Abstract
This chapter provides introductory aspects to the readers so that they may understand readily and clearly the significance of the book edition. It is important for polymer chemists to know the present status of “enzymatic polymerization” and “green polymer chemistry.” The former involves its historical background and characteristics including enzymatic reaction mechanism. The latter is related with several important “green” aspects, toward which the former is expected to contribute. Brief abstracts of all the chapters are also given for the easier understanding of the whole book.
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References
Payen A, Persoz J-F (1833) Memoir on diastase, the principal products of its reaction, and their application to the industrial arts. Ann Chim Phys 2nd Ser 53:73–92
Sym EA (1936) A method for enzymatic ester synthesis. Enzymologia 1:156–160
Jones JB (1986) Enzymes in organic-synthesis. Tetrahedron 42:3351–3403
Klibanov AM (1990) Asymmetric transformations catalyzed by enzymes in organic-solvents. Acc Chem Res 23:114–120
Wong CH, Whitesides GMP (1994) Enzymes in synthetic organic chemistry. Pergamon, Oxford
Kobayashi S, Shoda S, Uyama H (1995) Enzymatic polymerization and oligomerization. Adv Polym Sci 121:1–30
Kobayashi S, Uyama H, Kimura S (2001) Enzymatic polymerization. Chem Rev 101:3793–3818
Kobayashi S, Shoda S, Uyama H (1996) Enzymatic polymerization. In: Salamone JC (ed) Polymeric materials encyclopedia. CRC Press Inc, Boca Raton, pp 2102–2107
Kobayashi S, Shoda S, Uyama H (1997) Enzymatic catalysis. In: Kobayashi S (ed) Catalysis in precision polymerization. Wiley, Chichester, pp 417–441
Kobayashi S (1999) Enzymatic polymerization: a new method of polymer synthesis. J Polym Sci Polym Chem 37:3041–3056
Kobayashi S, Uyama H (1999) Biocatalytical routes to polymers. In: Schlueter AD (ed) Material science and technology-synthesis of polymers, vol 54. Wiley-VCH, Weinheim, pp 549–569
Kobayashi S, Uyama H, Ohmae M (2001) Enzymatic polymerization for precision polymer synthesis. Bull Chem Soc Jpn 74:613–635
Gross RA, Kumar A, Kalra B (2001) Polymer synthesis by in vitro enzyme catalysis. Chem Rev 101:2097–2124
Kobayashi S, Uyama H (2002) Enzymatic polymerization to polyesters. In: Doi Y, Steinbüchel A (eds) Handbook of biopolymers, polyesters I, vol 3a. Wiley-VCH, Weinheim, pp 373–400
Kobayashi S, Uyama H (2003) Enzymatic polymerization. In: Kroschwitz JI (ed) Encyclopedia of polymer science and technology, 3rd edn. Wiley, New York, pp 328–364
Cheng HN, Gross RA (eds) (2005) Polymer biocatalysis and biomaterials. ACS symposium series 900. American Chemical Society, Washington, DC
Kobayashi S, Ritter H, Kaplan D (eds) (2006) Enzyme-catalyzed synthesis of polymers. Advances in polymer science, vol 194. Springer, Berlin
Kobayashi S, Makino A (2009) Enzymatic polymer synthesis: an opportunity for green polymer chemistry. Chem Rev 109:5288–5353
Kobayashi S (2010) Lipase-catalyzed polyester synthesis – a green polymer chemistry. Proc Jpn Acad Ser B 86:338–365
Kadokawa J, Kobayashi S (2010) Polymer synthesis by enzymatic catalysis. Curr Opin Chem Biol 14:145–153
Cheng HN, Gross RA (eds) (2010) Green polymer chemistry: biocatalysis and biomaterials. ACS symposium series 1043. American Chemical Society, Washington, DC
Palmans ARA, Heise A, Guebitz GM (eds) (2010) Enzymatic polymerisation, Advances in polymer science, vol 237. Springer, Berlin
Loos K (ed) (2011) Biocatalysis in polymer chemistry. Wiley-VCH, Weinheim
Kadokawa J (2011) Precision polysaccharide synthesis catalyzed by enzymes. Chem Rev 111:4308–4345
