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Revealing Localized Electrochemical Transition of Sulfur in Sub-nanometer Confinement

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Design, Fabrication and Electrochemical Performance of Nanostructured Carbon Based Materials for High-Energy Lithium–Sulfur Batteries

Part of the book series: Springer Theses ((Springer Theses))

Abstract

A microporous-mesoporous carbon with graphitic structure was developed as a matrix for the sulfur cathode of a Li–S cell using a mixed carbonate electrolyte. Sulfur was selectively introduced into the carbon micropores by a melt adsorption-solvent extraction strategy. The micropores act as solvent-restricted reactors for sulfur lithiation that promise long cycle stability. The mesopores remain unfilled and provide an ion migration pathway, while the graphitic structure contributes significantly to low-resistance electron transfer. The cathode is able to operate reversibly over 800 cycles with a 1.8 C discharge–recharge rate. This integration of a micropore reactor, a mesopore ion reservoir, and a graphitic electron conductor represents a generalized strategy to be adopted in research on advanced sulfur cathodes.

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Authors and Affiliations

  1. Shenyang, People’s Republic of China

    Guangmin Zhou

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  1. Guangmin Zhou
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Correspondence to Guangmin Zhou .

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Zhou, G. (2017). Revealing Localized Electrochemical Transition of Sulfur in Sub-nanometer Confinement. In: Design, Fabrication and Electrochemical Performance of Nanostructured Carbon Based Materials for High-Energy Lithium–Sulfur Batteries. Springer Theses. Springer, Singapore. https://doi.org/10.1007/978-981-10-3406-0_2

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