Abstract
The industrial process of the selective hydrogenation of acetylene uses a gas-phase reaction with supported Pd or Pd–Ag catalysts in a fixed-bed reactor. The front-end process requires less equipment investment and a simpler process flow than the tail-end process.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Zhang QW, Li J, Liu XX et al (2000) Synergetic effect of Pd and Ag dispersed on Al2O3 in the selective hydrogenation of acetylene. Appl Catal A-Gen 197(2):221–228
Duca D, Frusteri F, Parmaliana A et al (1996) Selective hydrogenation of acetylene in ethylene feedstocks on Pd catalysts. Appl Catal A-Gen 146(2):269–284
Liu JY, Lu HM, Ling ZG et al (2008) Catalytic properties of supported Pd/SBA-15 catalyst for selective hydrogenation of alkadienes. Chin J Catal 29(3):206–208
Riyapan S, Boonyongmaneerat Y, Mekasuwandumrong O et al (2014) Improved catalytic performance of Pd/TiO2 in the selective hydrogenation of acetylene by using H2-treated sol-gel TiO2. J Mol Catal A-Chem 383:182–187
Komhom S, Mekasuwandumrong O, Panpranot J et al (2009) Influence of preparation method on the nanocrystalline porosity of α-Al2O3 and the catalytic properties of Pd/α-Al2O3 in selective acetylene hydrogenation. Ind Eng Chem Res 48(13):6273–6279
Zakumbayeva GD, Toktabayeva NF, Kubasheva AZ et al (1994) Influence of the degree of dispersion of palladium on the selective hydrogenation of acetylene in an ethane-ethylene fraction. Petro Chem 34(3):249–258
Khan NA, Uhl A, Shaikhutdinov S et al (2006) Alumina supported model Pd–Ag catalysts: a combined STM, XPS, TPD and IRAS study. Surf Sci 600(9):1849–1853
Khan NA, Shaikhutdinov S, Freund HJ (2006) Acetylene and ethylene hydrogenation on alumina supported Pd–Ag model catalysts. Catal Lett 108(3–4):159–164
Sheth PA, Neurock M, Smith CM (2005) First-principles analysis of the effects of alloying Pd with Ag for the catalytic hydrogenation of acetylene-ethylene mixtures. J Phys Chem B 109(25):12449–12466
Ma Y, Diemant T, Bansmann J et al (2011) The interaction of CO with PdAg/Pd(111) surface alloys—a case study of ensemble effects on a bimetallic surface. Phys Chem Chem Phys 13(22):10741–10754
Osswald J, Giedigkeit R, Jentoft RE et al (2008) Palladium-gallium intermetallic compounds for the selective hydrogenation of acetylene—part I: preparation and structural investigation under reaction conditions. J Catal 258(1):210–218
Osswald J, Kovnir K, Armbruester M et al (2008) Palladium-gallium intermetallic compounds for the selective hydrogenation of acetylene—part II: surface characterization and catalytic performance. J Catal 258(1):219–227
Kovnir K, Osswald J, Armbruester M et al (2006) PdGa and Pd3Ga7: highly-selective catalysts for the acetylene partial hydrogenation. Scientific bases for the preparation of heterogeneous catalysts, In: Proceedings of the 9th international symposium, vol 162, pp 481–488
Armbruester M, Wowsnick G, Friedrich M et al (2011) Synthesis and catalytic properties of nanoparticulate intermetallic Ga–Pd compounds. J Am Chem Soc 133(23):9112–9118
Tauster S, Fung S, Garten R (1978) Strong metal-support interactions. Group 8 noble metals supported on titanium dioxide. J Am Chem Soc 100(1):170–175
Kang JH, Shin EW, Kim WJ et al (2002) Selective hydrogenation of acetylene on TiO2-added Pd catalysts. J Catal 208(2):310–320
Borodzinski A, Bond GC (2008) Selective hydrogenation of ethyne in ethene-rich streams on palladium catalysts, part 2: steady-state kinetics and effects of palladium particle size, carbon monoxide, and promoters. Catal Rev 50(3):379–469
Praserthdam P, Phatanasri S, Meksikarin J (2000) Activation of acetylene selective hydrogenation catalysts using oxygen containing compounds. Catal Today 63(2–4):209–213
Ngamsom B, Bogdanchikova N, Borja MA et al (2004) Characterisations of Pd–Ag/Al2O3 catalysts for selective acetylene hydrogenation: Effect of pretreatment with NO and N2O. Catal Commun 5(5):243–248
