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Preparation of Nanoporous Hybrid Materials with Bridged Tetra Sulfide Functional Groups and Determination of Their Sensing Characteristics Towards Relative Humidity

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Advanced Nanotechnologies for Detection and Defence against CBRN Agents

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Abstract

Nano porous hybrid materials were synthesized by co-condensation of organically bridged tetra sulfide bis [3-(triethoxysilyl) propyl] tetra sulfide (BTPTS) and tetra ethoxylsilane (TEOS) in the presence of the non-ionic surfactant triblock copolymer poly(ethylene glycol)-block-poly (propylene glycol)-block-poly (ethylene glycol) (EO20PO70EO20) in acidic media as revealed by the measurement of nitrogen adsorption. The structure and chemical state of the materials were characterized by chemical analysis, Fourier–transform infrared spectroscopy (FTIR), 29Si MAS NMR, and thermo-gravimetric analysis (DTA/TG), revealing the integrity of organic groups inside the framework. The synthesized powders were prepared as sensors using the screen-printing technique and then evaluated on view of their sensing characteristics in the range from 0.0% to 96% relative humidity (RH) at room temperature. Sensors with a higher content of BTPTS show a better response towards RH.

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Acknowledgments

The authors gratefully acknowledge Professor Jean Marc Tulliani from department of applied science and technology (DISAT), Politecnico di Torino, Turin, Italy, for working in his laboratory facilities for gas sensors testing and useful discussions.

Author information

Authors and Affiliations

  1. Research and Development Department, MEPACO-MEDIFOOD, Cairo, Egypt

    M. Abdallah

  2. Department of Silicate Technology, University of Chemical Technology and Metallurgy, Sofia, Bulgaria

    M. Abdallah, N. Velikova & Y. Ivanova

  3. Department of Applied Science and Technology (DISAT), Politecnico di Torino, Torino, Italy

    Ahmed S. Afify & M. Hassan

  4. Faculty of Engineering and technology, Badr University in Cairo (BUC), Badr City, Egypt

    M. Ataalla

  5. Department of Natural Science, Obour Institute of Engineering and Technology, Cairo, Egypt

    M. Hassan

Authors
  1. M. Abdallah
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  2. N. Velikova
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  3. Y. Ivanova
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  4. Ahmed S. Afify
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  5. M. Ataalla
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  6. M. Hassan
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Editor information

Editors and Affiliations

  1. Department of Physics, University of Chemical Technology & Metallurgy, Sofia, Bulgaria

    Plamen Petkov

  2. Department of Physics, Technical University of Moldova, Chisinau, Moldova

    Dumitru Tsiulyanu

  3. Institute of Nanostructure Technologies and Analytics, University of Kassel, Kassel, Germany

    Cyril Popov

  4. Department of Mathematics and Natural Sciences, University of Kassel, Kassel, Germany

    Wilhelm Kulisch

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Abdallah, M., Velikova, N., Ivanova, Y., Afify, A.S., Ataalla, M., Hassan, M. (2018). Preparation of Nanoporous Hybrid Materials with Bridged Tetra Sulfide Functional Groups and Determination of Their Sensing Characteristics Towards Relative Humidity. In: Petkov, P., Tsiulyanu, D., Popov, C., Kulisch, W. (eds) Advanced Nanotechnologies for Detection and Defence against CBRN Agents. NATO Science for Peace and Security Series B: Physics and Biophysics. Springer, Dordrecht. https://doi.org/10.1007/978-94-024-1298-7_40

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