Skip to main content
SpringerLink
Log in

Preparation of Molybdenum Aminogermylene and Aminogermylyne Complexes

  • Chapter
  • First Online:
Preparation, Characterisation and Reactivity of Low Oxidation State d-Block Metal Complexes Stabilised by Extremely Bulky Amide Ligands

Part of the book series: Springer Theses ((Springer Theses))

  • 359 Accesses

Abstract

Transition metal carbyne complexes are organometallic compounds that contain a transition-metal carbon triple bond. Since their discovery in 1973 [1], this fundamental compound class has been extensively studied, due to their numerous synthetic, catalytic and analytical applications [2]. In recent years, considerable efforts have been made to extend this work to the preparation of heavier group 14 analogues, i.e. transition metal tetrelynes LnM≡ER (E = Si, Ge, Sn or Pb; M = a transition metal; L = a ligand, R = an organic group) to investigate their further chemistry. However, unlike their lighter carbon analogues, bulky substituents are required to kinetically stabilise the reactive M≡E core. The synthesis and reactivity of these transition metal tetrelyne complexes is the primary focus for this chapter.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
eBook
USD 16.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. E.O. Fischer, G. Kreis, C.G. Kreiter, J. Miller, G. Huttner, H. Lorenz, Angew. Chem. 85, 618 (1973); Angew. Chem. Int. Ed. Engl. 12, 564 (1973)

    Google Scholar 

  2. See, for example: (a) H. Fischer, P. Hofmann, F.R. Kreisal, R.R. Schrock, U. Schubert, K. Weiss, Carbyne Complexes; VCH: New York (1988); (b) F.R. Kreisel (ed.), Transition Metal Carbyne Complexes; Kluwer: Dordrecht, The Netherlands (1993); (c) A. Mayer, H. Hoffmeister, Adv. Organomet. Chem. 32, 227 (1991); d) R.R. Schrock, Chem. Rev. 102, 145 (2002)

    Google Scholar 

  3. S.D. Grumbine, R.K. Chadha, T.D. Tilley, J. Am. Chem. Soc. 114, 1518 (1992)

    Article  CAS  Google Scholar 

  4. R.S. Simons, P.P. Power, J. Am. Chem. Soc. 118, 11966 (1996)

    Article  CAS  Google Scholar 

  5. L.Y. Chan, W.K. Dean, W.A.G. Graham, Inorg. Chem. 16, 1067 (1977)

    Article  Google Scholar 

  6. F. Carré, E. Colomer, R.J.P. Corriu, A. Vioux, Organometallics 15, 741 (1984)

    Google Scholar 

  7. L. Pu, B. Twamley, S.T. Haubrich, M.M. Olmstead, B.V. Mork, R.S. Simons, P.P. Power, J. Am. Chem. Soc. 122, 650 (2000)

    Article  CAS  Google Scholar 

  8. L. Pauling, The Nature of the Chemical Bond, 3rd edn. (Cornell University Press, Ithaca, NY, 1960), p. 256

    Google Scholar 

  9. F.A. Cotton, G. Wilkinson, C. Murillo, M. Bochmann, Advanced Inorganic Chemistry, 6th edn. (Wiley, New York, 1999), p. 920

    Google Scholar 

  10. (a) A.C. Filippou, A.I. Philippopoulos, P. Portius, D.U. Neumann, Angew. Chem. Int. Ed. 39, 2778 (2000); (b) A.C. Filippou, P. Portius, A.I. Philippopoulos, Organometallics 21, 653 (2002); (c) A.C. Filippou, A.I. Philippopoulos, P. Portius, G. Schnakenburg, Organometallics 23, 4503 (2004); (d) A.C. Filippou, G. Schnakenburg, A.I. Philippopoulos, N. Weidemann, Angew. Chem. Int. Ed. 44, 5979 (2005); (e) A.C. Filippou, N. Weidemann, A.I. Philippopoulos, G. Schnakenburg, Angew. Chem. Int. Ed. 45, 5987 (2006); (f) A.C. Filippou, K.W. Stumpf, O. Chernov, G. Schnakenburg, Organometallics 31, 748 (2012); (g) H. Hashimoto, T. Fukuda, H. Tobita, M. Ray, S. Sakaki, Angew. Chem. Int. Ed. 51, 2930 (2012); (h) A.C. Filippou, A. Barandov, G. Schnakenburg, B. Lewall, M. van Gastel, A. Marchanka, Angew. Chem. Int. Ed. 51, 789 (2012); (i) A.C. Filippou, U. Chakraborty, G. Schnakenburg, Chem. Eur. J. 19, 5676 (2013)

    Google Scholar 

  11. B.E. Eichler, A.D. Phillips, S.T. Haubrich, B.V. Mork, P.P. Power, Organometallics 21, 5622 (2002)

    Article  CAS  Google Scholar 

  12. A.C. Filippou, P. Portius, A.I. Philippopoulos, H. Rohde, Angew. Chem. Int. Ed. 42, 445 (2003)

    Article  CAS  Google Scholar 

  13. A.D. Phillips, R.J. Wright, M.M. Olmstead, P.P. Power, J. Am. Chem. Soc. 124, 5930 (2002)

    Article  CAS  Google Scholar 

  14. Selected references used in the publication for complexes with WSn single and double bonds: (a) W. Petz, Chem. Rev. 86, 1019 (1986); (b) M.S. Holt, W.L. Wilson, J.H. Nelson, Chem. Rev. 89, 11 (1989); (c) O. Kircher, G. Huttner, B. Schiemenz, K. Heinze, L. Zsolnai, O. Walter, A. Jakobi, A. Driess, Chem. Ber. 130, 687 (1997); (d) T. Szymanska-Buzar, T. Glowiak, Polyhedron 17, 3419 (1998); (e) H. Nakazawa, M. Kishishita, T. Ishiyama, T. Mizuta, K. Miyoshi, J. Organomet. Chem. 617, 453 (2001)

