Abstract
This work presents a study of the structural, electrical, and dielectric properties of polymethylmethacrylate/polypyrrole composites. Structural analysis was performed using X-ray diffraction, showing an increase in the crystallinity index with the increasing of filler concentrations. The electrical conductivity mechanism and the dielectric relaxation process of these composites were studied in the frequency range from 100 Hz to 1 MHz and temperature range from 290 to 380 K, using impedance spectroscopy. The frequency-dependence of the conductivity is analyzed using the Jonscher power law. The values of the n exponent in this law are superior to 1, which is an indication that electron hopping occurs between neighboring sites. The Nyquist representations of the complex impedance spectra are modeled using the Cole-Cole model. The temperature dependence of both DC conductivity and relaxation process behaviors, using the Arrhenius equation, indicates that the conduction process is thermally activated.
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References
Kaur G, Adhikari R, Cass P, Bown M, Gunatillake P (2015) Electrically conductive polymers and composites for biomedical applications. RSC Adv 5:37553
Bouknaitir I, Aribou N, Elhad Kassim SA, El Hasnaoui M, Melo BMG, Achour ME, Costa LC (2017) Electrical properties of conducting polymer composites: experimental and modeling approaches. Spectro Lett 50:196
Mishra AK (2018) Conducting polymers: concepts and applications. J Atom Mol Cond Nano Phys 5:159
Bhadra S, Khastgir D, Singha NK, Lee JH (2009) Progress in preparation, processing and applications of polyaniline. Prog Polym Sci 34:783
Halik M, Klauk H, Zschieschang U, Schmid G, Ponomarenko S, Kirchmeyer S, Weber W (2003) Relationship between molecular structure and electrical performance of oligothiophene organic thin film transistors. Adv Mater 15:917
Soto-Oviedo MA, Araujo OA, Faez R, Rezende MC, De Paoli M-A (2006) Antistatic coating and electromagnetic shielding properties of a hybrid material based on polyaniline/organoclay nanocomposite and EPDM rubber. Synth Met 156:1249
El Hasnaoui M, Triki A, Achour ME, Arous M (2014) Modeling of dielectric relaxation processes of epoxy-resin filled with carbon black particles. Phys B Consens Matter 433:62
Aribou N, Nioua Y, Bouknaitir I, El Hasnaoui M, Achour ME, Costa LC (2019) Prediction of filler/matrix interphase effects on AC and DC electrical properties of carbon reinforced polymer composites. Polym Compos 40:346
Putson C, Lebrun L, Guyomar D, Muensit N, Cottinet P-J, Seveyrat L, Guiffard B (2011) Effects of copper filler sizes on the dielectric properties and the energy harvesting capability of nonpercolated polyurethane composites. J Appl Phys 109:024104
Evingür GA, Pekcan Ö. (2016) Carbon nanotubes –current progress of their polymer composites (MR Berber, IH Hafezeds), p 125. https://doi.org/10.5772/63054
Aliofkhazraei M (2019) Advances in nanostructured composites: volume 1: carbon nanotube and graphene composites. CRC Press
Bouknaitir I, Striccoli M, Panniello A, Costa LC, Teixeira SS, Achour ME, Kreit L, Corricelli M (2019) Optical and dielectric properties of PMMA (poly(methyl methacrylate))/carbon dots composites. Polym Compos 40:E1312
Elimat ZM (2006) AC electrical conductivity of poly(methyl methacrylate)/carbon black composite. J Phys D Appl Phys 39:2824
Dixit M, Gupta S, Mathur V, Rathore KS, Sharma K, Saxena NS (2009) Study of glass transition temperature of PMMA and CdS-PMMA composite. Chalcogenide Lett 6:131
Belhadj AM, Miane JL, Zangar H (2001) Radiofrequency and microwave (10 kHz–8 GHz) electrical properties of polypyrrole and polypyrrole–poly(methyl methacrylate) composites. Polym Int 50:773
Tripathi SN, Saini P, Gupta D, Choudhary V (2013) Electrical and mechanical properties of PMMA/reduced graphene oxide nanocomposites prepared via in situ polymerization. J Mater Sci 48:6223
Achour ME, Droussi A, Zoulef S, Gmati AF, Belhadj MA, Zangar H (2008) Electrical conductivity of polypyrrole-polymethylmethacrylate composites determined by impedance spectroscopy. Spectrosc Lett 41:328
