Abstract
Nickel-based superalloys are an exceptional class of structural materials for high temperature applications, particularly in the challenging environment of the turbine sections of aircraft engines. Continued improvements in the properties of these materials have been possible through close control of chemistry and microstructure as well as the introduction of advanced processing technologies. Surface modification by application of coating technology concurrent with the introduction of directional structures and then single crystals, has extended the useful temperature range of superalloys. Further improvements are likely with the development and implementation of tools for alloy design, microstructure-process evolution, and mechanical-property modelling. To date, six generations of single crystal (SC) nickel-based superalloys have been developed with improved creep properties and phase stability. Therefore it appears that the evolution of advanced nickel-based superalloys is a never ending process, and their replacement in turbine engine applications seems to be impossible at least for a few more decades. The present chapter is a brief review of various aspects pertaining to chemical composition, heat treatment, microstructure, properties and applications of both cast, and wrought alloys as well as the evolution of advanced cast nickel-based superalloys.
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References
Betteridge W (1974) The Nimonic alloys, and other Nickel-base high temperature alloys. In: Betteridge W, Heslop J (eds) Edward Arnold, London, UK
Sims CT, Stoloff NS, Hagel WC (1987) Superalloys II. Wiley, Hoboken, NJ, USA
Meetham GW, Van de Voorde MH (2000) Materials for high temperature engineering applications. Springer-Verlag, Berlin, Germany
Donachie MJ, Donachie SJ (2002) Superalloys: a technical guide, 2nd edn. ASM International. Materials Park, OH, USA
Reed RC (2006) The superalloys: fundamentals and applications. Cambridge University Press, Cambridge, UK
Muktinutalapati NR (2011) Materials for gas turbines—an overview, advances in gas turbine technology. Benini E (ed). Intech Open Source Publisher: book.department@intechopen.com, pp 293–314
MacKay A, Gabb TP, Smialek JL, Nathal MV (2009) Alloy design challenge: development of low density superalloys for turbine blade applications. Rebecca Glenn Research Center, Cleveland, Ohio 44135, NASA/TM—2009-215819
Caron P, Khan T, Evolution of Ni-based superalloys for single crystal gas turbine blade applications. Aerosp Sci Technol 3(8):513–523
Khan T (1986) High temperature alloys for gas turbines and other applications. In: Betz W et al (eds) D. Reidel Publishing Company, Dordrecht, Holland, p 21
Cetel AD, Duhl DN (1992) Second generation columnar grain Nickel-base superalloy. In: Antolo SD, Stusrud RW, MacKay RA, Anton L, Khan T, Kissinger RD, Klarstrom L (eds) Superalloys 1992, TMS, Warrendale, PA, USA, pp 287–296
Pollock TM, Tin S (2006) Propulsion and power, vol 22, 2, p 361
Diego Colombo (2006–2007) Nickel-based superalloys and their application in the aircraft industry. Anno accademico, Universita Deglistudi Di Trento, Italy
Caron P, Lavigne O (2011) Recent studies at onera on superalloys for single crystal turbine blades. J Aerosp Lab 3, pp 1–14
Second Generation single crystal superalloy(Developed under NIMS1/Toshiba2 collaboration), High Temperature Materials Group, Materials Engineering Laboratory (MEL), National Institute for Materials Science(NIMS), Japan, August, 2004
Li JR, Zhong ZG, Tang DZ, Liu SZ, Wei P, Wei PY, Wu ZT, Huang D, Han M (2000) A Low-cost second geneution single crystal superalloy DD6. In: Pollock TM, Kissinger RD, Bowman RR, Green KA, McLean S, Olson, Schina JJ (eds) Superalloys 2000, TMS, Warrendale, PA, USA, pp 777–783
Cetel AD, Duhl DN (1988) Second generation nickel base single crystal superalloy. In: Reichman S, lhhl DN, Maurer G, Antolovich, S, Lund C (eds) Superalloys 1988, TMS, Warrendale, PA, USA, pp 235–244
Ericson Gary L, JOM BS (2006) A new third generation, single crystal, casting superalloy 47(5):36–39
Walston S, O’Hara, KS, Ross EW, Pollock TM, Murphy WH (1996) RENE N6: third generation single crystal superalloy. In: Kissinger RD, Deye DJ, Anton DL, C&l AD, Nathal MV, Pollo TM, Woodford DA (eds) Superalloys 1996, TMS, Warrendale, PA, USA, pp 27–34
