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Groundwater Quality, Contamination, and Processes in Brahmaputra River Basin Aquifers

  • Swati Verma
  • Abhijit MukherjeeEmail author
Chapter
Part of the Springer Hydrogeology book series (SPRINGERHYDRO)

Abstract

The present study addresses the groundwater solute chemistry, hydrogeochemical evolution, aquifer sediments provenance, and geochemical processes that influences the fate of groundwater arsenic (As) in aquifers of three district tectono-morphic regions of Brahmaputra river basin (BRB). These regions are located in northwestern (NW), northern (N), and southern (S) site of Brahmaputra river along two distinct orogenic belts, i.e., Eastern Himalayas (NW and N) and Indo-Burma Range or Naga Hills (S) in Upper Assam, India. Stable isotopic composition (δ2H and δ18O) in groundwater suggests that the groundwater composition of BRB is influenced by slight evaporation through recharging water. Groundwater composition of S-region is dominated by Na–Ca–HCO3 hydrogeochemical facies, whereas groundwater samples from NW- and N-regions vary between Ca‒HCO3 and Ca–Na–HCO3 in BRB. The distribution of dissolved As concentrations shows huge variation among all studied regions in the Brahmaputra Basin. The groundwater of S-region is much enriched in groundwater As (bdl to 5.53 µM or 415 μg/L, mean 1.77 µM) compared to NW- and N-regions (bdl to 1.8 µM or 134 μg/L, mean 0.28 µM; bdl to 2.45 µM or 184 μg/L, mean 0.68 µM, respectively). Almost 92% collected groundwater sample from S-site is contaminated with dissolved As. This huge As variation might be caused by the differences in the geology, tectonic evolution, and the distance of the two regions from their provenances. Reductive dissolution of minerals, i.e., Fe/Mn oxides/hydroxides, is the most plausible mechanism for arsenic release into the groundwater of the NW and N part in BRB. However, As mobilization in groundwater of S-regions possibly controlled multiple hydrogeochemical processes and the groundwater As enrichment cannot be influenced by one single mechanism in S-aquifer. Thus, hydrogeochemical evolution and high variation in dissolved As enrichment (or distribution) might be explained in terms of geology and rock type of sediment provenance in BRB.

