Skip to main content

Morphology Evolution of Monolayer MoS2 Flakes with Seed Promotor Grown by CVD

  • Conference paper
  • First Online:
Advanced Functional Materials (CMC 2017)

Included in the following conference series:

  • 3427 Accesses

Abstract

We report a developed preparation process on the monolayer MoS2 which was grown on SiO2/Si substrates with seed promotor by atmospheric-pressure chemical vapor deposition (CVD) method. It is indicated that growth temperature and proportion of precursors play significant roles on the morphology of the monolayer MoS2 which can change from three-point star to triangle and hexagon. The dimension of the MoS2 flake is mainly dependent on the growth temperature, while its morphology is mainly influenced by the amount of the loaded MoO3. Raman spectra and AFM images show that the MoS2 flakes of the three morphologies are all monolayer.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Q.H. Wang, K. Kalantar-Zadeh, A. Kis, J.N. Coleman, M.S. Strano, Electronics and optoelectronics of two-dimensional transition metal dichalcogenides. J. Nat. Nanotechnol. 7, 699–712 (2012)

    Article  CAS  Google Scholar 

  2. K. Kalantar-Zadeh, J.Z. Ou, T. Daeneke, M.S. Strano, M. Pumera, S.L. Gras, Two-dimensional transition metal dichalcogenides in biosystems. J. Adv. Funct. Mater. 25, 5086–5099 (2015)

    Article  CAS  Google Scholar 

  3. A. Kuc, N. Zibouche, T. Heine, Influence of quantum confinement on the electronic structure of the transition metal sulfide TS2. J. Phys. Rev. B 83, 245213 (2011)

    Article  CAS  Google Scholar 

  4. B. Radisavljevic, A. Radenovic, J. Brivio, V. Giacometti, A. Kis, Single-layer MoS2 transistors. J. Nat. Nanotechnol. 6, 147–150 (2011)

    Article  CAS  Google Scholar 

  5. J.N. Coleman, M. Lotya, A. O’neill, S.D. Bergin, P.J. King, U. Khan, K. Young, A. Gaucher, S. De, R.J. Smith, I.V. Shvets, S.K. Arora, G. Stanton, H.Y. Kim, K. Lee, G.T. Kim, G.S. Duesberg, T. Hallam, J.J. Boland, J.J. Wang, J.F. Donegan, J.C. Grunlan, G. Moriarty, A. Shmeliov, R.J. Nicholls, J.M. Perkins, E.M. Grieveson, K. Theuwissen, D.W. Mccomb, P.D. Nellist, V. Nicolosi, Two-dimensional nanosheets produced by liquid exfoliation of layered materials. J. Sci. 331, 568–571 (2011)

    Article  CAS  Google Scholar 

  6. M.M. Benameur, B. Radisavljevic, J.S. Heron, S. Sahoo, H. Berger, A. Kis, Visibility of dichalcogenide nanolayers. J. Nat. Nanotechnol. 22, 125706 (2011)

    Article  CAS  Google Scholar 

  7. Y.H. Lee, X.Q. Zhang, W. Zhang, M.T. Chang, C.T. Lin, K.D. Chang, Y.C. Yu, J.T. Wang, C.S. Chang, L.J. Li, T.W. Lin, Synthesis of large-area MoS2 atomic layers with chemical vapor deposition. J. Adv. Mater. 24, 2320–2325 (2012)

    Article  CAS  Google Scholar 

  8. A.M. Van Der Zande, P.Y. Huang, D.A. Chenet, T.C. Berkelbach, Y. You, G.H. Lee, T.F. Heinz, D.R. Reichman, D.A. Muller, J.C. Hone, Grains and grain boundaries in highly crystalline monolayer molybdenum disulphide. J. Nat. Mater. 12, 554–561 (2013)

    Article  CAS  Google Scholar 

  9. S. Najmaei, Z. Liu, W. Zhou, X. Zou, G. Shi, S. Lei, B.I. Yakobson, J.C. Idrobo, P.M. Ajayan, J. Lou, Vapour phase growth and grain boundary structure of molybdenum disulphide atomic layers. J. Nat. Mater. 12, 754–759 (2013)