Thomas P, Ernest Ravindran RS, Varma KBR (2014) Fabrication and characterization of poly(methyl methacrylate)/CaCu3Ti4O12 composites. Polym Eng Sci 54:551
Segal L, Creely JJ, Martin AE Jr, Conrad CM (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text Res J 29:786
Kumar M, Chakraborty S, Upadhyaya P, Pugazhenthi G (2017) Morphological, mechanical, and thermal features of PMMA nanocomposites containing two-dimensional Co–Al layered double hydroxide. J Appl Polym Sci 135:45774
Patel AK, Jain N, Patel P, Das K, Bajpai R (2018) Crystalline and absorption studies on PMMA/CdS composite using XRD & UV-Vis techniques. AIP Conf Proc 1942:070029
El-Zaher NA, Melegy MS, Guirguis OW (2014) Thermal and structural analyses of PMMA/TiO2 nanoparticles composites. Nat Sci 6:859
Stauffer D, Aharony A (1992) Introduction to percolation theory. Taylor and Francis, London
Kirkpatrick S (1973) Percolation and conduction. Rev Mod Phys 45:574
Aribou N, Barnoss S., El Hasnaoui M, Achour ME, Costa LC (2019). Structural, electrical and thermal properties of composites based on conducting polymer. Jordan J Phy Accepted
Ou R, Gupta S, Parker CA, Gerhardt RA (2006) Fabrication and electrical conductivity of poly(methyl methacrylate) (PMMA)/carbon black (CB) composites: comparison between an ordered carbon black nanowire-like segregated structure and a randomly dispersed carbon black nanostructure. J Phys Chem B 110:22365
Kausar A (2019) Interpenetrating polymer network and nanocomposite IPN of polyurethane/epoxy: a review on fundamentals and advancements. Polym -Plast Polym Plast Technol Mater 58:691
Deepa KS, Kumari Nisha S, Parameswaran P, Sebastian MT, James J (2009) Effect of conductivity of filler on the percolation threshold of composites. Appl Phys Lett 94:142902
Kilbride BE, Coleman JN, Fraysse J, Fournet P, Cadek M, Drury A, Hutzler S, Roth S, Blau WJ (2002) Experimental observation of scaling laws for alternating current and direct current conductivity in polymer-carbon nanotube composite thin films. J Appl Phys 92:4024
Sinha S, Chatterjee SK, Ghosh J, Meikap AK (2015) Analysis of the dielectric relaxation and ac conductivity behavior of polyvinyl alcohol-cadmium selenide nanocomposite films. Polym Compos 38:287
Jonscher AK (1983) Dielectric relaxation in solids. Chelsea Dielectric, London
Funke K (1993) Jump relaxation in solid electrolytes. Prog Solid State Chem 22:111
Elliott SR (1987) A.c. conduction in amorphous chalcogenide and pnictide semiconductors. Adv Phys 36:135
Bairlein K, Bücker M, Hördt A, Hinze B (2016) Temperature dependence of spectral induced polarization data: experimental results and membrane polarization theory. Geophys J Int 205:440
Debye P (1945) Polar molecules. Dover, New York
Cole KS, Cole RH (1941) Dispersion and absorption in dielectrics I. alternating current characteristics. J Chem Phys 9:341
Clayton LM, Knudsen B, Cinke M, Meyyappan M, Harmon JP (2007) DC conductivity and interfacial polarization in PMMA/nanotube and PMMA/soot composites. J Nanosci Nanotechnol 7:3572
El Hasnaoui M, Graça MPF, Achour ME, Costa LC (2011) Electric modulus analysis of carbon black/copolymer composite materials. Mater Sci Appl 2:1421
El Hasnaoui M, Graça MPF, Achour ME, Costa LC, Lahjomri F, Outzourhit A, Oueriagli A (2011) Electrical properties of CB/ copolymer composites above and below the melting temperature. J Mater Environ Sci 2:1
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Barnoss, S., Aribou, N., Nioua, Y., El Hasnaoui, M., Achour, M.E., Costa, L.C. (2020). Dielectric Properties of PMMA/PPy Composite Materials. In: Petkov, P., Achour, M., Popov, C. (eds) Nanoscience and Nanotechnology in Security and Protection against CBRN Threats. NATO Science for Peace and Security Series B: Physics and Biophysics. Springer, Dordrecht. https://doi.org/10.1007/978-94-024-2018-0_21
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DOI: https://doi.org/10.1007/978-94-024-2018-0_21
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