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Biofuels from Renewable Biomass Resources: An Overview of Technologies for Production, Environmental and Economic Impacts

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Alternative Fuels and Their Utilization Strategies in Internal Combustion Engines

Abstract

In recent years, there is a great deal of social obligation involve with scientists to common people that a sustainable chemical processes having industrial importance which is associated with greener concept and environmentally benign methodology is the need of the hour. This trends of technology driven greener process will continues to roll on for next few decades. With this aspects in mind, biomass, a sustainable alternative feedstock, can be processed into liquid and solid fuels via thermal, light-induced, catalytic and bio-based techniques. Conversion of biomass materials into value added products and energy can address environmental sustainability and recycling of waste materials. Utilization of bio-based energy has not been explored fully. We continue to rely on fossil fuels, nuclear energy and hydroelectricity to meet our energy demands. Alcohols and its derivatives are the important source of bioenergy that are hidden in biomass. In this context, the production of alcohols or esters is an extremely important industrial process as they are useful as precursors, reagents, solvents or additives in perfumes, essential oils, food flavorings, cosmetics, etc. Even though there have been numerous methods available for the production of alcohols and esters, designing non-hazardous methods to generate chemical products that limit the usage of hazardous substances is highly required. The present chapter aims at the analysis of various green methods reported for the production of alcohols and esters from renewable energy sources. Also provide a broad overview of the environmental and economic impacts of biofuels. The major environmental impacts are conceived under two headings, viz. direct emissions those that are expelled during the biofuels production and consumption and indirect emissions those that are associated with their land use.

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References

  • Ali Y, Hanna MA, Leviticus LI (1995) Emissions and power characteristics of diesel engines on methyl soyate and diesel fuel blends. Biores Technol 52:185–195

    Article  Google Scholar 

  • Alonso DM, Bond JQ, Dumesic JA (2012) Catalytic conversion of biomass to biofuels. Green Chem 1493–1513

    Article  Google Scholar 

  • Anand K, Sharma RP, Mehta PS (2009) Experimental investigations on combustion, performance, and emissions characteristics of a neat biodiesel-fuelled, turbocharged, direct injection diesel engine. Proc IMechE: Part D – J Automobile Eng 224:661–679

    Article  Google Scholar 

  • Apostolakou AA, Kookos IK, Marazioti C, Angelopoulos K (2009) Techno-economic analysis of a biodiesel production process from vegetable oils. Fuel Process Technol 90:1023–1031

    Article  Google Scholar 

  • Appell HR, Fu YC, Friedman S, Yavorsky PM, Wender I (1971) Converting organic wastes to oil. US Burea of Mines Report of Investigation. No. 7560

    Google Scholar 

  • Balat M (2008) Mechanisms of thermochemical biomass conversion processes. Part 1: Reactions of pyrolysis. Energy Sources Part A 30:620–625

    Article  Google Scholar 

  • Bisio A, Boots S, Siegel P (eds) (1997) The Wiley encyclopedia of energy and the environment, vol I, II. Wiley, New York

    Google Scholar 

  • Canakci M (2005) Performance and emissions characteristics of biodiesel from soybean oil. Proc Int J Mech Eng, Part D: J Automobile Eng 219:1–8

    Google Scholar 

  • CARB (California Air Resources Board) (2009) California’s low carbon fuel standard final statement of reasons. Sacramento: State of California Environmental Protection Agency, Air Resources Board. http://www.arb.ca.gov/fuels/lcfs/010611lcfs_lutables.pdf

  • Chen G, Spliethoff H, Andries J, Glazer MP, Yang LB (2004) Biomass gasification in a circulating fluidised bed-Part I: preliminary experiments and modeling development. Energy Sources 26:485–498

    Article  Google Scholar 

  • Cheng CH, Cheung CS, Chan TL, Lee SC, Yao CD, Tsang KS (2008) Comparison of emissions of a direct injection diesel engine operating on biodiesel with emulsified and fumigated methanol. Fuel 87:1870–1879

    Article  Google Scholar 

  • Cheung CS, Zhu L, Huang Z (2009) Regulated and unregulated emissions from a diesel engine fueled with biodiesel and biodiesel blended with methanol. Atmos Environ 43:4865–4872

    Article  Google Scholar 

  • Chornet E, Overend RP (1985) Fundamentals of thermochemical biomass conversion. Elsevier, New York, pp 967–1002

    Chapter  Google Scholar 

  • Demirbas A (2000) Mechanisms of liquefaction and pyrolysis reactions of biomass. Energy Convers Manege 41:633–646

    Article  Google Scholar 

  • Demirbas A (2007) The influence of temperature on the yields of compounds existing in bio-oils obtaining from biomass samples via pyrolysis. Fuel Proc Technol 88:591–597