Caron P, Khan T (1996) Evolution of Ni-based superalloys for single crystal gas turbine blade applications. Office National d’Etudeset de Recherches Aérospatiales (ONERA), BP72 - 92322, Châtillon Cedex, France
Zietara M, Ceteland A, Czyrska-Filemonowicz A (2011), Microstructure stability of 4th generation single crystal superalloy, pwa 1497, during high temperature creep deformation. Materials Transactions, vol 52, no 3, pp 336–339
Walston S, Cetel A, MacKay R, O’Hara K, Duhl D, Dreshfield R (2004) Joint development of a fourth generation single crystal superalloy. In : 10th international symposium on superalloys cosponsored by the seven springs international symposium committee. The Minerals, Metals, and Materials Society (TMS), the TMS High Temperature Alloys Committee, and ASM International Champion, PA, USA, pp 19–23
Kawagishi Kyoko, Harada Hiroshi, Sato Akihiro, Kobayashi Toshiharu (2006) JOM 58(1):43–46
Sato A, Yeh AC, Kobayashi T, Yokokawa T, Harada H, Murakumo T, Zhang JX (2007) Energy materials 2(1):19–25
Sato A, Harada H, Yeh A-C, Kawagishi K, Kobayashi T, Koizumi Y, Tadaharu Y, Zhang J-X (2008) A 5th generation SC superalloy with balanced high temperature properties and processability. In: Reed RC, Green KA, Caron P, Gabb, Fahrman MG, Huron ES, Wodard SA (eds) Superalloys 2008, TMS, Warrendale, PA, USA, pp 131–138
Nickel base single crystal superalloys, TMS-196, July, 2008, High temperature materials center, National Institute for Materials Science, Japan
Kawagishi K, Yeh A-C, Yokokawa T, Kobayashi T, Koizumi Y, Harada H (2012) Development of an oxidation resistant high strength sixth generation SC superalloy. In: 12th international symposium on superalloys. In: Huron ES, Reed RC, Hardy MC, Mills MJ, Montero RE, Portella PD, Telesman J (eds) TMS, Warrendale, PA, USA, pp 189–195
Ross EW (1967) Rene 100-a sigma-free turbine blade alloy. J Met 19(12):12–14
Nystrom JD, Nystrom TM, Murphy WH, Garg A (1997) Discontinuous cellular precipitation in a high-refractory nickel-base superalloy. Metall Mater Trans 28A:2443–2452
Wlodek ST (1964) The structure of IN100. Trans ASM 57:110–119
Rae CMF, Reed RC (2001) The precipitation of topologically close-packed phases in rhenium-containing superalloys. Acta Mater 49(10):4113–4125
Darolia R, Lahrman DF, Field RD (1988) Formation of topologically closed packed phases in nickel base single crystal superalloys. TMS, Warrendale, PA, USA, pp 255–264
Agren J (1996) Calculation of phase diagrams: Calphad. Curr Opin Solid State Mater Sci 1:355–360
Kattner UR (1997) Thermodynamic modeling of multicomponent phase equilibria. J Met 49(12):14–19
Saunders N, Fahrmann M, Small CJ (2000) The application of CALPHAD calculations to Ni-Based superalloys. Superalloys 2000. TMS, Warrendale, PA, USA, pp 803–811
Wu K, Chang YA, Wang Y (2004) Simulating interdiffusion microstructuresin Ni–Al–Cr diffusion couples: a phase field approach coupled with calphad database. ScriptaMaterialia 50:1145–1150
Schilke PW (2004) Advanced gas turbine materials and coatings. Available at www.Gepower.com/prod-serv/products/tech-docs/en/downloads/ger3569.pdf
Loria ED (1989) Proceedings of conference on superalloy 718—metallurgy and applications, TMS, Warrendale, PA, USA
Loria ED (1991) Proceedings of conference on superalloy 718, 625 and various derivatives. TMS, Warrendale, PA, USA
Loria ED (1994) Superalloys 718, 625, and various derivatives. The Minerals, Metals & Materials Society, Warrendale, PA, USA
Loria ED (1997) Superalloys 718, 625, 706 and various derivatives. The Minerals, Metals & Materials Society. Warrendale, PA, USA
Loria ED (2001) Proceedings of the fifth international conference on superalloys 718, 625, 706 and various derivatives. TMS, Warrendale, PA, USA
Loria ED (2005) Proceedings of sixth international symposium on superalloys 718, 625, 706 and derivatives. TMS, Warrendale, PA, USA
Furrer D, Fecht H (1999) JOM, vol 51, 1, pp 14–17
Das N, Trans. IIM, vol 63, 210, pp 265–274
Tien JK, Caulfield T (1988) Superalloys, supercomposites and superceramics. Academic Press, New York, USA
Tin S, Pollock TM, Murphy W (2001) Stabilization of thermosolutal convective instabilities in Ni-based single crystal superalloys: carbon additions and freckle formation. Metall Mater Trans 32A(7):1743–1753
Tin S, Pollock TM (2004) Predicting freckle formation in single crystal Ni-base superalloys. J Mater Sci 39(24):7199–7205
