Abstract
We used a combined technique of the ice film nanocapacitor and matrix isolation to experimentally study the behavior of isolated molecules and molecular clusters under the influence of external electrostatic fields. The field-driven changes were recorded by means of reflection–absorption infrared spectroscopy. All experiments were conducted in an ultrahigh vacuum chamber equipped with devices for thin film preparation and spectroscopic detection.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Block PA, Bohac EJ, Miller RE (1992) Spectroscopy of pendular states: the use of molecular complexes in achieving orientation. Phys Rev Lett 68:1303–1306
Nauta K, Moore DT, Miller RE (1999) Molecular orientation in superfluid liquid helium droplets: high resolution infrared spectroscopy as a probe of solvent-solute interactions. Faraday Discuss. 113:261–278
Nauta K, Miller RE (1999) Nonequilibrium self-assembly of long chains of polar molecules in superfluid helium. Science 283:1895–1897
Toennies JP, Vilesov AF (2004) Superfluid helium droplets: a uniquely cold nanomatrix for molecules and molecular complexes. Angew Chem Int Ed 43:2622–2648
Choi M, Dong F, Miller R (2004) Multiple tautomers of cytosine identified and characterized by infrared laser spectroscopy in helium nanodroplets: probing structure using vibrational transition moment angles. Philos Trans Royal Soc A 363:393–413
Choi MY, Douberly GE, Falconer TM, Lewis WK, Lindsay CM, Merritt JM, Stiles PL, Miller RE (2006) Infrared spectroscopy of helium nanodroplets: novel methods for physics and chemistry. Int Rev Phys Chem 25:15–75
Choi MY, Miller RE (2006) Infrared laser spectroscopy of imidazole complexes in helium nanodroplets: monomer, dimer, and binary water complexes. J Phys Chem A 110:9344–9351
Andrews SS, Boxer SG (2000) Vibrational stark effects of nitriles I. Methods and experimental results. J Phys Chem A 104:11853–11863
Andrews SS, Boxer SG (2002) Vibrational stark effects of nitriles II. Physical origins of stark effects from experiment and perturbation models. J Phys Chem A 106:469–477
Saggu M, Levinson NM, Boxer SG (2011) Direct measurements of electric fields in weak OH···π hydrogen bonds. J Am Chem Soc 133:17414–17419
Saggu M, Levinson NM, Boxer SG (2012) Experimental quantification of electrostatics in X-H···π hydrogen bonds. J Am Chem Soc 134:18986–18997
Fried SD, Boxer SG (2015) Measuring electric fields and noncovalent interactions using the vibrational stark effect. Acc Chem Res 48:998–1006
Shin S, Kim Y, Moon E-S, Lee DH, Kang H, Kang H (2013) Generation of strong electric fields in an ice film capacitor. J Chem Phys 139:074201
Shin S, Kim Y, Kang H, Kang H (2015) Effect of electric field on condensed-phase molecular systems. I. Dipolar polarization of amorphous solid acetone. J Phys Chem C 119:15588–15595
Shin S, Kang H, Cho D, Lee JY, Kang H (2015) Effect of electric field on condensed-phase molecular systems. II. Stark effect on the hydroxyl stretch vibration of ice. J Phys Chem C 119:15596–15603
Shin S, Park Y, Kang H, Kang H (2017) Electric field effect on condensed-phase molecular systems. IV. Conformational change of 1,2-dichloroethane in a frozen molecular solid. J Phys Chem C 121:25342–25346
Shin S, Park Y, Kang H, Kang H (2018) Electric field effect on condensed-phase molecular systems: V. Acid–base proton transfer at the interface of molecular films. J Phys Chem C 122:4901–4907
Park Y, Kang H, Kang H (2017) Brute force orientation of matrix-isolated molecules: reversible reorientation of formaldehyde in an argon matrix toward perfect alignment. Angew Chem Int Ed 56:1046–1049
Kang H, Park Y, Kim ZH, Kang H (2018) Electric field effect on condensed-phase molecular systems. VI. Field-driven orientation of hydrogen chloride in an argon matrix. J Phys Chem A 122:2871–2876
Park Y, Lim JH, Lee JY, Kang H (2019) Electric field effect on condensed-phase molecular systems. VII. Vibrational stark sensitivity of spatially oriented water molecules in an argon matrix. J Phys Chem C 123:9868–9874
Park Y, Kang H, Field RW, Kang H (2019) The frequency-domain IR spectrum of ammonia encodes changes in molecular dynamics caused by a DC electric field. Proc Natl Acad Sci USA 116:23444–23447
Whittle E, Dows DA, Pimentel GC (1943) Matrix isolation method for the experimental study of unstable species. J Chem Phys 1954:22
Hallam HE (1973) Vibrational spectroscopy of trapped species. Wiley, Hoboken
Marcoux J (1970) Dielectric constants and indices of refraction of Xe, Kr, and Ar. Can J Phys 48:244–245
Tsekouras AA, Iedema MJ, Cowin JP (1998) Amorphous water-ice relaxations measured with soft-landed ions. Phys Rev Lett 80:5798–5801
Onsager L (1936) Electric moments of molecules in liquids. J Am Chem Soc 58:1486–1493
Böttcher CJF (1973) Theory of electric polarization. Elsevier, Amsterdam
Griffiths PR, De Haseth JA (2007) Fourier transform infrared spectrometry, 2nd edn. Wiley, Hoboken, pp 277–301
Golden WG, Saperstein DD, Severson MW, Overend J (1984) Infrared reflection-absorption spectroscopy of surface species: a comparison of fourier transform and dispersion methods. J Phys Chem 88:574–580
Rost JM, Griffin JC, Friedrich B, Herschbach DR (1992) Pendular states and spectra of oriented linear molecules. Phys Rev Lett 68:1299–1302
Maergoiz A, Troe J (1993) Weak- and strong-field stark energy levels of symmetric top dipolar molecules. J Chem Phys 99:3218–3223
Kanya R, Ohshima Y (2004) Pendular-limit representation of energy levels and spectra of symmetric- and asymmetric-top molecules. Phys Rev A 70:013403
Härtelt M, Friedrich B (2008) Directional states of symmetric-top molecules produced by combined static and radiative electric fields. J Chem Phys 128:224313
Moore DT, Oudejans L, Miller R (1999) Pendular state spectroscopy of an asymmetric top: parallel and perpendicular bands of acetylene-HF. J Chem Phys 110:197–208
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 2020 The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.
About this chapter
Cite this chapter
Park, Y. (2020). Method. In: Manipulation of Matrix-Isolated Molecules and Molecular Clusters with Electrostatic Fields. Springer Theses. Springer, Singapore. https://doi.org/10.1007/978-981-15-8693-4_2
Download citation
DOI: https://doi.org/10.1007/978-981-15-8693-4_2
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-15-8692-7
Online ISBN: 978-981-15-8693-4
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)