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Energy Sustainability Through the Use of Thermoelectric Materials in Waste Heat Recovery Systems Recent Developments and Challenges

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Energy Sustainability in Built and Urban Environments

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Abstract

In many applications, only a reduced percentage (industrial processes 30–40%, internal combustion engines ICE 25%, photovoltaic systems PV 15%, etc.) of the primary energy is converted into useful energy. Increased energy efficiency can be realized through better performance of the involved devices, but also through the recovery of the energy losses. Partial recovery of the losses (mainly heat) may be done using mechanical means (turbines, Stirling generators, solar collectors), but still, the heat wasted to environment remains important. In this context, the thermoelectric generators (TEG) based on (novel) thermoelectric materials may offer a good alternative for heat recovery, since TEGs are static devices that in principle do not require maintenance and may work even in harsh environments, like, e.g., space, extreme cold, etc. Besides, TEGs can be used together with PV systems in hybrid installations to harvest more energy from the solar radiation. Up to date, expensive (due to complex manufacturing and scarcity of used materials) and not so efficient (due to low figure of merit ZT < 1 and inefficient MPPT techniques) TEGs have not been applied at large scale for low-grade heat recovery and for (solar) energy harvesting in smart buildings. However, in recent years, many research and development activities around TE-materials are going on worldwide and there is more pressure to increase the energy efficiency of many heat wasting processes and of (solar) energy harvesting in smart buildings. Potential of existent, commercially available TEGs and of emerging TEGs is investigated taking into account their properties, their past and emerging usage related to industrial and residential waste heat recovery and (solar) energy harvesting.

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References

  • Al-Madhhachi H, Min G (2017) Effective use of thermal energy at both hot and cold side of thermoelectric module for developing efficient thermoelectric water distillation system. Energy Convers Manag 133:14–19

    Google Scholar 

  • Angeline AA, Jayakumar J, Asirvatham LG, Marshal JJ, Wongwises S (2017) Power generation enhancement with hybrid thermoelectric generator using biomass waste heat energy. Exp Therm Fluid Sci 85:1–12

    Google Scholar 

  • Assadi MK, Bakhoda S, Saidur R, Hanaei H (2018) Recent progress in perovskite solar cells. Renew Sustain Energy Rev 81:2812–2822

    Google Scholar 

  • Baranowski LL, Snyder GJ, Toberer ES, Baranowski LL, Snyder GJ, Toberer ES (2013) Effective thermal conductivity in thermoelectric materials. J Appl Phys 204904:1–11

    Google Scholar 

  • Benday NS, Dryden DM, Kornbluth K, Stroeve P (2017) A temperature-variant method for performance modeling and economic analysis of thermoelectric generators: linking material properties to real-world conditions. Appl Energy 190:764–771

    Google Scholar 

  • Bharti M, Singh A, Samanta S, Aswal DK (2018) Conductive polymers for thermoelectric power generation. Prog Mater Sci 93:270–310

    Google Scholar 

  • Bine Information Service (2016) Thermoelectrics: power from waste heat, Themeninfo I, Jan 2017

    Google Scholar 

  • Borcuch M, Musiał M, Gumuła S, Sztekler K, Wojciechowski K (2017) Analysis of the fins geometry of a hot-side heat exchanger on the performance parameters of a thermoelectric generation system. Appl Therm Eng 127:1355–1363

    Google Scholar 

  • Champier D (2017) Thermoelectric generators: a review of applications. Energy Convers Manag 140:167–181

    Google Scholar 

  • Chandel SS, Agarwal T (2017) Review of cooling techniques using phase change materials for enhancing efficiency of photovoltaic power systems. Renew Sustain Energy Rev 73:1342–1351

    Google Scholar 

  • Chen WH, Wu PH, Lin YL (2018) Performance optimization of thermoelectric generators designed by multi-objective genetic algorithm. Appl Energy 209:211–223

    Google Scholar 

  • Cheng F et al (2017a) A thermoelectric generator for scavenging gas-heat: from module optimization to prototype test. Energy 121:545–560

    Google Scholar 

  • Cheng K, Qin J, Jiang Y, Lv C, Zhang S, Bao W (2017b) Performance assessment of multi-stage thermoelectric generators on hypersonic vehicles at a large temperature difference. Appl Therm Eng 141:456–466

    Google Scholar 

  • Cheng K, Feng Y, Lv C, Zhang S, Qin J, Bao W (2017c) Performance evaluation of waste heat recovery systems based on semiconductor thermoelectric generators for hypersonic vehicles. Energies 10(4)

