Abstract
Solid-state chiral organic luminophores bearing various functionalities have been successfully developed. These chiral luminophores can emit circularly polarized luminescence (CPL) when wrapped with organic polymer films or inorganic crystal pellet in the solid state. The chiroptical properties of these chiral luminophores in the solid state and solution state are different. In the solid state, a precise chiral arrangement of the fluorescent units in the luminescent molecule generates characteristic CPL that is not observed in the solution state.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Similar content being viewed by others
References
Kimoto, T., Amako, T., Tajima, N., Kuroda, R., Fujiki, M., Imai, Y.: Control of Solid-state Circularly Polarized Luminescence of Binaphthyl Organic Fluorophores through Environmental Changes. Asian J. Org. Chem. 2, 404–410 (2013)
Amako, T., Harada, T., Suzuki, N., Mishima, K., Fujiki, M., Imai, Y.: Solid-state circularly polarized luminescence and circular dichroism of viscous binaphthyl compounds. RSC Adv. 3, 23508–23513 (2013)
Nakabayashi, K., Amako, T., Tajima, N., Fujiki, M., Imai, Y.: Nonclassical dual control of circularly polarized luminescence modes of binaphthyl-pyrene organic fluorophores in fluidic and glassy media. Chem. Commun. 50, 13228–13230 (2014)
Kitayama, Y., Nakabayashi, K., Wakabayashi, T., Tajima, N., Fujiki, M., Imai, Y.: Circularly polarized luminescence of biaryl atropisomers: subtle but significant structural dependency. RSC Adv. 5, 410–415 (2015)
Amako, T., Nakabayashi, K., Sudo, A., Fujiki, M., Imai, Y.: Solid-state circularly polarised luminescence of atropisomeric fluorophores embedded in achiral myo-inositol-containing polyurethanes. Org. Biomol. Chem. 13, 2913–2917 (2015)
Amako, T., Nakabayashi, K., Suzuki, N., Guo, S., Abdul Rahim, N.A., Harada, T., Fujiki, M., Imai, Y.: Pyrene magic: chiroptical enciphering and deciphering 1,3-dioxolane bearing two wirepullings to drive two remote pyrenes. Chem. Commun. 51, 8237–8240 (2015)
Zheng, H., Li, W., Li, W., Wang, X., Tang, Z., Zhang, S.X., Xu, Y.: Uncovering the Circular Polarization Potential of Chiral Photonic Cellulose Films for Photonic Applications. Adv. Mater. 30, 1705948 (2018)
Zhao, B., Pan, K., Deng, J.: Combining chiral helical polymer with achiral luminophores for generating full-color, on-off, and switchable circularly polarized luminescence. Macromolecules 52, 376–384 (2019)
Jin, Q., Chen, S., Sang, Y., Guo, H., Dong, S., Han, J., Chen, W., Yang, X., Li, F., Duan, P.: Circularly polarized luminescence of achiral open-shell π-radicals. Chem. Commun. 55, 6583–6586 (2019)
Chen, Y., Li, X., Li, N., Quan, Y., Cheng, Y., Tang, Y.: Strong circularly polarized electroluminescence based on chiral salen-Zn(II) complex monomer chromophores. Mater. Chem. Front. 3, 867–873 (2019)
Kimoto, T., Tajima, N., Fujiki, M., Imai, Y.: Control of circularly polarized luminescence by open- and closed-type binaphthyl derivatives with the same axial chirality. Chem. Asian J 7, 2836–2841 (2012)
Sato, T., Tajima, N., Ueno, H., Harada, T., Fujiki, M., Imai, Y.: Binaphthyl luminophores with triphenylsilyl groups: Sign inversion of circularly polarized luminescence and circular dichroism. Tetrahedron 72, 7032–7038 (2016)
Taniguchi, N., Nakabayashi, K., Harada, T., Tajima, N., Shizuma, M., Fujiki, M., Imai, Y.: Circularly polarized luminescence of chiral binaphthyl with achiral terthiophene fluorophores. Chem. Lett. 44, 598–600 (2015)
Kono, Y., Nakabayashi, K., Kitamura, S., Kuroda, R., Fujiki, M., Imai, Y.: A comparison of circularly polarised luminescent BINAP and BINAPO as chiral binaphthyl luminophores. Tetrahedron 71, 3985–3989 (2015)
Taniguchi, A., Kaji, D., Hara, N., Murata, R., Akiyama, S., Harada, T., Sudo, A., Nishikawa, H., Imai, Y.: Solid-state aienh-circularly polarised luminescence of chiral perylene diimide fluorophores. RSC Adv. 9, 1976–1981 (2019)
Watanabe, K., Taniguchi, A., Kaji, D., Hara, N., Hosoya, T., Kanesaka, A., Harada, T., Nishikawa, H., Imai, Y.: Non-classical control of solid-state aggregation-induced enhanced circularly polarized luminescence in chiral perylene diimides. Tetrahedron 75, 2944–2948 (2019)
Nishiguchi, N., Kinuta, T., Nakano, Y., Harada, T., Tajima, N., Sato, T., Fujiki, M., Kuroda, R., Matsubara, Y., Imai, Y.: Control of solid-state chiral optical properties of a supramolecular organic fluorophore containing of 4-(2-arylethynyl)-benzoic acid. Chem. Asian J. 6, 1092–1098 (2011)
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2020 Springer Nature Singapore Pte Ltd.
About this chapter
Cite this chapter
Imai, Y. (2020). Circularly Polarized Luminescence from Solid-State Chiral Luminophores. In: Sakamoto, M., Uekusa, H. (eds) Advances in Organic Crystal Chemistry. Springer, Singapore. https://doi.org/10.1007/978-981-15-5085-0_16
Download citation
DOI: https://doi.org/10.1007/978-981-15-5085-0_16
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-15-5084-3
Online ISBN: 978-981-15-5085-0
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)