Network Structures and Thermal Characteristics of Bi2O3–SiO2–B2O3 Glass Powder by Sol-Gel

  • Peixian Li
  • Gecheng YuanEmail author
  • Zhenghua Lu
  • Qian Li
  • Qiguang Wu
Conference paper
Part of the Springer Proceedings in Physics book series (SPPHY, volume 216)


Glass powder of Bi2O3–SiO2–B2O3 was prepared by Sol-Gel method, and the powder was heated to the temperature range from 200 to 800 °C to study the network structures formed during heat treatment. The effect of structures change of the glass powders on the transition temperature and sintering softening properties was analyzed. The results indicate that Bi3+ get into the network structure with the rising of heat treatment temperature, [BiO6] octahedral and [BiO3] triangle, [BO4] tetrahedron and [BO3] triangle connected with [SiO4] tetrahedron separately in the way of vertex connecting to build the network structures. The O1s and Bi4f binding energies increase gradually while the B1s binding energies decrease, which strengthen the stability of glass structure. This causes an increase in the transition temperature and a decrease in the wettability of the glass powder. The glass powders treated at 600 °C have excellent sintering properties. The glass transition temperature (Tg) is about 542, and the thermal expansion coefficient (25–300 °C) is close to 6.57 × 10−6/°C.



This work was financially supported by Guangdong Provincial Natural Science Fund of China (Nos. 2006B14701003) and Guangzhou Science and Technology Project of China (Nos. 2015110010034).


  1. 1.
    Y.U. Xiaojun, Z.H.U. Lihui et al., Effects of Bi2O3 on structure and properties of Al2O3-ZnO-Bi2O3-B2O3 low-melting glasses. Electron. Compon. Mat. 32(9), 12–14 (2013)Google Scholar
  2. 2.
    H.E. Feng, D.E.N.G. Dawei, W.A.N.G. Jun, Effect of Bi2O3 contents on sintering property of Bi2O3-ZnO-B2O3 system low-melting electronic sealing glass. J. Wuhan Univ. Technol. 31(22), 1–4 (2009)Google Scholar
  3. 3.
    Z. Hongping, Z. Renjie, Effects of CuO on structure and heat treatment of Bi2O3-B2O3-ZnO glasses. J. Ceram. 31(4), 569–574 (2010)Google Scholar
  4. 4.
    J. Cheng, F. Chen, S. Dai, et al., Vitreous network formation and optical characteristics of glasses within Bi2O3—B2O3 binary system. J. Chin. Ceram. Soc. 41(4), 475–479 (2013)Google Scholar
  5. 5.
    Y. Huang, Y. Li, J. Wang, et al., Network structures and characteristics of Bi2O3-ZnO-B2O3 Ternary system glasses. J. Chin. Ceram. Soc. 43(7), 998–1001 (2015)Google Scholar
  6. 6.
    S. Shruti, A.J. Salinas, G. Malavasi et al., Structural and in vitro study of cerium, gallium and zinc containing Sol-Gel bioactive glasses. J. Mater. Chem. 22(27), 13698–13706 (2012)CrossRefGoogle Scholar
  7. 7.
    J. Chen, W. Que, Y. Xing et al., Molecular level-based bioactive glass-poly (caprolactone) hybrids monoliths with porous structure for bone tissue repair. Ceram. Int. 41(2), 3330–3334 (2015)CrossRefGoogle Scholar
  8. 8.
    B.B. Das, A. Srinivassan, M. Yogapriya, et al., Sol–gel synthesis and characterization of xCuO-(1-x)Bi2O3 (0.15 ≤ x ≤ 0.55) glasses by magnetic and spectral studies. J. Non-Cryst. Solids 427, 146–151 (2015)Google Scholar
  9. 9.
    M. Wang., Investigation of the structure evolution process in sol–gel derived CaO-B2O3-SiO2 glass ceramics. J. Non-Cryst. Solids 357, 1160–1163 (2011)Google Scholar
  10. 10.
    X. Zhu, C. Mai, M. Li, Effects of B2O3 content variation on the Bi ions in Bi2O3- B2O3- SiO2 glass structure. J. Non-Cryst. Solids 388, 55–61 (2014)CrossRefGoogle Scholar
  11. 11.
    H. Fan, Infrared, Raman and XPS spectroscopic studies of Bi2O3-B2O3-GeO2 glasses. Solid State Sci. 12(4), 541–545 (2010)CrossRefGoogle Scholar
  12. 12.
    Y. Zhang, Y. Yang, J. Zheng et al., Effects of oxidizing additives on optical properties of Bi2O3-B2O3-SiO2 glasses. J. Am. Ceram. Soc. 91(10), 3410–3412 (2008)CrossRefGoogle Scholar
  13. 13.
    I. Ardelean, S. Cora, FTIR and Raman investigations of MnO-B2O3-Bi2O3. Optoelectron. Adv. Mater. 12(2), 239–243 (2010)Google Scholar
  14. 14.
    H.W. Nesbitt, G.M. Bancroft, et al., Bridging, non-brifging free (O2-) oxygen in Na2O-SiO2 glasses. J. Non-Cryst. Solids 1(357), 173–175 (2011)Google Scholar
  15. 15.
    L.E. Yingfeng, Y.U.A.N. Gecheng, L.I. Qian et al., Thermal properties of Bi2O3-SiO2-B2O3-Zn O-Al2O3 glass powders prepared by sol-gel method. China Powder Sci. Technol. 23(1), 85–87 (2017)Google Scholar
  16. 16.
    D.I.N.G. Kanjunjie, C.H.E.N. Nan, Preparation, structures, thermal properties and sintering behaviors of B2O3-SiO2-ZnO-BaO-Al2O3 glass. J. Wuhan Univ. Technol. Mater 31(6), 1323–1328 (2016)CrossRefGoogle Scholar

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© Springer Nature Singapore Pte Ltd. 2019

Authors and Affiliations

  • Peixian Li
    • 1
  • Gecheng Yuan
    • 1
    Email author
  • Zhenghua Lu
    • 1
  • Qian Li
    • 1
  • Qiguang Wu
    • 2
  1. 1.School of Materials and EnergyGuangdong University of TechnologyGuangdong, GuangzhouChina
  2. 2.Analysis and Test Center, Guangdong University of TechnologyGuangzhouChina

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