    Article  Google Scholar 

  • Demirbas A (2009) Biofuels (Chap. 6). In: Thermochemical conversion processes, Springer, Berlin, pp 261–304

    Google Scholar 

  • Demirbas A (2009b) Political, economic and environmental impacts of biofuels: a review. Appl Energy 86:S108–S117

    Article  Google Scholar 

  • Di Serio M, Ledda M, Cozzolino M, Minutillo G, Tesser R, Santacesaria E (2006) Ind Eng Chem Res 45:3009–3014

    Article  Google Scholar 

  • Dorado MP, Ballesteros E, Arnal AM, Gomez J, Gimenez FJL (2003) Testing waste olive oil methyl ester as a fuel in a diesel engine. Energy Fuels 17:1560–1565

    Article  Google Scholar 

  • Dudaa K, Wierzbickia S, Åšmiejaa M, Mikulski M (2018) Comparison of performance and emissions of a CRDI diesel engine fuelled with biodiesel of different origin. Fuel 212:202–222

    Article  Google Scholar 

  • Eggeman T, Elander RT (2005) Process and economic analysis of pretreatment technologies. In: Bioresoure technology, vol 96(18 SPEC. ISS.), pp 2019–2025. https://doi.org/10.1016/j.biortech.2005.01.017

    Article  Google Scholar 

  • Feng W, van der Kooi HJ, Arons JDS (2004) Biomass conversions in subcritical and supercritical water: driving force, phase equilibria, and thermodynamic analysis. Chem Eng Proc 43:1459–1467

    Article  Google Scholar 

  • Goudriaan F, Peferoen D (1990) Liquid fuels from biomass via a hydrothermal process. Chem Eng Sci 45:2729–2734

    Article  Google Scholar 

  • Graboski MS, McCormick RL (1998) Combustion of fat and vegetable oil derived fuels in diesel engines. Prog Energy Combust Sci 24:125–164

    Article  Google Scholar 

  • Granados ML, Poves MDZ, Alonso DM, Mariscal R, Galisteo FC, Moreno-Tost R, Santamaria J, Fierro JLG (2007) Appl Catal B 73:317–326

    Article  Google Scholar 

  • Gubicza K et al (2016) Techno-economic analysis of ethanol production from sugarcane bagasse using a liquefaction plus simultaneous saccharification and co-fermentation process. Bioresour Technol 208:42–48. https://doi.org/10.1016/j.biortech.2016.01.093 (Elsevier Ltd)

    Article  Google Scholar 

  • Haas MJ (2005) Improving the economics of biodiesel production through the use of low value lipids as feedstocks: vegetable oil soapstock. Fuel Process Technol 86:1087–1096

    Article  Google Scholar 

  • Hao H, Guo L, Zhang X, Guan Y (2005) Hydrogen production from catalytic gasification of cellulose in supercritical water. Chem Eng J 110:57–65

    Article  Google Scholar 

  • How HG, Masjuki HH, Kalam MA, Teoh YH (2018) Influence of injection timing and split injection strategies on performance, emissions, and combustion characteristics of diesel engine fueled with biodiesel blended fuels. Fuel 213:106–114

    Article  Google Scholar 

  • https://www.transportenvironment.org/publications/globiom-basis-biofuel-policy-post-2020. Accessed 29 May 19

  • Jomaa S (2001) Combined sludge treatment and production of useful organic by-products using hydrothermal oxidation, PhD thesis. Brisbane, Australia: Department of Civil Engineering, Queensland University of Technology

    Google Scholar 

  • Jomaa S, Shanableh A, Khalil W, Trebilco B (2003) Hydrothermal decomposition and oxidation of the organic component of municipal and industrial waste products. Adv Environ Res 7:647–653

    Article  Google Scholar 

  • Khatiwada D, Venkata BK, Silveira S, Johnson FX (2016) Energy and GHG balances of ethanol production from cane molasses in Indonesia. Appl Energy 164:756–768. https://doi.org/10.1016/j.apenergy.2015.11.032

    Article  Google Scholar 

  • Kim HJ, Kang BS, Kim MJ, Park YM, Kim DK, Lee JS, Lee KY (2004) Catal Today 93–95:315–320

    Article  Google Scholar 

  • Lin CY, Lin HA (2006) Diesel engine performance and emission characteristics of biodiesel produced by the peroxidation process. Fuel 85:298–305

    Article  Google Scholar 

  • Liu B, Zhang Z (2016) Catalytic conversion of biomass into chemicals and fuels over magnetic catalysts. ACS Catalysis 61:326–338

    Article  Google Scholar 

  • Lotero E, Liu YJ, Lopez DE, Suwannakarn K, Bruce DA, Goodwin JG (2005) Ind Eng Chem Res 44:5353–5363

