Skip to main content

Synthesis and Characterization of Geopolymers from Coal Gangue, Fly Ash and Red Mud

  • Conference paper
  • First Online:
Proceedings of the 8th International Congress on Environmental Geotechnics Volume 1 (ICEG 2018)

Part of the book series: Environmental Science and Engineering ((ENVENG))

Included in the following conference series:

Abstract

Geopolymers are inorganic aluminosilicate polymers which have been synthesized from pure sources and more recently, from industrial byproducts. In this study, the industrial by-products, coal gangue, fly ash and red mud were used to synthesize geopolymers at low and elevated temperatures. NaOH, which is often used to raise the pH of the mixture, has been partly replaced using red mud. The strength characteristics of geopolymers synthesized using binary mixtures of coal gangue and red mud as well as ternary mixtures of coal gangue, fly ash and red mud were examined. The compressive strength of the end products was determined using unconfined compression tests. The textural and morphological properties of the end products were also studied. The results reveal the influences of temperature and Si/Al and Na/Al ratios of the raw materials in the geopolymerization reactions and the subsequent development of strength, textural and morphological characteristics. The binary mixtures of coal gangue and red mud showed an increase in strength with curing temperature while the ternary mixtures of coal gangue, fly ash and red mud developed higher strength at lower curing temperatures.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 229.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 299.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 299.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Provis JL, Lukey GC, Van Deventer JSJ (2005) Do geopolymers actually contain nanocrystalline zeolites? a reexamination of existing results. Chem Mater 17(12):3075–3085

    Article  Google Scholar 

  2. Selmani S, Sdiri A, Bouaziz S, Joussein E, Rossignol S (2017) Effects of metakaolin addition on geopolymer prepared from natural kaolinitic clay. Appl Clay Sci 146:457–467

    Article  Google Scholar 

  3. Xu H, Van Deventer JSJ (2000) The geopolymerisation of alumino-silicate minerals. Int J Miner Process 59(3):247–266

    Article  Google Scholar 

  4. Badanoiu AI, Al Saadi THA, Stoleriu S, Voicu G (2015) Preparation and characterization of foamed geopolymers from waste glass and red mud. Constr Build Mater 84:284–293

    Article  Google Scholar 

  5. Bashar II, Alengaram UJ, Jumaat MZ, Islam A (2016) Development of sustainable geopolymer mortar using industrial waste materials. Mater Today: Proc 3(2):125–129

    Article  Google Scholar 

  6. Zhang M, Zhao M, Zhang G, Mann D, Lumsden K, Tao M (2016) Durability of red mud-fly ash based geopolymer and leaching behavior of heavy metals in sulfuric acid solutions and deionized water. Constr Build Mater 124:373–382

    Article  Google Scholar 

  7. Toniolo N, Boccaccini AR (2017) Fly ash-based geopolymers containing added silicate waste. A review. Ceram Int 43:14545–14551

    Article  Google Scholar 

  8. Koshy N, Singh DN (2016) Textural alterations in coal fly ash due to alkali activation. J Mater Civ Eng 28(11):04016126

    Article  Google Scholar 

  9. Jabłońska B, Kityk AV, Busch M, Huber P (2017) The structural and surface properties of natural and modified coal gangue. J Environ Manag 190:80–90

    Article  Google Scholar 

  10. Wu H, Wen Q, Hu L, Gong M, Tang Z (2017) Feasibility study on the application of coal gangue as landfill liner material. Waste Manag 63:161–171

    Article  Google Scholar 

  11. Geng J, Zhou M, Zhang T, Wang W, Wang T, Zhou X, Wang X, Hou H (2017) Preparation of blended geopolymer from red mud and coal gangue with mechanical co-grinding preactivation. Mater Struct 50(2):109

    Article  Google Scholar 

  12. Zhang M, El-Korchi T, Zhang G, Liang J, Tao M (2014) Synthesis factors affecting mechanical properties, microstructure, and chemical composition of red mud-fly ash based geopolymers. Fuel 134:315–325

    Article  Google Scholar 

  13. Geng JJ, Zhou M, Li Y, Chen Y, Han Y, Wan S, Zhou X, Hou H (2017) Comparison of red mud and coal gangue blended geopolymers synthesized through thermal activation and mechanical grinding preactivation. Constr Build Mater 153:185–192

    Article  Google Scholar 

  14. Zhang N, Liu X, Sun H, Li L (2011) Pozzolanic behaviour of compound-activated red mud-coal gangue mixture. Cem Concr Res 41(3):270–278

    Article  Google Scholar 

  15. Ye N, Yang J, Ke X, Zhu J, Li Y, Xiang C, Wang H, Li L, Xiao B (2014) Synthesis and characterization of geopolymer from bayer red mud with thermal pretreatment. J Am Ceram Soc 97(5):1652–1660

    Article  Google Scholar 

  16. Hu W, Nie Q, Huang B, Shu X, He Q (2018) Mechanical and microstructural characterization of geopolymers derived from red mud and fly ashes. J Clean Prod 186:799–806

    Article  Google Scholar 

Download references

Acknowledgements

The financial support from the National Natural Science Foundation of China (Project No. 41372352, 51579132), and Tsinghua University (Project No. 2015THZ02-2, 2015THZ01) are gratefully acknowledged. The support for the testing facility from State Key Laboratory of Hydro Science and Engineering (SKLHSE-2016-D-03) is also acknowledged.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Liming Hu .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2019 Springer Nature Singapore Pte Ltd.

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Dondrob, K., Koshy, N., Wen, Q., Hu, L. (2019). Synthesis and Characterization of Geopolymers from Coal Gangue, Fly Ash and Red Mud. In: Zhan, L., Chen, Y., Bouazza, A. (eds) Proceedings of the 8th International Congress on Environmental Geotechnics Volume 1. ICEG 2018. Environmental Science and Engineering(). Springer, Singapore. https://doi.org/10.1007/978-981-13-2221-1_44

Download citation

Publish with us

Policies and ethics