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Combustion Synthesized MLi2Ti6O14 (M = Sr, Ba, Pb) Titanate Anodes for Lithium-Ion Batteries

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Abstract

Three isostructural MLi2Ti6O14 (M = Sr, Ba and Pb) titanates with an orthorhombic structure have been considered as anodes for lithium-ion batteries. Phase pure white titanate powders were prepared using a rapid two-step solution combustion method. Morphology and electrochemical activity of the titanate powders have been comparatively studied. 3 Li+ could be reversibly intercalated in SrLi2Ti6O14 and BaLi2Ti6O14, while more than 4 lithium per formula unit (160 mAh/g) could be (de)inserted with distinct three-step profile in PbLi2Ti6O14. Combustion made MLi2Ti6O14 form a robust family of anode materials for Li-ion batteries.

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Acknowledgements

The authors acknowledge financial support from Shell Technology Center (STC) Bangalore.

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Correspondence to Anshuman Chaupatnaik .

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Chaupatnaik, A., Barpanda, P. (2021). Combustion Synthesized MLi2Ti6O14 (M = Sr, Ba, Pb) Titanate Anodes for Lithium-Ion Batteries. In: Sharma, Y., Varma, G.D., Mukhopadhyay, A., Thangadurai, V. (eds) Recent Research Trends in Energy Storage Devices. Springer, Singapore. https://doi.org/10.1007/978-981-15-6394-2_2

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  • DOI: https://doi.org/10.1007/978-981-15-6394-2_2

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  • Print ISBN: 978-981-15-6393-5

  • Online ISBN: 978-981-15-6394-2

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