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Assembled Lanthanide Complexes with Advanced Photophysical Properties pp 15–33Cite as

Luminescent Lanthanide Coordination Zippers with Dense-Packed Structures for High Energy Transfer Efficiencies

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Part of the book series: Springer Theses ((Springer Theses))

Abstract

Novel Eu(III) coordination polymers [Eu(hfa)3(dpt)] n [dpt: 2,5-bis(diphenylphosphoryl)thiophene] and [Eu(hfa)3(dpedot)] n [dpedot: 3,4-bis(diphenylphosphoryl)ethylenedioxythiophene] were designed for dense structures with high energy transfer efficiency. The zig-zag orientation of single polymer chains induced the formation of dense-packed coordination structures with multiple inter-molecular hydrogen bonds. These polymers exhibited high intrinsic emission quantum yields (~80%) due to their asymmetrical and low-vibrational coordination structures. The significant energy transfer efficiencies of up to 80% were also achieved.

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Authors and Affiliations

  1. Hokkaido University, Sapporo, Hokkaido, Japan

    Yuichi Hirai

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  1. Yuichi Hirai
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Correspondence to Yuichi Hirai .

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Hirai, Y. (2018). Luminescent Lanthanide Coordination Zippers with Dense-Packed Structures for High Energy Transfer Efficiencies. In: Assembled Lanthanide Complexes with Advanced Photophysical Properties. Springer Theses. Springer, Singapore. https://doi.org/10.1007/978-981-10-8932-9_2

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