    Article  Google Scholar 

  • Marchetti JM, Miguel VU, Errazu AF (2008) Techno-economic study of different alternatives for biodiesel production. Fuel Process Technol 89:740–748

    Article  Google Scholar 

  • Mccormick RL, Graboski MS, Alleman TL, Herring AM, Tyson KS (2001) Impact of biodiesel source material and chemical structure on emissions of criteria pollutants from a heavy-duty engine. Environ Sci Technol 35:1742–1747

    Article  Google Scholar 

  • Melero JA, Iglesias J, Morales G (2009) Green Chem 11:1285–1308

    Article  Google Scholar 

  • Monyem A, Van Gerpen JH (2001) The effect of biodiesel oxidation on engine performance and emissions. Biomass Bioenerg 20:317–325

    Article  Google Scholar 

  • Owusu PA, Asumadu-Sarkodie S (2016) A review of renewable energy sources, sustainability issues and climate change mitigation. J Cogent Eng 3:1–14

    Google Scholar 

  • Plevin RJ et al (2010) The greenhouse gas emissions from indirect land use change are uncertain, but potentially much greater than previously estimated. Environ Sci Technol 44(21):1–19

    Article  Google Scholar 

  • Qi DH, Chen H, Matthews RD, Bian YZH (2010) Combustion and emission characteristics of ethanol–biodiesel–water micro-emulsions used in a direct injection compression ignition engine. Fuel 89:958–964

    Article  Google Scholar 

  • Rajagopal D, Hochman G, Zilberman D (2011) Indirect fuel use change (IFUC) and the lifecycle environmental impact of biofuel policies. Energy Policy 39(1):228–233. https://doi.org/10.1016/j.enpol.2010.09.035 (Elsevier)

    Article  Google Scholar 

  • Rajkumar S, Thangaraja J (2019) Effect of biodiesel, biodiesel binary blends, hydrogenated biodiesel and injection parameters on NOx and soot emissions in a turbocharged diesel engine. Fuel 240:101–118 (Elsevier). https://doi.org/10.1016/j.fuel.2018.11.141

    Article  Google Scholar 

  • Silva FND, Prata AS, Teixeira JR (2003) Technical feasibility assessment of oleic sunflower methyl ester utilization in diesel bus engines. Energy Convers Manage 44:2857–2878

    Article  Google Scholar 

  • Stevens DJ (2001) Hot gas conditioning: recent progress with larger-scale biomass gasification systems. National Renewable Energy Laboratory, NREL/SR-510-29952, 1617

    Google Scholar 

  • Szybist JP, Song J, Alam M, Boehman AL (2007) Biodiesel combustion, emissions and emission control. Fuel Process Technol 88:679–691

    Article  Google Scholar 

  • Usta N (2005) Use of tobacco seed oil methyl ester in a turbocharged indirect injection diesel engine. Biomass Bioenergy 28:77–86

    Article  Google Scholar 

  • Warnecke R (2000) Gasification of biomass: comparison of fixed bed and fluidized bed gasifier. Biomass Bioenergy 18:489–497

    Article  Google Scholar 

  • Yilmaz N (2012) Comparative analysis of biodiesel-ethanol-diesel and biodiesel-methanol-diesel blends in a diesel engine. Energy, 1–4

    Google Scholar 

  • Yilmaz N, Sanchez TM (2012) Analysis of operating a diesel engine on biodiesel-ethanol and biodiesel-methanol blends. Energy, 1–4

    Google Scholar 

  • Yung MM (2016) Catalytic conversion of biomass to fuels and chemicals. Top Catal 59:1

    Article  Google Scholar 

  • Yusri IM et al (2017) Alcohol based automotive fuels from first four alcohol family in compression and spark ignition engine: a review on engine performance and exhaust emissions. Renew Sustain Energy Rev 77:169–181. https://doi.org/10.1016/j.rser.2017.03.080

    Article  Google Scholar 

  • Zhang Y, Dube M, McLean D, Kates M (2003) Biodiesel production from waste cooking oil: 2. Economic assessment and sensitivity analysis. Bioresour Technol 90:229–240

    Article  Google Scholar 

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Thangaraja, J., Sivaramakrishna, A., Desikan, R. (2020). Biofuels from Renewable Biomass Resources: An Overview of Technologies for Production, Environmental and Economic Impacts. In: Singh, A., Sharma, Y., Mustafi , N., Agarwal , A. (eds) Alternative Fuels and Their Utilization Strategies in Internal Combustion Engines. Energy, Environment, and Sustainability. Springer, Singapore. https://doi.org/10.1007/978-981-15-0418-1_3

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  • DOI: https://doi.org/10.1007/978-981-15-0418-1_3

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