    Google Scholar 

  • Cheng K, Zhang D, Qin J, Zhang S, Bao W (2018) Performance evaluation and comparison of electricity generation systems based on single- and two-stage thermoelectric generator for hypersonic vehicles. Acta Astronaut 151:15–21

    Google Scholar 

  • Contento G, Lorenzi B, Rizzo A, Narducci D (2017) Efficiency enhancement of a-Si and CZTS solar cells using different thermoelectric hybridization strategies. Energy 131:230–238

    Google Scholar 

  • Cottrill AL et al (2018) Ultra-high thermal effusivity materials for resonant ambient thermal energy harvesting. Nat Commun 9(1):1–11

    Google Scholar 

  • Cowen LM, Atoyo J, Carnie MJ, Baran D, Schroeder BC (2017) Review—organic materials for thermoelectric energy generation. ECS J Solid State Sci Technol 6(3):N3080–N3088

    Google Scholar 

  • Cui T, Xuan Y, Li Q (2016) Design of a novel concentrating photovoltaic-thermoelectric system incorporated with phase change materials. Energy Convers Manag 112:49–60

    Google Scholar 

  • Cui T, Xuan Y, Yin E, Li Q, Li D (2017) Experimental investigation on potential of a concentrated photovoltaic-thermoelectric system with phase change materials. Energy 122:94–102

    Google Scholar 

  • Demir ME, Dincer I (2017) Performance assessment of a thermoelectric generator applied to exhaust waste heat recovery. Appl Therm Eng 120:694–707

    Google Scholar 

  • Deng YD, Hu T, Su CQ, Yuan XH (2017) Fuel economy improvement by utilizing thermoelectric generator in heavy-duty vehicle. J Electron Mater 46(5):3227–3234

    Google Scholar 

  • Di Paolo Emilio M (2017) Microelectronic circuit design for energy harvesting systems

    Google Scholar 

  • El kamouny K et al (2018) Thermoelectric cooling micro-inverter for PV application. Sol Energy Mater Sol Cells 180:311–321

    Google Scholar 

  • Ferreira-Teixeira S, Pereira AM (2018) Geometrical optimization of a thermoelectric device: numerical simulations. Energy Convers Manag 169:217–227

    Google Scholar 

  • Fu Y, Zhang X, Liu H, Tian J, Zhang J (2018) Thermoelectric properties of Ag-doped compound: Mg3-xAgxSb2. J Mater 4(1):75–79

    Google Scholar 

  • Gaurav K, Pandey SK (2016) Efficiency calculation of thermoelectric generator using temperature dependent material’s properties, May 2016

    Google Scholar 

  • Gayner C, Kar KK (2016) Recent advances in thermoelectric materials. Prog Mater Sci 83:330–382

    Google Scholar 

  • Gong CL, Gou JJ, Hu JX, Gao F (2018) A novel TE-material based thermal protection structure and its performance evaluation for hypersonic flight vehicles. Aerosp Sci Technol 77:458–470

    Google Scholar 

  • Guo L, Lu Q (2017) Potentials of piezoelectric and thermoelectric technologies for harvesting energy from pavements. Renew Sustain Energy Rev 72:761–773

    Google Scholar 

  • Hajji M et al (2017) Photovoltaic and thermoelectric indirect coupling for maximum solar energy exploitation. Energy Convers Manag 136:184–191

    Google Scholar 

  • Hannan MA, Hoque MM, Mohamed A, Ayob A (2017) Review of energy storage systems for electric vehicle applications: issues and challenges. Renew Sustain Energy Rev 69:771–789

    Google Scholar 

  • Haras M et al (2015) Thermoelectric energy conversion: how good can silicon be? Mater Lett 157:193–196

    Google Scholar 

  • Hernandez H, Kofuji ST, Van Noije W (2013) Fully integrated boost converter for thermoelectric energy harvesting. In: 2013 IEEE 4th Latin American symposium on circuits and systems, pp 1–3

    Google Scholar 

  • HĂśgblom O, Andersson R (2016) A simulation framework for prediction of thermoelectric generator system performance. Appl Energy 180:472–482

    Google Scholar 

  • Huang K, Li B, Yan Y, Li Y, Twaha S, Zhu J (2017) A comprehensive study on a novel concentric cylindrical thermoelectric power generation system. Appl Therm Eng 117:501–510

    Google Scholar 

  • Hwang J et al (2017) More than half reduction in price per watt of thermoelectric device without increasing the thermoelectric figure of merit of materials. Appl Energy 205:1459–1466

