede G (1972) From electrocatalysis to fuel cells. SANSTEDE (ed) Seattle, pp 15–31
McNicol BD, Rand DAJ, Williams KR (1999) Direct methanol–air fuel cells for road transportation. J Power Sources 83(1–2):15–31
Turner JW, Pearson RJ, McGregor MA, Ramsay JM, Dekker E, Iosefa B, ... ac Bergström K (2012) GEM ternary blends: testing iso-stoichiometric mixtures of gasoline, ethanol and methanol in a production flex-fuel vehicle fitted with a physical alcohol sensor (No. 2012–01–1279). SAE Technical Paper
Turner JW, Pearson RJ, Bell A, de Goede S, Woolard C (2012) Iso-stoichiometric ternary blends of gasoline, ethanol and methanol: investigations into exhaust emissions, blend properties and octane numbers. SAE Int J Fuels Lubric 5(3):945–967
The Standards Institution of Israel. Israel M15 press release. https://methanolfuels.wpengine.com/wpcontent/uploads/2013/05/Israel-M15-Press-Release-8 2016.pdf
Australian GEM fuel program.https://methanolfuels.org/wpcontent/ uploads/2013/05/Grant-Lukey-Coogee-Energy-Australia.pdf (2013)
Bourhis G, Solari JP, Dauphin R, De Francqueville L (2016) Fuel properties and engine injection configuration effects on the octane on demand concept for a dual-fuel turbocharged spark ignition engine (No. 2016–01–2307). SAE Technical Paper
Sileghem L, Coppens A, Casier B, Vancoillie J, Verhelst S (2014) Performance and emissions of iso-stoichiometric ternary GEM blends on a production SI engine. Fuel 117:286–293
Yates A, Bell A, Swarts A (2010) Insights relating to the autoignition characteristics of alcohol fuels. Fuel 89(1):83–93
Turner JW, Pearson RJ, Dekker E, Iosefa B, Johansson K, Ac Bergström K (2013) Extending the role of alcohols as transport fuels using iso-stoichiometric ternary blends of gasoline, ethanol and methanol. Appl Energy 102:72–86
Turner J, Griffith W (2012) Processing of fuel and recirculated exhaust gas. UK Patent GB2484495
Turner D, Xu H, Cracknell RF, Natarajan V, Chen X (2011) Combustion performance of bio-ethanol at various blend ratios in a gasoline direct injection engine. Fuel 90(5):1999–2006
Waqas M, Naser N, Sarathy M, Feijs J, Morganti K, Nyrenstedt G, Johansson B (2017). Auto-ignition of iso-stoichiometric blends of gasoline-ethanol-methanol (GEM) in SI, HCCI and CI combustion modes
Anderson JE, Leone TG, Shelby MH, Wallington TJ, Bizub JJ, Foster M, ..., Polovina D (2012) Octane numbers of ethanol-gasoline blends: measurements and novel estimation method from molar composition (No. 2012–01–1274). SAE Technical Paper
Qi DH, Liu SQ, Zhang CH, Bian YZ (2005) Properties, performance, and emissions of methanol-gasoline blends in a spark ignition engine. Proc Inst Mech Eng Part D: J Autom Eng 219(3):405–412
Balki MK, Sayin C (2014) The effect of compression ratio on the performance, emissions and combustion of an SI (spark ignition) engine fueled with pure ethanol, methanol and unleaded gasoline. Energy 71:194–201
Agarwal AK, Karare H, Dhar A (2014) Combustion, performance, emissions and particulate characterization of a methanol–gasoline blend (gasohol) fuelled medium duty spark ignition transportation engine. Fuel Process Technol 121:16–24
Bromberg L, Cheng WK (2010) Methanol as an alternative transportation fuel in the US: Options for sustainable and/or energy-secure transportation. Sloan Automotive Laboratory, Massachusetts Institute of Technology, Cambridge, MA
Bansal P, Upadhyay L (2013) Experimental investigations to study tool wear during turning of alumina reinforced aluminium composite. Proc Eng 51:818–827
Bansal P, Upadhyay L (2016) Effect of turning parameters on tool wear, surface roughness and metal removal rate of alumina reinforced aluminum composite. Proc Technol 23:304–310
Bansal P, Pandya A, Ahuja A (2016, December) Experimental performance evaluation on SI engine with gasoline and liquefied petroleum gas as fuel. In: Techno-Societal 2016, International conference on advanced technologies for societal applications. Springer, Cham, pp 183–191
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2021 The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.
About this chapter
Cite this chapter
Bansal, P., Meena, R. (2021). Methanol as an Alternative Fuel in Internal Combustion Engine: Scope, Production, and Limitations. In: Agarwal, A.K., Valera, H., Pexa, M., ÄŚedĂk, J. (eds) Methanol. Energy, Environment, and Sustainability. Springer, Singapore. https://doi.org/10.1007/978-981-16-1224-4_2
Download citation
DOI: https://doi.org/10.1007/978-981-16-1224-4_2
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-16-1223-7
Online ISBN: 978-981-16-1224-4
eBook Packages: EnergyEnergy (R0)