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Synthesis of Polysaccharides II: Phosphorylase as Catalyst

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Enzymatic Polymerization towards Green Polymer Chemistry

Part of the book series: Green Chemistry and Sustainable Technology ((GCST))

Abstract

Oligo- and polysaccharides are important macromolecules in living systems, showing their multifunctional characteristics in the construction of cell walls, energy storage, cell recognition, and their immune response. The chemical synthesis of oligo- and polysaccharides is feasible though it can be laborious since multiple protection, deprotection, and purification steps are required. In contrast to this, phosphorylases are useful synthetic tools for the preparation of natural oligo- and polysaccharides, glycoconjugates, and their analogs. Since phosphorylases are rather tolerant with respect to utilizing modified donors and acceptor substrates, they can be used to prepare oligo- and polysaccharide analogs and for diversification of natural products. Their strict primer-dependence allows synthesis of interesting hybrid materials. Furthermore, enzymatic reaction, such as that using phosphorylase, is one of the most promising environmentally benign technologies with a simple operation under mild conditions, eliminating undesirable side reactions.

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Authors and Affiliations

  1. Macromolecular Chemistry and New Polymeric Materials, Zernike Institute for Advanced Materials, University of Groningen, Groningen, The Netherlands

    Katja Loos

  2. Department of Chemistry, Biotechnology, and Chemical Engineering, Graduate School of Science and Engineering, Kagoshima University, Kagoshima, Japan

    Jun-ichi Kadokawa

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  1. Katja Loos
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  1. Kyoto University, Yoshida-honmachi, Sakyo-ku, Kyoto, Japan

    Shiro Kobayashi

  2. Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Japan

    Hiroshi Uyama

  3. Department of Chemistry, Biotechnology, and Chemical Engineering, Graduate School of Science and Engineering, Kagoshima University, Kagoshima, Japan

    Jun-ichi Kadokawa

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Loos, K., Kadokawa, Ji. (2019). Synthesis of Polysaccharides II: Phosphorylase as Catalyst. In: Kobayashi, S., Uyama, H., Kadokawa, Ji. (eds) Enzymatic Polymerization towards Green Polymer Chemistry. Green Chemistry and Sustainable Technology. Springer, Singapore. https://doi.org/10.1007/978-981-13-3813-7_3

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