    Google Scholar 

  • Iezzi B, Ankireddy K, Twiddy J, Losego MD, Jur JS (2017) Printed, metallic thermoelectric generators integrated with pipe insulation for powering wireless sensors. Appl Energy 208:758–765

    Google Scholar 

  • Jänsch D (2017) Energy and thermal management, air conditioning, waste heat recovery

    Google Scholar 

  • Jiang W et al (2017) Energy harvesting from asphalt pavement using thermoelectric technology. Appl Energy 205:941–950

    Google Scholar 

  • Ju C, Dui G, Zheng HH, Xin L (2017) Revisiting the temperature dependence in material properties and performance of thermoelectric materials. Energy 124:249–257

    Google Scholar 

  • Kang BO, Lee M, Kim Y, Jung J (2018) Economic analysis of a customer-installed energy storage system for both self-saving operation and demand response program participation in South Korea. Renew Sustain Energy Rev 94:69–83

    Google Scholar 

  • Kempf N, Zhang Y (2016) Design and optimization of automotive thermoelectric generators for maximum fuel efficiency improvement. Energy Convers Manag 121:224–231

    Google Scholar 

  • Kim TY, Negash A, Cho G (2017) Experimental and numerical study of waste heat recovery characteristics of direct contact thermoelectric generator. Energy Convers Manag 140:273–280

    Google Scholar 

  • Kirihara K, Wei Q, Mukaida M, Ishida T (2017) Thermoelectric power generation using nonwoven fabric module impregnated with conducting polymer PEDOT:PSS. Synth Met 225:41–48

    Google Scholar 

  • KĂźtt L, Millar J, Karttunen A, Lehtonen M, Karppinen M (2015) Thermoelectric applications for energy harvesting in domestic applications and micro-production units. Part I: thermoelectric concepts, domestic boilers and biomass stoves. Renew Sustain Energy Rev 1–26

    Google Scholar 

  • Lan S, Yang Z, Chen R, Stobart R (2018) A dynamic model for thermoelectric generator applied to vehicle waste heat recovery. Appl Energy 210:327–338

    Google Scholar 

  • Laux E et al (2016) Development of thermoelectric generator based on ionic liquids for high temperature applications. Eur. Conf. Thermoelectr. 5(4):10195–10202

    Google Scholar 

  • Lefèvre R, Berthebaud D, PĂŠrez O, Pelloquin D, Boudin S, Gascoin F (2017) Ultra-low thermal conductivity of TlIn5Se8and structure of the new complex chalcogenide Tl0.98In13.12Se16.7Te2.3. J Solid State Chem 250:114–120

    Google Scholar 

  • Lewandowski CM (2015) Modern theory of thermoelectricity. In: Effect of brief mindfulness intervention on acute pain experience: an examination of individual difference, vol 1

    Google Scholar 

  • Li C et al (2017a) A simple thermoelectric device based on inorganic/organic composite thin film for energy harvesting. Chem Eng J 320:201–210

    Google Scholar 

  • Li Y, Wang S, Zhao Y, Lu C (2017b) Experimental study on the influence of porous foam metal filled in the core flow region on the performance of thermoelectric generators. Appl Energy 207:634–642

    Google Scholar 

  • Liu D, Cai Y, Zhao FY (2017) Optimal design of thermoelectric cooling system integrated heat pipes for electric devices. Energy 128:403–413

    Google Scholar 

  • Lu W, Xiao R, Yang J, Li H, Zhang W (2017) Data mining-aided materials discovery and optimization. J Mater 3(3):191–201

    Google Scholar 

  • Makki A, Omer S, Sabir H (2015) Advancements in hybrid photovoltaic systems for enhanced solar cells performance. Renew Sustain Energy Rev 41:658–684

    Google Scholar 

  • Makki A, Omer S, Su Y, Sabir H (2016) Numerical investigation of heat pipe-based photovoltaic-thermoelectric generator (HP-PV/TEG) hybrid system. Energy Convers Manag 112:274–287

    Google Scholar 

  • Maolikul S, Kiatgamolchai S, Chavarnakul T (2017) Low-power energy harvesting of thermoelectric battery charger with step-up DC–DC converter: applicable case study for personal electronic gadgets. J Energy Eng 143(4):05017001

    Google Scholar 

  • Meng JH, Wang XD, Chen WH (2016) Performance investigation and design optimization of a thermoelectric generator applied in automobile exhaust waste heat recovery. Energy Convers Manag 120:71–80