Kobayashi S (2012) Enzymatic polymerization. In: Matyjaszewski K, Moeller M (eds) Polymer science: a comprehensive reference, vol 5. Elsevier, Amsterdam, pp 217–237
Kobayashi S (2013) Green polymer chemistry: recent developments. Adv Polym Sci 262:141–166
Kobayashi S (2014) Enzymatic polymerization. In: Seidel A (ed) Encyclopedia of polymer science and technology, 4th edn. Wiley, Hoboken, pp 221–292
Cheng HN, Gross RA, Smith PB (eds) (2015) Green polymer chemistry: bio-based materials and biocatalysis. ACS symposium series 1192. American Chemical Society, Washington, DC
Shoda S, Kobayashi A, Kobayashi S (2015) Production of polymers by white biotechnology. In: Coelho MAZ, Ribeiro BD (eds) White biotechnology for sustainable chemistry. Royal Society of Chemistry, Cambridge, pp 274–309
Shoda S, Uyama H, Kadokawa J et al (2016) Enzymes as green catalysts for precision macromolecular synthesis. Chem Rev 116:2307–2413
Staudinger H, Johner H, Singer R et al (1927) Polymerized formaldehyde, a model of cellulose. Z Phys Chem 126:425–448
Percec V (ed) (2013) Special issues on “hierarchical macromolecular structures: 60 years after the staudinger nobel prize”, Advances in polymer science, vol 261/262. Springer, Cham/New York
Taylor HS, Jones WH (1930) The thermal decomposition of metal alkyls in hydrogen-ethylene mixtures. J Am Chem Soc 52:1111–1121
Carothers WH (1931) Polymerization. Chem Rev 8:353–426
Meerwein H (1955) Organic ionic reactions. Angew Chem 67:374–380
Williams G (1940) Kinetics of the catalyzed polymerization of styrene. III. The mechanism of the metal chloride catalysis. J Chem Soc:775–789
Ziegler K, Holzkamp E, Breil H et al (1955) The mulheim normal pressure polyethylene process. Angew Chem Int Ed 67:541–547
Natta G, Pino P, Corradini P et al (1955) Crystalline high polymers of α-olefins. J Am Chem Soc 77:1708–1710
Boor J (1979) Ziegler-Natta catalysts and polymerizations. Academic Press, New York
Szwarc M (1956) Living polymers. Nature 178:1168–1169
Merrifield RB (1963) Solid phase peptide synthesis. I. The synthesis of a tetrapeptide. J Am Chem Soc 85:2149–2154
Lehn JM (2002) Supramolecular polymer chemistry- scope and perspectives. Polym Int 51:825–839
Shirakawa H, Louis EJ, Macdiarmid AG et al (1977) Synthesis of electrically conducting organic polymers – halogen derivatives of polyacetylene, (CH)X. J Chem Soc Chem Commun:578–580
Trnka TM, Grubbs RH (2001) The development of L2X2Ru = CHR olefin metathesis catalysts: an organometallic success story. Acc Chem Res 34:18–29
Schrock RR (2002) High oxidation state multiple metal-carbon bonds. Chem Rev 102:145–179
International union of biochemistry and molecular biology. Nomenclature committee., Webb EC (1992) Enzyme nomenclature 1992: recommendations of the nomenclature committee of the international union of biochemistry and molecular biology on the nomenclature and classification of enzymes. Published for the International Union of Biochemistry and Molecular Biology by Academic Press, San Diego
Jiang Y, Loos K (2016) Enzymatic synthesis of bio-based polyesters and polyamides. Polymers 8:243. https://doi.org/10.3390/polym8070243
Fischer E (1894) Einfluss der Configuration auf die Wirkung der Enzyme. Ber Dtsch Chem Ges 27:2985–2993
Pauling L (1946) Molecular architecture and biological reactions. Chem Eng News 24:1375–1377
Kollman PA, Kuhn B, Donini O et al (2001) Elucidating the nature of enzyme catalysis utilizing a new twist on an old methodology: quantum mechanical – free energy calculations on chemical reactions in enzymes and in aqueous solution. Acc Chem Res 34:72–79
Borman S (2004) Much ado about enzyme mechanisms. Chem Eng News 82:35–39
Alberts B, Bray D, Lewis J et al (1994, Chapter 3) Molecular biology of the cell, 3rd edn. Newton Press, New York
