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Investigating Effect of Chemical Composition on Emulsion Stability and Rag Layer Growth During Separation

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ICIPEG 2016

Abstract

Alkaline–surfactant–polymer (ASP) flooding is a promising chemical enhanced oil recovery (EOR) method, currently applied in many oilfields in China, USA, India, and Malaysia. ASP has been the worldwide focus of research and field trials for the last decade. In a Malaysian EOR oilfield, a range of ASP concentrations were reported to breakthrough into the separator feed which results in forming stable/tight crude oil emulsions. Stable emulsion makes oil/water separation costly, time-consuming, and contributes to several operational problems in the surface facilities.The contribution of ASP components to the stability of produced emulsions has not been fully investigated. This paper discusses the design of experiments used to investigate the effect of water cut, alkaline concentration, surfactant concentration, polymer concentration, and temperature effect on stabilization of ASP-produced emulsion. A series of batch and continuous experiments are utilized to investigate the effect of various ASP compositions on the coalescence rate, rag layer growth, rheological properties, and droplet size of the generated emulsion after ASP flooding.

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References

  1. Kokal, S. L. (2005). Crude oil emulsions: A state-of-the-art review. SPE Production & facilities, 20(01), pp. 5–13.

    Google Scholar 

  2. Khatri N. L., Andrade, J., Baydak, E. N., & Yarranton, H. W. (2011). Emulsion layer growth in continuous oil–water separation. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 384(1), pp. 630–642.

    Google Scholar 

  3. Sheng J. (2010). Modern chemical enhanced oil recovery: theory and practice. Gulf Professional Publishing.

    Google Scholar 

  4. McLean, J. D., Spiecker, P. M., Sullivan, A. P., & Kilpatrick, P. K. (1998). The role of petroleum asphaltenes in the stabilization of water-in-oil emulsions. In Structures and Dynamics of Asphaltenes (pp. 377–422). Springer US.

    Google Scholar 

  5. Kang, W., Guo, L., Fan, H., Meng, L., & Li, Y. (2012). Flocculation, coalescence and migration of dispersed phase droplets and oil–water separation in heavy oil emulsion. Journal of Petroleum Science and Engineering, 81, pp. 177–181.

    Google Scholar 

  6. Di, W., Meng, X., Zhao, F., Zhang, R., Yan, C., Wang, Q., & Liang, H. (2001, January). Emulsification and stabilization of ASP flooding produced liquid. In SPE In-ternational Symposium on Oilfield Chemistry. Society of Petroleum Engineers.

    Google Scholar 

  7. Czarnecki, J., Moran, K., & Yang, X. (2007). On the “rag layer” and diluted bitumen froth dewatering. The Canadian Journal of Chemical Engineering, 85(5), pp. 748–755.

    Google Scholar 

  8. Hartland S., & Vohra, D. K. (1980). Effect of interdrop forces on the coalescence of drops in close-packed dispersions. Journal of Colloid and Interface Science, 77(2), pp. 295–316.

    Google Scholar 

  9. Kang, W., & Wang, D. (2001, January). Emulsification characteristic and de-emulsifiers action for alkaline/surfactant/polymer flooding. In SPE Asia Pacific Im-proved Oil Recovery Conference. Society of Petroleum Engineers.

    Google Scholar 

  10. Olsen, D. K., Hicks, M. D., Hurd, B. G., Sinnokrot, A. A., & Sweigart, C. N. (1990, January). Design of a novel flooding system for an oil-wet Central Texas carbonate reservoir. In SPE/DOE Enhanced Oil Recovery Symposium. Society of Petroleum Engineers.

    Google Scholar 

  11. Chang, H. L., Hou, H., Wu, F., & Gao, Y. (2013, July). Chemical EOR Injection Fa-cilities-From Pilot Test to Field-Wide Expansion. In SPE Enhanced Oil Recovery Conference. Society of Petroleum Engineers.

    Google Scholar 

  12. Sheng, J. J. (2014). A comprehensive review of alkaline–surfactant–polymer (ASP) flooding. Asia‐Pacific Journal of Chemical Engineering, 9(4), pp. 471–489.

    Google Scholar 

  13. Deng, S., Bai, R., Chen, J. P., Yu, G., Jiang, Z., & Zhou, F. (2002). Effects of alka-line/surfactant/polymer on stability of oil droplets in produced water from ASP flooding. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 211(2), pp. 275–284.

    Google Scholar 

  14. Nguyen, D. T., Sadeghi, N., & Houston, C. W. (2011, January). Emulsion Character-istics and Novel Demulsifiers for Treating Chemical EOR Induced Emulsions. In SPE Enhanced Oil Recovery Conference. Society of Petroleum Engineers.

    Google Scholar 

  15. Kang, W. L. (2001). Study of chemical interactions and drive mechanisms in Daqing ASP flooding.

    Google Scholar 

  16. Hartland S., & Jeelani, S. A. K. (1988). Prediction of sedimentation and coalescence profiles in a decaying batch dispersion. Chemical engineering science, 43(9), pp. 2421–2429.

    Google Scholar 

  17. Dickinson E., Murray, B. S., & Stainsby, G. (1988). Coalescence stability of emul-sion-sized droplets at a planar oil–water interface and the relationship to protein film surface rheology. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 84(3), pp. 871–883.

    Google Scholar 

  18. Chen F., Finch, J. A., Xu, Z., & Czarnecki, J. (1999). Wettability of fine solids ex-tracted from bitumen froth. Journal of adhesion science and technology, 13(10), pp. 1209–1224.

    Google Scholar 

  19. Sztukowski D. M., & Yarranton, H. W. (2005). Oilfield solids and water-in-oil emulsion stability. Journal of colloid and interface science, 285(2), pp. 821–833.

    Google Scholar 

  20. Jiang T., Hirasaki, G. J., Miller, C. A., & Moran, K. (2008). Using silicate and pH control for removal of the rag layer containing clay solids formed during demulsifi-cation. Energy & Fuels, 22(6), pp. 4158–4164.

    Google Scholar 

  21. Saadatmand, M., Yarranton, H. W., & Moran, K. (2008). Rag layers in oil sand froths. Industrial & Engineering Chemistry Research, 47(22), pp. 8828–8839.

    Google Scholar 

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Correspondence to Ahmed Basyouni .

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Basyouni, A., Elraies, K.A., Al-Kaieym, H.H. (2017). Investigating Effect of Chemical Composition on Emulsion Stability and Rag Layer Growth During Separation. In: Awang, M., Negash, B., Md Akhir, N., Lubis, L., Md. Rafek, A. (eds) ICIPEG 2016. Springer, Singapore. https://doi.org/10.1007/978-981-10-3650-7_9

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  • DOI: https://doi.org/10.1007/978-981-10-3650-7_9

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