    Google Scholar 

  15. A.C. Filippou, A.I. Philippopoulos, G. Schnakenburg, Organometallics 22, 3339 (2003)

    Article  CAS  Google Scholar 

  16. A.C. Filippou, P. Ghana, U. Chakraborty, G. Schnakenburg, J. Am. Chem. Soc. 135, 11525 (2013)

    Article  CAS  Google Scholar 

  17. A.C. Filippou, H. Rohde, H. Schnakenburg, Angew. Chem. Int. Ed. 43, 2243 (2004)

    Article  CAS  Google Scholar 

  18. L. Pu, P.P. Power, I. Boltes, R. Herbst-Irmer, Organometallics 19, 352 (2000)

    Article  CAS  Google Scholar 

  19. L. Pu, B. Twamley, P.P. Power, J. Am. Chem. Soc. 122, 3524 (2000)

    Article  CAS  Google Scholar 

  20. A.C. Filippou, N. Weidemann, G. Schnakenburg, H. Rohde, A.I. Philippopoulos, Angew. Chem. Int. Ed. 43, 6512 (2004)

    Article  CAS  Google Scholar 

  21. A.C. Filippou, N. Weidemann, G. Schnakenburg, Angew. Chem. Int. Ed. 47, 5799 (2008)

    Article  CAS  Google Scholar 

  22. B.V. Mork, T.D. Tilley, Angew. Chem. Int. Ed. 42, 357 (2003)

    Article  CAS  Google Scholar 

  23. A.C. Filippou, O. Chernov, K.W. Stumpf, G. Schnakenburg, Angew. Chem. Int. Ed. 49, 3296 (2010)

    Article  CAS  Google Scholar 

  24. (a) B.V. Mork, T. Don Tilley, A.J. Schultz, J.A. Cowan, J. Am. Chem. Soc. 126, 10428 (2004); (b) M. Hirotsu, T. Nunokawa, K. Ueno, Organometallics 25, 1554 (2006); (c) S.H.A. Petri, D. Eikenberg, B. Neumann, H.-G. Stammler, P. Jutzi, Organometallics 18, 2615 (1999); (d) M. Haaf, T.A. Schmedake, R. West, Acc. Chem. Res. 33, 704 (2000); (e) S.B. Clendenning, B. Gehrhus, P.B. Hitchcock, D.F. Moser, J.F. Nixon, R. West, J. Chem. Soc. Dalton Trans. 484 (2002)

    Google Scholar 

  25. A.C. Filippou, O. Chernov, G. Schnakenburg, Angew. Chem. Int. Ed. 50, 1122 (2011)

    Article  CAS  Google Scholar 

  26. A.C. Filippou, B. Baars, O. Chernov, Y.N. Lebedev, G. Schnakenburg, Angew. Chem. Int. Ed. 53, 565 (2014)

    Article  CAS  Google Scholar 

  27. J. Li, A. Stasch, C. Schenk, C. Jones, Dalton Trans. 40, 10448 (2011)

    Article  CAS  Google Scholar 

  28. K.P. Pandey, M. Lein, G. Frenking, J. Am. Chem. Soc. 125, 1660 (2003)

    Article  CAS  Google Scholar 

  29. W.-P. Leung, W.-K. Chiu, T.C.W. Mak, Organometallics 31, 6966 (2012)

    Article  CAS  Google Scholar 

  30. B. Cordero, V. Gómez, A.E. Platero-Prats, M. Revés, J. Echeverría, E. Cremades, F. Barragán, S. Alvarez, Dalton Trans. 2832 (2008)

    Google Scholar 

  31. See selected reviews: (a) A.J.L. Pombiero, M.F. C. Guedes da Silva, R.A. Michelin, Coord. Chem. Rev. 218, 43 (2001); (b) R.L. Cordiner, A.F, Hill, J. Wagler, Organometallics 27, 4532 (2008)

    Google Scholar 

  32. S.J. Dossett, A.F. Hill, J.C. Jeffrey, F. Marken, P. Sherwood, F.G.A. Stone, J. Chem. Soc. Dalton Trans. 2453 (1988)

    Google Scholar 

  33. A.C. Filippou, W. Grünleitner, E.O. Fischer, J. Organomet. Chem. 413, 165 (1991)

    Article  CAS  Google Scholar 

  34. U. Behrens, F.J. Edelmann, J. Organomet. Chem. 263, 179 (1984)

    Article  CAS  Google Scholar 

  35. J. Hicks, T.J. Hadlington, C. Schenk, J. Li, C. Jones, Organometallics 32, 323 (2013)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Chemistry, Monash University, Clayton, Victoria, Australia

    Jamie Hicks

Authors
  1. Jamie Hicks
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jamie Hicks .

Rights and permissions

Reprints and permissions

Copyright information

© 2017 Springer Nature Singapore Pte Ltd.

About this chapter

Cite this chapter

Hicks, J. (2017). Preparation of Molybdenum Aminogermylene and Aminogermylyne Complexes. In: Preparation, Characterisation and Reactivity of Low Oxidation State d-Block Metal Complexes Stabilised by Extremely Bulky Amide Ligands. Springer Theses. Springer, Singapore. https://doi.org/10.1007/978-981-10-2905-9_6

Download citation

Publish with us

Policies and ethics

Search

Navigation