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Potential- or Adsorbate-Induced Changes in Surface Stress of Solid Metal Electrode, and Surface Stress versus Surface Charge Density or Potential versus Surface Elastic Strain

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Electro-Chemo-Mechanical Properties of Solid Electrode Surfaces

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Abstract

Potential- or adsorbate-induced changes in surface stress associated with surface reconstruction or adsorption of electrolyte anions on single-crystal Au electrodes are explained and discussed as typical examples of the electro-chemo-mechanical properties. The surface stress versus potential curves measured for single-crystal Au electrodes subjected to surface reconstruction or adsorption of electrolyte anions are compared with the corresponding electrocapillary (surface tension vs. potential) curves, and it is experimentally confirmed that surface stress differs from surface tension for a solid electrode. Two important parameters for characterizing solid electrode surfaces are surface stress–surface charge coefficient and potential–surface elastic strain coefficient which are theoretically equivalent to each other. The above two coefficients measured separately by several methods for a (111)-textured Au (111) thin-film electrode in perchloric acid solution are compared, and the equality of both coefficients is confirmed experimentally. Furthermore, the sign-reversals of the above coefficients observed for nano-porous or (111)-textured Pt electrodes in acid solutions are explained and the causes of the sign-reversal are discussed on the basis of the changes in electronic structure of the electrode surfaces.

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Authors and Affiliations

  1. Emeritus Professor, Faculty of Engineering, Hokkaido University, Sapporo, Japan

    Masahiro Seo

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  1. Masahiro Seo
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Correspondence to Masahiro Seo .

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Seo, M. (2020). Potential- or Adsorbate-Induced Changes in Surface Stress of Solid Metal Electrode, and Surface Stress versus Surface Charge Density or Potential versus Surface Elastic Strain. In: Electro-Chemo-Mechanical Properties of Solid Electrode Surfaces. Springer, Singapore. https://doi.org/10.1007/978-981-15-7277-7_3

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