    Google Scholar 

  • Mustafa KF, Abdullah S, Abdullah MZ, Sopian K (2017) A review of combustion-driven thermoelectric (TE) and thermophotovoltaic (TPV) power systems. Renew Sustain Energy Rev 71:572–584

    Google Scholar 

  • Nandhakumar I, White NM, Beeby S (2016) Thermoelectric materials and devices

    Google Scholar 

  • Negash A (2017) Direct contact thermoelectric generator (DCTEG): A concept for removing the contact resistance between thermoelectric modules and heat source. Energy Convers Manag 142:20–27

    Google Scholar 

  • Nesarajah M, Frey G (2016) Thermoelectric power generation: Peltier element versus thermoelectric generator. In: IECON Proceedings (Industrial Electronics Conference), pp 4252–4257

    Google Scholar 

  • Nesarajah M, Frey G (2017) Optimized design of thermoelectric energy harvesting systems for waste heat recovery from exhaust pipes. Appl Sci 7(6):634

    Google Scholar 

  • Omer G, Yavuz AH, Ahiska R (2017) Heat pipes thermoelectric solar collectors for energy applications. Int J Hydrog Energy 42(12):8310–8313

    Google Scholar 

  • Ong KS, Tan CF, Lai KC (2017) Methodological considerations of using thermoelectrics with fin heat sinks for cooling applications. Appl Sci 7(2):1–11

    MathSciNet  Google Scholar 

  • Orr B, Akbarzadeh A (2017) Prospects of waste heat recovery and power generation using thermoelectric generators. Energy Procedia 110:250–255

    Google Scholar 

  • Panayiotou GP et al (2017) Preliminary assessment of waste heat potential in major European industries. Energy Procedia 123:335–345

    Google Scholar 

  • Petsagkourakis I et al (2018) Correlating the Seebeck coefficient of thermoelectric polymer thin films to their charge transport mechanism. Org Electron Phys Mater Appl 52:335–341

    Google Scholar 

  • Poddar VS, Dhokey NB, Garbade RR, Butee SP, Prakash D, Purohit RD (2017) Rapid production of iron disilicide thermoelectric material by hot press sintering route. Mater Sci Semicond Process 71:477–481

    Google Scholar 

  • Rana S, Orr B, Iqbal A, Ding LC, Akbarzadeh A, Date A (2017) Modelling and optimization of low-temperature waste heat thermoelectric generator system. Energy Procedia 110:196–201

    Google Scholar 

  • Rehman NU, Siddiqui MA (2017) Performance model and sensitivity analysis for a solar thermoelectric generator. J Electron Mater 46(3):1794–1805

    Google Scholar 

  • Ren Z, Lan Y, Zhang Q (2017) Advanced thermoelectrics: materials, contacts, devices, and systems. In: Materials Science and Engineering, p 790. CRC Press. https://www.crcpress.com/Advanced-Thermoelectrics-Materials-Contacts-Devices-and-Systems/Ren-Lan-Zhang/p/book/9781498765725. ISBN 9781498765725. CAT# K29106

  • Rogl G, Rogl P (2017) How nanoparticles can change the figure of merit, ZT, and mechanical properties of skutterudites. Mater Today Phys 3:48–69

    Google Scholar 

  • Rogl G et al (2018) Nanostructuring as a tool to adjust thermal expansion in high ZT skutterudites. Acta Mater 145:359–368

    Google Scholar 

  • Sajid M, Hassan I, Rahman A (2017) An overview of cooling of thermoelectric devices. Renew Sustain Energy Rev 78:15–22

    Google Scholar 

  • Sathe TM, Dhoble AS (2017) A review on recent advancements in photovoltaic thermal techniques. Renew Sustain Energy Rev 76:645–672

    Google Scholar 

  • Savani I, Waage MH, Børset M, Kjelstrup S, Wilhelmsen Ø (2017) Harnessing thermoelectric power from transient heat sources: Waste heat recovery from silicon production. Energy Convers Manag 138:171–182

    Google Scholar 

  • Schwall M, Balke B (2018) On the Phase Separation in n-Type thermoelectric half-Heusler materials. Materials (Basel, Switzerland) 11(4):1–17

    Google Scholar 

  • Siddique ARM, Mahmud S, Van Heyst B (2017) A review of the state of the science on wearable thermoelectric power generators (TEGs) and their existing challenges. Renew Sustain Energy Rev 73:730–744

    Google Scholar 

  • Siouane S, Jovanović S, Poure P (2017) Equivalent electrical circuits of thermoelectric generators under different operating conditions. Energies 10(3)