    Article  CAS  Google Scholar 

  10. S.Y. Yang, G.W. Shim, S.-B. Seo, S.-Y. Choi, Effective shape-controlled growth of monolayer MoS2 flakes by powder-based chemical vapor deposition. J. Nano Res. 10, 255–262 (2016)

    Article  CAS  Google Scholar 

  11. X.S. Wang, H.B. Feng, Y.M. Wu, L.Y. Jiao, Controlled synthesis of highly crystalline MoS2 flakes by chemical vapor deposition. J. J. Am. Chem. Soc. 135, 5304–5307 (2013)

    Article  CAS  Google Scholar 

  12. B. Chen, Q. Yu, Q. Yang, P. Bao, W. Zhang, L. Lou, W. Zhu, G. Wang, Large-area high quality MoS2 monolayers grown by sulfur vapor counter flow diffusion. J. RSC Adv. 6, 50306–50314 (2016)

    Article  CAS  Google Scholar 

  13. J. Li, C. Hu, H. Wu, Z. Liu, S. Cheng, W. Zhang, H. Shu, H. Chang, Facile preparation of single MoS2 atomic crystals with highly tunable photoluminescence by morphology and atomic structure. J. Cryst. Growth Des. 16, 7094–7101 (2016)

    Article  CAS  Google Scholar 

  14. S. Wang, Y. Rong, Y. Fan, M. Pacios, H. Bhaskaran, K. He, J.H. Warner, Shape evolution of monolayer MoS2 crystals grown by chemical vapor deposition. J. Chem. Mater. 26, 6371–6379 (2014)

    Article  CAS  Google Scholar 

  15. C. Lee, H. Yan, L.E. Brus, T.F. Heinz, J. Hone, S. Ryu, Anomalous lattice vibrations of single- and few-layer MoS2. J. ACS Nano 4, 2695–2700 (2010)

    Article  CAS  Google Scholar 

  16. H. Schmidt, S. Wang, L. Chu, M. Toh, R. Kumar, W. Zhao, A.H. Neto, J. Martin, S. Adam, B. Ozyilmaz, G. Eda, Transport properties of monolayer MoS2 grown by chemical vapor deposition. J. Nano Lett. 14, 1909–1913 (2014)

    Article  CAS  Google Scholar 

  17. Y. Gong, Z. Lin, G. Ye, G. Shi, S. Feng, Y. Lei, A.L. Elias, N. Perea-Lopez, R. Vajtai, H. Terrones, Z. Liu, M. Terrones, P.M. Ajayan, Tellurium-assisted low-temperature synthesis of MoS2 and WS2 monolayers. J. ACS Nano 9, 11658–11666 (2015)

    Article  CAS  Google Scholar 

  18. X. Ling, Y. Lin, Q. Ma, Z. Wang, Y. Song, L. Yu, S. Huang, W. Fang, X. Zhang, A.L. Hsu, Y. Bie, Y.H. Lee, Y. Zhu, L. Wu, J. Li, P. Jarillo-Herrero, M. Dresselhaus, T. Palacios, J. Kong, Parallel stitching of 2D materials. J. Adv. Mater. 28, 2322–2329 (2016)

    Article  CAS  Google Scholar 

  19. Y. Feldman, E. Wasserman, D.J. Srolovitz, R. Tenne, High-rate, gas-phase growth of MoS2 nested inorganic fullerenes and nanotubes. J. Sci. 267, 222–225 (1995)

    Article  CAS  Google Scholar 

  20. J. Dang, G.H. Zhang, K.-C. Chou, R.G. Reddy, Y. He, Y. Sun, Kinetics and mechanism of hydrogen reduction of MoO3 to MoO2. J. Int. J. Refract. Met. Hard Mater. 41, 216–223 (2013)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by GRINM Innovation Fund.

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Xin Zhang or Feng Wei .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2018 Springer Nature Singapore Pte Ltd.

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Zhang, X., Zhao, H., Zhang, Q., Wei, F. (2018). Morphology Evolution of Monolayer MoS2 Flakes with Seed Promotor Grown by CVD. In: Han, Y. (eds) Advanced Functional Materials. CMC 2017. Springer, Singapore. https://doi.org/10.1007/978-981-13-0110-0_45

Download citation

Publish with us

Policies and ethics