Abstract
In this chapter, the influence of the strength of the metal–molecule interaction on the formation of a single-molecule junction with a high, well-defined conductance value was investigated. Although the Pt/benzene/Pt single-molecule junction exhibits high conductivity, its conductance value is not well defined. In order to restrict the configuration of the benzene molecule, the strength of the interaction between the metal and benzene should be reduced. Ag and Au are expected to interact more gently with the benzene than Pt. The moderately strong interaction between Ag and benzene successfully formed a single-molecule junction; however, Au did not form a single-molecule junction because of the formation of the linear atomic chain.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
M. Kiguchi, O. Tal, S. Wohlthat, F. Pauly, M. Krieger, D. Djukic, J.C. Cuevas, J.M. van Ruitenbeek, Highly conductive molecular junctions based on direct binding of benzene to platinum electrodes. Phys. Rev. Lett. 101, 046801 (2008)
M. Kiguchi, Electrical conductance of single C60 and benzene molecules bridging between Pt electrode. Appl. Phys. Lett. 95, 073301 (2009)
M. Kiguchi, R. Stadler, I. Kristensen, D. Djukic, J. Van Ruitenbeek, Evidence for a single hydrogen molecule connected by an atomic chain. Phys. Rev. Lett. 98, 146802 (2007)
S. Kaneko, T. Nakazumi, M. Kiguchi, Fabrication of a well-defined single benzene molecule junction using Ag electrodes. J. Phys. Chem. Lett. 1, 3520–3523 (2010)
Y. Li, P. Wei, M.L. Bai, Z.Y. Shen, S. Sanvito, S.M. Hou, Contact geometry and electronic transport properties of Ag-benzene-Ag molecular junctions. Chem. Phys. 397, 82–86 (2012)
Y. G. Naidyuk, I. K. Yanson, Point-Contact Spectroscopy, vol 145. Springer Series in Solid-State Sciences, (Springer, New York, New York, 2005)
R.A. Wolkow, M. Moskovits, A comparative-study of the electron-energy loss spectrum and the surface-enhance raman-spectrum of benzene adsorbed on silver. J. Chem. Phys. 96, 3966–3980 (1992)
J.I. Pascual, J.J. Jackiw, Z. Song, P.S. Weiss, H. Conrad, H.P. Rust, Adsorbate-substrate vibrational modes of benzene on Ag(110) resolved with scanning tunneling spectroscopy. Phys. Rev. Lett. 86, 1050–1053 (2001)
J. Ferrer, V.M. Garcia-Suarez, Tuning the conductance of molecular junctions: transparent versus tunneling regimes. Phys. Rev. B 80, 085426 (2009)
H. Song, Y. Kim, Y.H. Jang, H. Jeong, M.A. Reed, T. Lee, Observation of molecular orbital gating. Nature 462, 1039–1043 (2009)
M. Saeys, M.F. Reyniers, G.B. Marin, M. Neurock, Density functional study of benzene adsorption on Pt(111). J. Phys. Chem. B 106, 7489–7498 (2002)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2017 Springer Nature Singapore Pte Ltd.
About this chapter
Cite this chapter
Kaneko, S. (2017). Design of the Metal–Molecule Interaction at the Benzene Single-Molecule Junction. In: Design and Control of Highly Conductive Single-Molecule Junctions. Springer Theses. Springer, Singapore. https://doi.org/10.1007/978-981-10-4412-0_4
Download citation
DOI: https://doi.org/10.1007/978-981-10-4412-0_4
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-10-4411-3
Online ISBN: 978-981-10-4412-0
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)