Skip to main content

Structure and Growth of Latex Particles

  • Chapter
Science and Technology of Polymer Colloids

Part of the book series: NATO ASI Series ((NSSE,volume 67-68))

Abstract

The morphology of latex particles is of interest because of the structural implications regarding growth mechanisms involved in emulsion polymerization and because of the practical expectation of certain beneficial effects obtained from structured particles. Since process and properties are so closely linked in the production of emulsion polymers, a variety of processes have been devised as efforts to design and control the microstructure of latex particles have intensified. The central issue is whether, as a general rule, particle growth is better represented in terms of a surface growth model or of a bulk polymerization model. Results obtained by a variety of methods developed to study particle and film morphology will be reviewed, and the special case of water-soluble monomers will be considered along with descriptions of process techniques designed to control particle structure.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

eBook
USD 16.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 16.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Smith, W. V. and R. H. Ewart, J. Chem. Phys. 16 (1948) 592.

    Article  CAS  Google Scholar 

  2. Fitch, R. M. “Emulsion Polymers and Emulsion Polymerization”, ACS Symposium Series, No. 165 (1981) 1.

    Article  CAS  Google Scholar 

  3. Ugelstad, J., M. S. El-Aasser and J. W. Vanderhoff, J. Polymer. Sci., Polym. Letters Ed. 11 (1973) 503.

    Google Scholar 

  4. Grancio, M. R. and D. J. Williams, J. Polym. Sci., A-1, 8 (1970) 2617, 2733.

    Google Scholar 

  5. Keusch, P. and D. J. Williams, J. Polym. Sci., Polym. Chem. Ed. 11 (1973) 143.

    Google Scholar 

  6. Keusch, P., J. Prince and D. J. Williams, J. Macromol. Sci. -Chem. A7 (1973) 623.

    Google Scholar 

  7. Morton, M., S. Kaizermann and M. W. Altier, J. Colloid Sci. 9 (1954) 300.

    Article  CAS  Google Scholar 

  8. Gardon, J. L. J. Polym. Sci., Polym. Chem. Ed. 11 (1973) 241.

    Google Scholar 

  9. Napper, D. H. J. Polym. Sci., A-1, 9 (1971) 2089.

    CAS  Google Scholar 

  10. Vanderhoff, J. W. Proc. Water-Borne-and High Solids Coatings Symp., New Orleans, 1976.

    Google Scholar 

  11. Chung -li, Y., J. W. Goodwin and R. H. Ottewill, Prog. Colloid Polym. Sci. 60 (1976) 163.

    CAS  Google Scholar 

  12. Fitch, R. M. and C. H. Tsai, “Polymer Colloids”, R. M. Fitch, ed., Plenum Press, New York (1971) 73.

    Book  Google Scholar 

  13. Peppard, B. D. Dissertation, Iowa State Univ., 1974.

    Google Scholar 

  14. Yeliseyeva, V. I. “Emulsion Polymerization”, I. Piirma, ed., Academic Press, New York (1982) 247.

    Google Scholar 

  15. Vijayendran, B. R. “Polymer Colloids II”, R. M. Fitch, ed., Plenum Press, New York (1980) 209.

    Google Scholar 

  16. Okubo, M., A. Yamada and T. Matsumoto, J. Polym. Sci., Polym. Chem. Ed. 18 (1980) 3219.

    Google Scholar 

  17. Lee, D. I.“Emulsion Polymers and Emulsion Polymerization”, ACS Symposium Series, No. 165 (1981) 406.

    Google Scholar 

  18. Misra, S. C., C. Pichot, M. S. El-Aasser and J. W. Vanderhoff, J. Polym. Sci., Polym. Letters Ed. 17 (1979) 567.

    Google Scholar 

  19. Kanig. G. and H. Neff, Colloid and Polymer Sci. 253 (1975) 29.

    Google Scholar 

  20. See, for example, C. F. