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Coconut Oil Plasticizer as a Replacement of Petroleum Oil in Natural Rubber Compound: Physical and Mechanical Properties

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Charting the Sustainable Future of ASEAN in Science and Technology

Abstract

Plasticizer that is derived from petroleum oil has been used commercially in rubber compounding especially in tyre industries. Despite its harmful effect to the environment, the urge to replace this nonrenewable source is needed. Coconut oil has a great potential as a natural plasticizer source. The aim of this study was to investigate the effectiveness on the physical and mechanical properties of natural rubber with different amounts of coconut oil (2, 4 and 6 phr). The rubber compounding was performed on a two-roll mill machine. The composition of fatty acid in the oil was examined by using gas chromatography flame ionization detector (GC-FID). The predominant saturated fatty acid was found to be lauric acid. Meanwhile, the natural rubber compound showed a significant reduction in cure time to 4.15 min and highest torque development at 8.67 dN m. In addition, the mechanical properties were significantly improved at 4 phr of coconut oil loading, which gave good tensile strength at 18.26 MPa and elongation at break for 1859.05%. The crosslink density was at 3.15 × 10−4 gm/mol/cm3. Therefore, coconut oil exhibits as one of the sustainable source for plasticizing oil and it is known to be environmentally friendly.

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References

  • Afiratul AA, Noriman NZ, Husin K, Sam ST, Ismail H, Mustafa Al Bakri AM, Omar MF, Norhafizah Z (2015) The addition of imperata cylindric as natural filler in epoxidized natural rubber filled recycled nitrile glove: cure characteristics and physical properties. Appl Mech Mater 815:39–43

    Google Scholar 

  • Aguele FO, Madufor CI (2012) Effects of carbonized coir on physical properties of natural rubber composites. Am J Polymer Science. 2(3):28–34

    Article  Google Scholar 

  • Bergaman C, Trimbach J (2014) Influence of plasticizer on the properties of natural rubber-based compounds. Prufen Und Mess Test Meas 40

    Google Scholar 

  • Bertrand Matthaus MM (2010) Lipid evaluation of cultivated and wild carob seed oil growing in Turkey. Sci Hortic 130:182

    Google Scholar 

  • Chigondo F, Shoko P, Nyamunda BC, Guyo U, Moyo M (2013) Maize stalk as reinforcement in natural rubber composite. Int J Sci Technol Res 2(6):263–271

    Google Scholar 

  • Ginting EM, Bukit N, Muliani, Frida E (2017) Mechanical properties and morphology natural rubber blend with bentonite and carbon black. In: innovation in polymer science and technology. IOP Publishing, Bristol, pp 1–7

    Google Scholar 

  • Gopala Krishna AG, Raj G, Bhatnagar AS, Prasant Kumar PK, Chandrashekar P (2010) Coconut oil in chemistry production and its applications. Indian Coconut J 16–18

    Google Scholar 

  • Gutierrez MC, Nunez-Santiago MDC, Romero-Bastida CA, Martinez-Bustos F (2014) Effect of coconut oil concentration as plasticizer as a surfactant in the preparation of extruded corn starch films. Starch 1079–1088

    Google Scholar 

  • Jamarani R, Erythropel CH, Nicell JA, Leask RL, Maric M (2018) How green is your plasticizer? Polymer 10:834

    Article  Google Scholar 

  • Kumpulan Ladang-ladang Perbadanan Kedah Sdn Bhd (2018). From standard Malaysia Rubber. http://www.klpk.com.my/smr-10-and-smr20/. Accessed 6 Oct 2018

  • Nasruddin, Susanto T (2018) The effect of natural based oil as plasticizer towards physics-mechanical properties of NR-SBR blending for solid tyres. In: The 6th international conference of the Indonesia Chemical Society. IOP Publishing, Bristol, pp 20–27

    Google Scholar 

  • Norwood, VM (2014). Introduction of Natural Oils into Rubber Compounds. In: Digital Commons@ East Tennessee State University, pp 10–43

    Google Scholar 

  • Patil U, Benjakul S (2018) Coconut milk and coconut oil: their manufacture associated with protein functionality. J Food Sci 83(1):1–9

    Article  Google Scholar 

  • Petrovic ZS, Ionescu M, Milic J, Halladay JR (2013) Soybean oil plasticizer as replacement of petroleum oil in rubber. Rubber Chem Technol 86(2):233–246

    Article  Google Scholar 

  • Raju NS (2007) A study on the use of coconut oil as plasticizer in natural rubber compounds. J Rubber Res 10(1):1–7

    Google Scholar 

  • Sears JK, Darby JK (1982) The Technology of Plasticizers. Wiley, New York

    Google Scholar 

  • Wilson AS (1995) Plasticizers principles and practice, 1st edn. Institute of Materials, London, England

    Google Scholar 

  • Zanchet A, Garcia PS, Nunes RCR, Crespo JS, Scuracchio CH (2016) Sustainable natural rubber compounds: naphthenic oil exchange for another alternativefrom renewable source. Int Ref J Eng Sci 5(12):2319

    Google Scholar 

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Correspondence to Farhana Othman .

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Othman, F., Ismail, N.A. (2020). Coconut Oil Plasticizer as a Replacement of Petroleum Oil in Natural Rubber Compound: Physical and Mechanical Properties. In: Alias, N., Yusof, R. (eds) Charting the Sustainable Future of ASEAN in Science and Technology . Springer, Singapore. https://doi.org/10.1007/978-981-15-3434-8_18

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  • DOI: https://doi.org/10.1007/978-981-15-3434-8_18

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  • Publisher Name: Springer, Singapore

  • Print ISBN: 978-981-15-3433-1

  • Online ISBN: 978-981-15-3434-8

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