Panpranot J, Aungkapipattanachai S, Sangvanich T et al (2007) Effect of N2O pretreatment on fresh and regenerated Pd–Ag/α-Al2O3 catalysts during selective hydrogenation of acetylene. React Kinet Catal Lett 91(2):195–202
Arras J, Paki E, Roth C et al (2010) How a supported metal is influenced by an ionic liquid: In-depth characterization of SCILL-type palladium catalysts and their hydrogen adsorption. J Phys Chem C 114(23):10520–10526
Jess A, Kern C, Korth W (2012) Solid catalyst with ionic liquid layer (SCILL)—a concept to improve the selectivity of selective liquid and gas phase hydrogenations. Oil Gas-Eur Mag 38(1):38–45
Kernchen U, Etzold B, Korth W et al (2007) Solid catalyst with ionic liquid layer (SCILL)—a new concept to improve selectivity illustrated by hydrogenation of cyclooctadiene. Chem Eng Technol 30(8):985–994
Herrmann T, Roessmann L, Lucas M et al (2011) High-performance supported catalysts with an ionic liquid layer for the selective hydrogenation of acetylene. Chem Commun 47(45):12310–12312
Ruta M, Laurenczy G, Dyson PJ et al (2008) Pd nanoparticles in a supported ionic liquid phase: highly stable catalysts for selective acetylene hydrogenation under continuous-flow conditions. J Phys Chem C 112(46):17814–17819
Lee JM, Palgunadi J, Kim JH et al (2010) Selective removal of acetylenes from olefin mixtures through specific physicochemical interactions of ionic liquids with acetylenes. Phys Chem Chem Phys 12(8):1812–1816
Hou R, Wang T, Lan X (2013) Enhanced selectivity in the hydrogenation of acetylene due to the addition of a liquid phase as a selective solvent. Ind Eng Chem Res 52(37):13305–13312
Edvinsson RK, Holmgren AM, Irandoust S (1995) Liquid-phase hydrogenation of acetylene in a monolithic catalyst reactor. Ind Eng Chem Res 34(1):94–100
Johnson MM, Peterson ER, Gattis SC et al (2005) US Patent 2005049445-A1
Cheung TP, Johnson MM (2005) US Patent 2005107649-A1
Shitova NB, Shlyapin DA, Afonasenko TN et al (2011) Liquid-phase hydrogenation of acetylene on the Pd/sibunit catalyst in the presence of carbon monoxide. Kinet Catal 52(2):251–257
Hou R, Lan X, Wang TF (2013) Enhanced selectivity in the hydrogenation of acetylene due to the addition of a liquid phase as a selective solvent. Ind Eng Chem Res 52(37):13305–13312
Garcia-Mota M, Bridier B, Perez-Ramirez J et al (2010) Interplay between carbon monoxide, hydrides, and carbides in selective alkyne hydrogenation on palladium. J Catal 273(2):92–102
Borodzinski A, Bond GC (2006) Selective hydrogenation of ethyne in ethene-rich streams on palladium catalysts. Part 1. Effect of changes to the catalyst during reaction. Catal Rev 48(02):91–144
Chen B (1988) Handbook of petroleum and chemical engineering: Basic materials. Chemical Industry Press, Beijing
Hou R, Lan X, Wang TF (2015) Selective hydrogenation of acetylene on Pd/SiO2 in bulk liquid phase: A comparison with solid catalyst with ionic liquid layer (SCILL). Catal Today 251:47–52
Ahn IY, Lee JH, Kum SS et al (2007) Formation of C4 species in the deactivation of a Pd/SiO2 catalyst during the selective hydrogenation of acetylene. Catal Today 123(1–4):151–157
Tew MW, Janousch M, Huthwelker T et al (2011) The roles of carbide and hydride in oxide-supported palladium nanoparticles for alkyne hydrogenation. J Catal 283(1):45–54
Knapp R, Jentys A, Lercher JA (2009) Impact of supported ionic liquids on supported Pt catalysts. Green Chem 11(5):656–661
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2017 Springer Science+Business Media Singapore
About this chapter
Cite this chapter
Hou, R. (2017). Selective Hydrogenation of Acetylene in Liquid Phase: A Novel Process. In: Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene. Springer Theses. Springer, Singapore. https://doi.org/10.1007/978-981-10-0773-6_6
Download citation
DOI: https://doi.org/10.1007/978-981-10-0773-6_6
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-10-0772-9
Online ISBN: 978-981-10-0773-6
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)