Keywords

Groundwater Arsenic Hydrogeochemistry Brahmaputra river basin 

References

  1. Acharyya SK (2007) Collisional emplacement history of the Naga-Andaman ophiolites and the position of the eastern Indian suture. J Asian Earth Sci 29(2):229–242CrossRefGoogle Scholar
  2. Ahmed KM, Bhattacharya P, Hasan MA, Akhter SH, Alam SM, Bhuyian MAH, Imam MB, Khan AA, Sracek O (2004) Arsenic enrichment in groundwater of the alluvial aquifers in Bangladesh: an overview. Appl Geochem 19:181–200CrossRefGoogle Scholar
  3. Bhattacharya P, Chatterjee D, Jacks G, (1997) Occurrence of arsenic-contaminated groundwater in alluvial aquifers from the Bengal Delta Plain, Eastern India: options for a safe drinking water supply. Water Resou Dev, 13:79–92Google Scholar
  4. Bhattacharya P, Jacks G, Jana J, Sracek A, Gustafsson JP, Chatterjee D (2001) Geochemistry of the Holocene alluvial sediments of Bengal Delta Plain from West Bengal, India: implications on arsenic contamination in groundwater. Groundw Arsen Contamination Bengal Delta Plain Bangladesh 3084:21–40Google Scholar
  5. Bhattacharya P, Welch AH, Stollenwerk KG, McLaughlin MJ, Bundschuh J, Panaullah G (2007) Arsenic in the environment: biology and chemistry. Sci Total Environ 379:109–120CrossRefGoogle Scholar
  6. Bhattacharya P, Mukherjee A, Mukherjee AB (2011) Arsenic contaminated groundwater of India. In: Nriagu J (ed) Encyclopedia of environmental health. Elsevier B.V, Netherlands, pp 150–164CrossRefGoogle Scholar
  7. Böttcher J, Strebel O, Voerkelius S, Schmidt HL (1990) Using isotope fractionation of nitrate–nitrogen and nitrate–oxygen for evaluation of microbial denitrification in sandy aquifer. J Hydrol 114:413–424CrossRefGoogle Scholar
  8. Charlet L, Polya DA (2006) Arsenic in shallow, reducing groundwater in Southern Asia: an environmental health disaster. Elements 2:91–96CrossRefGoogle Scholar
  9. Chetia M, Chatterjee S, Banerjee S, Nath J, Singh L, Srivastava B, Sarma P (2011) Groundwater arsenic contamination in Brahmaputra river basin: a water quality assessment in Golaghat (Assam), India. Environ Monit Assess 173:371–385CrossRefGoogle Scholar
  10. Craig H (1961) Isotopic variations in meteoric water. Sci 133:1702–1703CrossRefGoogle Scholar
  11. Dutta SK, Gill GKS, Srinivasan J (1983) Geology of the Subansiri and Kamala valleys. In: Proceedings of symposium on geology and mineral resources of North eastern Himalayas. G.S.I., Misc. Pub. no. 43, pp 9–14Google Scholar
  12. Drever JI (1997) The geochemistry of natural waters, third edn. Prentice Hall, Upper Saddle River, New JerseyGoogle Scholar
  13. Dowling CB, Poreda RJ, Basu AR, Peters SL, Aggarwal PK (2002) Geochemical study of arsenic release mechanisms in the Bengal Basin groundwater. Water Resour Res 38(9):1–18CrossRefGoogle Scholar
  14. Fendorf S, Michael AH, van Geen A (2010) Spatial and temporal variations of groundwater arsenic in South and Southeast Asia. Science 328(5982):1123–1127CrossRefGoogle Scholar
  15. Faure G (1998) Principles and applications of geochemistry, second edn. Prentice Hall, Upper Saddle River, New JerseyGoogle Scholar
  16. Goodbred SL, Paolo PM, Ullah MS, Pate RD, Khan SR, Kuehl SA, Rahaman W (2014) Piecing together the Ganges-Brahmaputra-Meghna River delta: use of sediment provenance to reconstruct the history and interaction of multiple fluvial systems during Holocene delta evolution. Geol Soc Am Bull 126(11–12):1495–1510CrossRefGoogle Scholar
  17. Guillot S, Charlet L (2007) Bengal arsenic, an archive of paleohydrology and Himalayan erosion. Environ Sci Health Part A 42:1785–1794CrossRefGoogle Scholar
  18. Guillot S, Garçon M, Weinman B, Gajurel A, Tisserand D, France-Lanord C, Charlet L (2015) Origin of arsenic in Late Pleistocene to Holocene sediments in the Nawalparasi district (Terai, Nepal). Environ Earth Sci 74(3):2571–2593CrossRefGoogle Scholar
  19. Harvey CF, Swartz CH, Badruzzaman ABM, Keon-Blute N, Yu W, Ali MA, Jay J, Beckie R, Niedan V, Brabander D, Oates PM, Ashfaque KN, Islam S, Hemond HF, Ahmed MF (2002) Arsenic mobility and groundwater extraction in Bangladesh. Science 298:1602–1606CrossRefGoogle Scholar
  20. Islam FS, Gault AG, Boothman C, Polya DA, Charnock JM, Chatterjee D, Lloyd JR (2004) Role of metal-reducing bacteria in arsenic release from Bengal delta sediments. Nature 430(6995):68–71CrossRefGoogle Scholar
  21. Mahanta C, Choudhury R, Basu S, Hemani R, Dutta A, Barua PP, Saikia L (2015) Preliminary assessment of arsenic distribution in Brahmaputra River Basin of India based on examination of 56,180 public groundwater wells. In: Safe and sustainable use of arsenic-contaminated aquifers in the gangetic plain. Springer International Publishing, pp 57–64CrossRefGoogle Scholar
  22. McLean W, Jankowski J (2000) Groundwater quality and sustainability in an alluvial aquifer, Australia. In: Sililo A (ed), XXX IAH Congress on Groundwater: Past Achievements and Future Challenges. A.A. Balkema, RotterdamGoogle Scholar
  23. Mukherjee A, Fryar AE (2008) Deeper groundwater chemistry and geochemical modeling of the arsenic affected western Bengal basin, West Bengal, India. Appl Geochem 23:863–892CrossRefGoogle Scholar