    Google Scholar 

  • Skovajsa J, Koláček M, ZĂĄleĹĄĂĄk M (2017) Phase change material based accumulation panels in combination with renewable energy sources and thermoelectric cooling. Energies 10(2)

    Google Scholar 

  • Stobart R, Wijewardane MA, Yang Z (2017) Comprehensive analysis of thermoelectric generation systems for automotive applications. Appl Therm Eng 112:1433–1444

    Google Scholar 

  • Sun Y, Xu W, Di C, Zhu D (2017) Metal-organic complexes-towards promising organic thermoelectric materials. Synth Met 225:22–30

    Google Scholar 

  • Sun D, Shen L, Sun M, Yao Y, Chen H, Jin S (2018) An effective method of evaluating the device-level thermophysical properties and performance of micro-thermoelectric coolers. Appl Energy 219:93–104

    Google Scholar 

  • Tappura K (2018) A numerical study on the design trade-offs of a thin-film thermoelectric generator for large-area applications. Renew Energy 120:78–87

    Google Scholar 

  • Tuley R, Simpson K (2017) ZT optimization: an application focus. Materials (Basel) 10(3)

    Google Scholar 

  • Wang BL (2017) A finite element computational scheme for transient and nonlinear coupling thermoelectric fields and the associated thermal stresses in thermoelectric materials. Appl Therm Eng 110:136–143

    Google Scholar 

  • Wang X, Wang ZM (eds) (2014) Nanoscale thermoelectrics, vol 16

    Google Scholar 

  • Wang BL, Guo YB, Zhang CW (2016) Cracking and thermal shock resistance of a Bi2Te3 based thermoelectric material. Eng Fract Mech 152:1–9

    Google Scholar 

  • Wang C, CalderĂłn C, Wang YD (2017) An experimental study of a thermoelectric heat exchange module for domestic space heating. Energy Build 145:1–21

    Google Scholar 

  • Wang P, Wang KF, Wang BL, Cui YJ (2018) Effective thermoelectric conversion properties of thermoelectric composites containing a crack/hole. Compos Struct 191:180–189

    Google Scholar 

  • Wood L, Manager S (2018) Global thermoelectric energy harvesting market 2018–2028—technologies, devices & applications for thermoelectric generators–Research and Markets, pp 1–4

    Google Scholar 

  • Yang T, Xie D, Li Z, Zhu H (2017) Recent advances in wearable tactile sensors: materials, sensing mechanisms, and device performance. Mater Sci Eng R Rep 115:1–37

    Google Scholar 

  • Yusop AM, Mohamed R, Mohamed A (2016) Inverse dynamic analysis type of MPPT control strategy in a thermoelectric-solar hybrid energy harvesting system. Renew Energy 86:682–692

    Google Scholar 

  • Yusop AM, Mohamed R, Ayob A, Mohamed A (2017) Shapeable maximum-power point-tracking algorithm to improve the stability of the output behavior of a thermoelectric-solar hybrid energy-harvesting system. J Assoc Arab Univ Basic Appl Sci 22:1–8

    Google Scholar 

  • Zhang H et al (2016) The investigation of thermal properties on multilayer Sb2Te3/Au thermoelectric material system with ultra-thin Au interlayers. Superlattices Microstruct 89:312–318

    Google Scholar 

  • Zhang Z, Yue H, Chen D, Qin D, Chen Z (2017a) Machine-thermal coupling stresses analysis of the fin-type structural thermoelectric generator. J Electron Mater 46(5):3156–3165

    Google Scholar 

  • Zhang AB, Wang BL, Wang J, Du JK, Xie C, Jin YA (2017b) Thermodynamics analysis of thermoelectric materials: influence of cracking on efficiency of thermoelectric conversion. Appl Therm Eng 127:1442–1450

    Google Scholar 

  • Zhu DC, Su CQ, Deng YD, Wang YP, Liu X (2018) The influence of the inner topology of cooling units on the performance of automotive exhaust-based thermoelectric generators. J Electron Mater 47(6):3320–3329

    Google Scholar 

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Motoasca, E. (2019). Energy Sustainability Through the Use of Thermoelectric Materials in Waste Heat Recovery Systems Recent Developments and Challenges. In: Motoasca, E., Agarwal, A., Breesch, H. (eds) Energy Sustainability in Built and Urban Environments. Energy, Environment, and Sustainability. Springer, Singapore. https://doi.org/10.1007/978-981-13-3284-5_11

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