Lerner RA, Benkovic SJ, Schultz PG (1991) At the crossroads of chemistry and immunology – catalytic antibodies. Science 252:659–667
Kobayashi S, Kiyosada T, Shoda S (1996) Synthesis of artificial chitin: irreversible catalytic behavior of a glycosyl hydrolase through a transition state analogue substrate. J Am Chem Soc 118:13113–13114
Anastas PT, Warner JC (1998) Green chemistry: theory and practice. Oxford University Press, Oxford
Kobayashi S (1999) Enzymatic polymerization: synthesis of artificial macromolecules catalyzed by natural macromolecules. High Polym Jpn 48:124–127
Puskas JE, Sen MY, Seo KS (2009) Green polymer chemistry using nature’s catalysts, enzymes. J Polym Sci Polym Chem 47:2959–2976
Gandini A (2011) The irruption of polymers from renewable resources on the scene of macromolecular science and technology. Green Chem 13:1061–1083
Kobayashi S (2015) Enzymatic ring-opening polymerization and polycondensation for the green synthesis of polyesters. Polym Adv Technol 26:677–686
Kobayashi S (2017) Green polymer chemistry: new methods of polymer synthesis using renewable starting materials. Struct Chem 28:461–474
Lee JH, Brown RM, Kuga S et al (1994) Assembly of synthetic cellulose-I. Proc Natl Acad Sci U S A 91:7425–7429
Kobayashi S, Okamoto E, Wen X et al (1996) Chemical synthesis of native-type cellulose and its analogues via enzymatic polymerization. J Macromol Sci Pure Appl Chem A33:1375–1384
Kobayashi S, Shoda S, Wen X et al (1997) Choroselective enzymatic polymerization for synthesis of natural polysaccharides. J Macromol Sci Pure Appl Chem A34:2135–2142
Kobayashi S, Uyama H, Takamoto T (2000) Lipase-catalyzed degradation of polyesters in organic solvents, a new methodology of polymer recycling using enzyme as catalyst. Biomacromolecules 1:3–5
Ebata H, Toshima K, Matsumura S (2000) Lipase-catalyzed transformation of poly(e-caprolactone) into cyclic dicaprolactone. Biomacromolecules 1:511–514
Takahashi Y, Okajima S, Toshima K et al (2004) Lipase-catalyzed transformation of poly(lactic acid) into cyclic oligomers. Macromol Biosci 4:346–353
Osanai Y, Toshima K, Matsumura S (2003) Enzymatic degradation of poly(R,S-3-hydroxybutanoate) to cyclic oligomers under continuous flow. Green Chem 5:567–570
Numata K, Srivastava RK, Finne-Wistrand A et al (2007) Branched poly(lactide) synthesized by enzymatic polymerization: effects of molecular branches and stereochernistry on enzymatic degradation and alkaline hydrolysis. Biomacromolecules 8:3115–3125
Shirke AN, White C, Englaender JA et al (2018) Stabilizing leaf and branch compost cutinase (LCC) with glycosylation: mechanism and effect on PET hydrolysis. Biochemistry 57:1190–1200
Igarashi K, Uchihashi T, Koivula A et al (2011) Traffic jams reduce hydrolytic efficiency of cellulase on cellulose surface. Science 333:1279–1282
Igarashi K, Uchihashi T, Uchiyama T et al (2014) Two-way traffic of glycoside hydrolase family 18 processive chitinases on crystalline chitin. Nat Commun 5:3975
Negoro S, Shibata N, Tanaka Y et al (2012) Three-dimensional structure of nylon hydrolase and mechanism of nylon-6 hydrolysis. J Biol Chem 287:5079–5090
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Kobayashi, S., Uyama, H., Kadokawa, Ji. (2019). Introduction. In: Kobayashi, S., Uyama, H., Kadokawa, Ji. (eds) Enzymatic Polymerization towards Green Polymer Chemistry. Green Chemistry and Sustainable Technology. Springer, Singapore. https://doi.org/10.1007/978-981-13-3813-7_1
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DOI: https://doi.org/10.1007/978-981-13-3813-7_1
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