Abstract
Nanocomposite dielectrics in 2.5BaO–18.5SrO–8.5PbO–8TiO2–20SiO2–20Nb2O5 system were prepared via melt-quenching followed by controlled crystallization. X-ray diffraction studies revealed that Pb2Nb2O7, (Ba,Sr,Pb)Nb2O6 and (Sr,Pb)TiO3 phases formed from the as-quenched glass annealed in the temperature range from 800 to 1000 °C. Pb2Nb2O7, (Ba,Sr,Pb)Nb2O6 and (Sr,Pb)TiO3 crystallized at 800 °C and then Pb2Nb2O7 disappears at 900 °C, while PbNb2O6 formed at 900 °C. The microstructural observation showed that randomly oriented, the nanometer-sized crystalline grains were found with residual glass concentrated at phase boundaries. Meanwhile, the crystalline grain of the samples grew with the increase in crystallization temperature. And the dielectric constant is enhanced with the increasing crystallization temperature as well. The dielectric constant of the nanocomposites crystallized at different temperatures showed good temperature and electric field stability. In particular, the sample had a high dielectric constant of 900 after crystallized at 1000 °C, and the dielectric loss still remained at a low level of 0.0042, which is expected to be used as a promising candidate material for high voltage ceramic capacitor applications.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Y. Zhou et al., Structural optimization and improved discharged energy density for niobate glass-ceramics by La2O3 addition. J. Am. Ceram. Soc. 96, 372–375 (2013)
J. Du, B. Jones, M. Lanagan, Preparation and characterization of dielectric glass-ceramics in Na2O–PbO–Nb2O5–SiO2 system. Mater. Lett. 59, 2821–2826 (2005)
C. Li, Q.M. Zhang, Q. Tang et al., Dielectric and Energy Storage Properties of BaO–SrO–NaO–NbO–SiO Glass-ceramics with different crystallization times. J. Electron. Mater. 6, 45 (2016)
Q.M. Zhang, J. Luo, Q. Tang et al., Nanocomposite dielectrics in PbO–BaO–Na2O–Nb2O5–SiO2 system with high breakdown strength for high voltage capacitor applications. J. Nanosci. Nanotechnol. 12, 8832–8835 (2012)
X.R. Wang, Y. Zhang, T. Ma et al., Effects of MnO2 concentration on dielectric properties of barium strontium titanate glass ceramics. Ceram. Int. 38, S57–S60 (2012)
J.J. Ruiz-Valdés, A.V. Gorokhovsky, J.I. Escalante-Garcı́ et al., Glass–ceramic materials with regulated dielectric properties based on the system BaO–PbO–TiO2–B2O3–Al2O3. J. Eur. Ceram. Soc. 24, 1505–1508 (2004)
D.F. Han, Q.M. Zhang, J. Luo et al., Optimization of energy storage density in ANb2O6–NaNbO3–SiO2(A=[(1−x)Pb, xSr]) nanostructured glass-ceramic dielectrics. Ceram. Int. 38, 6903–6906 (2012)
M. Wang, X. Liu, X. Wang et al., Influence of crystallization time on microstructures and dielectric properties of tungsten-bronze glass-ceramics. Ceram. Int. 47, 2535–2540 (2012)
D.F. Han et al., Glass-ceramic nanocomposites in the [(1−x)PbO–xBaO]–Na2O–Nb2O5–SiO2 system: crystallization and dielectric performance. Solid State Sci. 14, 661–667 (2012)
J.S. Cheng, H. Li, L.Y. Tang et al., Glass Ceramics (Chemical Industry Publishing, Beijing, 2006)
Acknowledgements
This work was supported by the National Natural Science Foundation of China (No. 51477012).
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2018 Springer Nature Singapore Pte Ltd.
About this paper
Cite this paper
Chen, J., Zhang, Q., Tan, F., Zhou, P., Zhou, M. (2018). Effect of Different Crystallization Temperature on Dielectric Properties of BaO–SrO–PbO–TiO2–SiO2–Nb2O5 Glass-Ceramic Composites. In: Han, Y. (eds) Advanced Functional Materials. CMC 2017. Springer, Singapore. https://doi.org/10.1007/978-981-13-0110-0_59
Download citation
DOI: https://doi.org/10.1007/978-981-13-0110-0_59
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-13-0109-4
Online ISBN: 978-981-13-0110-0
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)