Abstract
During hot rolling, high-temperature oxidation has a direct effect on the thickness and structures of oxide scales of hot-rolled steel, even influences the descaling and the final surface quality of product. The GLEEBLE thermal simulator was used to investigate the short-time (30–900 s) oxidation of low-alloy steel Q345B in the temperature ranging from 850 to 1050 °C. The structures, thickness and proportion of each layer were characterized by SEM and EDS. The research showed that the initial surface of the scale was in mesh pattern. The scale blistered with increasing time and the grown crystals surrounded by mesh-like gullies could be observed. The scale thickness increased with the elevating temperature, ranged from 5.19 to 207.59 μm depending on the experiments process. It was less than 10 μm within 60 s at 850 °C, increased slowly with the oxidation time below 950 °C, but increased sharply above 950 °C before 120 s. The oxide scales had triple layers after oxidized at 850 °C, and at 950 °C for 30 s. The scale was a double-layer structure at high temperature, consisted of FeO and Fe3O4. With increasing temperature and time of oxidation, the proportion of loose layer (FeO) increased, but compact layer (Fe3O4) decreased from 70.13 to 7.30% in the two layers. The bottom oxide layer with main component of Fe2SiO4 was found between the scale and substrate. It can improve the scale adhesion and is bad for scale separation from substrate.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
R.Y. Chen, W.Y.D. Yuen, Oxide-scale structures formed on commercial hot-rolled steel strip and their formation mechanisms. Oxid. Met. 56, 89–118 (2001)
R.Y. Chen, W.Y.D. Yuen, Review of the high-temperature oxidation of iron and carbon steels in air or oxygen. Oxid. Met. 59, 433–468 (2003)
Y. Yu, J.G. Lenard, Estimating the resistance to deformation of the layer of scale during hot rolling of carbon steel strips. J. Mater. Process. Tech. 121, 60–68 (2002)
R. Endo, T. Yagi, M. Ueda, M. Susa, Thermal diffusivity measurement of oxide scale formed on steel during hot-rolling process. ISIJ Int. 54, 2084–2088 (2014)
B. Gleeson, S.M.M. Hadavi, D.J. Young, Isothermal transformation behavior of thermally-grown wustite. Mater. High Temp. 17, 311–318 (2000)
R.Y. Chen, D.W.Y. Yuen, A study of the scale structure of hot-rolled steel strip by simulated coiling and cooling. Oxid. Met. 53, 539–560 (2000)
N. Otsuka, T. Doi, Y. Hidaka, Y. Higashida, Y. Masaki, N. Mizui, M. Sato, In-situ measurements of isothermal wustite transformation of thermally grown FeO scale formed on 0.048 mass% Fe by synchrotron radiation in air. ISIJ. Int. 53, 286–293 (2013)
C.H. Zhou, H.T. Ma, Y. Li, Eutectoid magnetite in wustite under conditions of compressive stress and cooling. Oxid. Met. 78, 145–152 (2012)
R.Y. Chen, W.Y.D. Yuen, Oxidation of low-carbon, low-silicon mild steel at 450–900 °C under conditions relevant to hot-strip processing. Oxid. Met. 53, 53–79 (2012)
Q. Yuan, G. Xu, M.X. Zhou, B. He, The effect of the Si content on the morphology and amount of Fe2SiO4 in low carbon steels. Metals-Basel 6, 94–103 (2016)
E.J. Song, D.W. Suh, H.K.D.H. Bhadeshia, Oxidation of silicon containing steel. Ironmak. Steelmak. 39, 599–604 (2012)
B. He, G. Xu, M.X. Zhou, Q. Yuan, Effect of oxidation temperature on the oxidation process of silicon-containing steel. Metals-Basel 6, 137–146 (2016)
J.G. Speight, Lange’s Handbook of Chemistry, 16th edn. (The McGraw-Hill Companies, America, 2005), pp. 254–255
P. Atkins, J.D. Paula, Atkins’ Physical Chemistry, 8th edn. (Oxford University Press, Oxford, 2006), pp. 1000–1001
D. Genève, D. Rouxel, P. Pigeat, B. Weber, M. Confente, Surface composition modification of high-carbon low-alloy steels oxidized at high temperature in air. Appl. Surf. Sci. 254, 5348–5358 (2008)
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2018 Springer Nature Singapore Pte Ltd.
About this paper
Cite this paper
Wang, J., Yu, W., Dong, E., Shi, J. (2018). Evolution of Oxide Structures of Low-Alloy Steel Surface During Short-Time Oxidation at High Temperature. In: Han, Y. (eds) Advances in Materials Processing. CMC 2017. Lecture Notes in Mechanical Engineering. Springer, Singapore. https://doi.org/10.1007/978-981-13-0107-0_69
Download citation
DOI: https://doi.org/10.1007/978-981-13-0107-0_69
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-13-0106-3
Online ISBN: 978-981-13-0107-0
eBook Packages: EngineeringEngineering (R0)