Beckermann C, Gu JP, Boettinger WJ (2000) Development of a freckle predictor via rayleigh number method for single-crystal superalloy castings. Metall Mater Trans 31A(10):2545–2557
Wang W, Lee PD, McLean M (2003) A model of solidification microstructures in Nickel-Based superalloys: Predicting primary dendrite spacing selection. Acta Mater 51(10):2971–2987
Pollock TM, Murphy WH (1996) The breakdown of solidification in high refractory nickel-base superalloys. Metall Mater Trans 27A(4):1081–1094
Giamei AF, Kear BH (1970) Nature of freckles in nickel-base superalloys. Metall Trans A 1:2185–2192
Copley SM, Giamei AF, Johnson SM, Hornbecker MF (1970) Origin of freckles in unidirectionally solidified castings. Metall Trans A 1(8):2193–2204
Giamei AF, Tschinkel JG (1976) Liquid metal cooling—a new solidification technique. Metall Trans A 7A:1427–1434
Elliott AJ, Tin S, King WT, Huang SC, Gigliotti MFX, Pollock TM (2004) Directional solidification of large superalloy castings with radiation and liquid-metal cooling: a comparative assessment. Metall Mater Trans A 35A(10):3221–3231
Huron ES (1992) Serrated yielding in a nickel-base superalloy. TMS, Warrendale, PA, USA, pp 675–684
Pollock TM, Field RD (2002) Dislocations and high temperature plastic deformation of superalloy single crystals. In: Nabarro FRN, Duesbery MS (eds) Dislocations in solids, vol 11. Elsevier, Amsterdam, pp 549–618
Yoo MH (1986) ScriptaMetallurgica 20:915–920
Kear BH, Wilsdorf HGF (1962) Trans Metall Soc AIME 224:382–386
Copley SM, Kear BH (1967) Trans AIME 239:984–992
Murakumo T, Kobayashi T, Koizumi Y, Harada H (2004) Creep of Ni-base single-crystal superalloys with various gamma volume fraction. Acta Mater 52(12):3737–3744
Karunarante MSA, Reed RC (2003) Interdiffusion of platinum-group metals in nickel at elevated temperatures. Acta Mater 51(10):2905–2914
Reed RC, Karunarantne MSA (2000) Interdiffusion in the face-centered cubic Phase of Ni–Re, Ni–Ta and Ni–W systems between 900 °C and 1300 °C. Mater Sci Eng A 281(1–2):229–233
Walston WS, Cetel A, MacKay R, O’Hara K, Duhl D, Dreshfield R, Joint development of a fourth generation single crystal superalloy. TMS, Warrendale, PA, USA, pp 15–24
Tanaka R (2000) Research and development of ultra-high temperature materials in Japan. Mater High Temp 17(4):457–464
Shyam A, Torbet CJ, Jha SK, Larsen JM, Caton MJ, Szczepanski CJ, Pollock TM, Jones JW (2004) Development of ultrasonic fatigue for rapid, high temperature fatigue studies in turbine engine materials. TMS, Warrendale, PA, USA, pp 259–267
Miner RV, Gayada J, Maier RD (1982) Fatigue and creep fatigue deformation of several nickel-base superalloys at 650 °C. Metall Trans A 13A(10):1755–1765
Clavel M, Pineau A (1982) Fatigue behavior of two nickel-base alloys: Experimental results on low cycle fatigue, fatigue crack propagation and substructures. Mater Sci Eng 55(2):157–171
Chan KS, Hack JE, Leverant GR (1987) Fatigue crack growth in mar-m200 single crystals. Metall Trans 18A(4):581–591
Antolovich SD, Lerch B (1989) Cyclic deformation, fatigue and fatigue crack propagation in Ni-base alloys. In: Tien JK, Caulfield T (eds) Superalloys, supercomposites and superceramic. Academic Press, New York, USA, pp 363–412
Wright PK, Jain M, Cameron D (2004) High cycle fatigue in a single crystal superalloy: time dependence at elevated temperature. TMS, Warrendale, PA, pp 657–666
Crompton JS, Martin JW (1984) Crack growth in a single crystal superalloy at elevated temperature. Metall Trans A 15A:1711–1718
Larsen JM, Christodoulou (2004) Using materials prognosis to maximize the utilization of complex mechanical systems. J Met 56(3):15–28
Saunders N (1995) Phil Trans R Soc Lond A 351:543–561
Das N (2008) Unpublished work, DMRL, Hyderabad, India
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The authors acknowledge Dr. R. J. H. Wanhill for many useful and critical comments. They are thankful to the Director, DMRL, for his permission to publish this present work, and DRDO for financial support.
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Satyanarayana, D.V.V., Eswara Prasad, N. (2017). Nickel-Based Superalloys. In: Prasad, N., Wanhill, R. (eds) Aerospace Materials and Material Technologies . Indian Institute of Metals Series. Springer, Singapore. https://doi.org/10.1007/978-981-10-2134-3_9
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