  24. Mukherjee A, Bhattacharya P, Shi F, Fryar AE, Mukherjee AB, Xie ZM, Sracek O, Jacks G, Bundschuh J (2009) Chemical evolution in the high arsenic groundwater of the Huhhot basin (Inner Mongolia, PR China) and its difference from the western Bengal basin (India). Appl Geochem 24:1835–1851CrossRefGoogle Scholar
  25. Mukherjee A, Scanlon B, Fryar A, Saha D, Ghoshe A, Chowdhuri S, Mishra R (2012) Solute chemistry and arsenic fate in aquifers between the Himalayan foothills and Indian craton (including central Gangetic plain): Influence of geology and geomorphology. Geochim Cosmochim Acta 90:283–302CrossRefGoogle Scholar
  26. Mukherjee A, Verma S, Gupta S, Henke KR, Bhattacharya P (2014) Influence of tectonics, sedimentation and aqueous flow cycles on the origin of global groundwater arsenic: paradigms from three continents. J Hydrol 518:284–299CrossRefGoogle Scholar
  27. Mukherjee A (2018) Groundwater of South Asia. Springer Nature, Singapore, ISBN 978-981-10-3888-4Google Scholar
  28. Nordstrom DK (2009) Natural arsenic enrichment: effects of diagenetic tectonichydrothermal cycle. Geol Soc Am Abstracts Progr 41(7):217Google Scholar
  29. Nriagu JO, Bhattacharya P, Mukherjee AB, Bundschuh J, Zevenhoven R, Loeppert RH (2007) Arsenic in soil and groundwater: an overview. Trace Metals other Contam Environ 9:3–60CrossRefGoogle Scholar
  30. Nickson RT, McArthur JM, Ravenscroft P, Burgess WG, Ahmed KM (2000) Mechanism of arsenic release to groundwater, Bangladesh and West Bengal. Appl Geochem 15:403–413CrossRefGoogle Scholar
  31. Nesbitt HW, Young GM (1989) Formation and diagenesis of weathering profiles. J Geol 97:129–147CrossRefGoogle Scholar
  32. Ravenscroft P, Brammer H, Richards KS (2009) Arsenic pollution: a global synthesis. Wiley-Blackwell, Cichester, UKCrossRefGoogle Scholar
  33. Saunders JA, Lee MK, Uddin A, Mohammad S, Wilkin RT, Fayek M, Korte NE (2005) Natural arsenic contamination of Holocene alluvial aquifers by linked tectonic, weathering, and microbial processes. Geochem Geophys Geosyst 6(4)CrossRefGoogle Scholar
  34. Sarin MM, Krishnaswami S, Dilli K, Somayajulu BLK, Moore WS (1989) Major ion chemistry of the Ganga–Brahmaputra river system: weathering processes and fluxes to the Bay of Bengal. Geochim Cosmochim Acta 53:997–1009CrossRefGoogle Scholar
  35. Singh SK, Sarin MM, France-Lanord C (2005) Chemical erosion in the eastern Himalaya: major ion composition of the Brahmaputra and δ13C of dissolved inorganic carbon. Geochim Cosmochim Acta 69(14):3573–3588CrossRefGoogle Scholar
  36. Stüben D, Berner Z, Chandrasekharam D, Karmakar J (2003) Arsenic enrichment in groundwater of West Bengal, India: geochemical evidence for mobilization of As under reducing conditions. Appl Geochem 18(9):1417–1434CrossRefGoogle Scholar
  37. Smedley PL, Kinniburgh DG (2002) A review of the source, behaviour and distribution of arsenic in natural waters. Appl Geochem 17:517–568CrossRefGoogle Scholar
  38. Smedley PL (2005) Arsenic occurrence in groundwater in South and East Asia-scale, causes and mitigation. In: Towards a more effective operational response: arsenic contamination of groundwater in South and East Asian countries, vol II Technical Report, World Bank Report No. 31303Google Scholar
  39. Swartz CH, Blute NK, Badruzzaman B, Ali A, Brabander D, Jay J, Besancon J, Islam S, Hemond HF, Harvey CF (2004) Mobility of arsenic in a Bangladesh aquifer: inferences from geochemical profiles, leaching data, and mineralogical characterization. Geochim Cosmochim Acta 68:4539–4557CrossRefGoogle Scholar
  40. Tardy Y (1971) Characterization of the principal weathering types by the geochemistry of waters from some European and African crystalline massifs. Chem Geol 7:253–271CrossRefGoogle Scholar
  41. Verma S, Mukherjee A, Choudhury R, Mahanta C (2015) Brahmaputra river basin groundwater: solute distribution, chemical evolution and arsenic occurrences in different geomorphic settings. J Hydrol Reg Stud 4:131–153CrossRefGoogle Scholar
  42. Verma S, Mukherjee A, Mahanta C, Choudhury R, Mitra K (2016) Influence of geology on groundwater-sediment interactions in varied arsenic enriched tectono-morphic aquifers of the Brahmaputra River Basin. J Hydrol 540:176–195CrossRefGoogle Scholar
  43. Wood WW (1981) Guidelines for Collection and Field Analysis of Ground-Water Samples for Selected Unstable Constituents. In: US Geological Survey, Techniques of Water Resources Investigation, Book 1 (Chapter D2)Google Scholar
  44. Zheng Y (2006) The heterogeneity of arsenic in the crust: a linkage to occurrence in groundwater. Geol Soc Am Abstracts Progr 38(7):179Google Scholar

Copyright information

© Springer Nature Singapore Pte Ltd. 2018

Authors and Affiliations

  1. 1.Department of Geology and GeophysicsIndian Institute of Technology (IIT)—KharagpurKharagpurIndia
  2. 2.School of Environmental Science and EngineeringIndian Institute of Technology (IIT)—KharagpurKharagpurIndia
  3. 3.Applied Policy Advisory To Hydrogeosciences GroupIndian Institute of Technology (IIT)—KharagpurKharagpurIndia

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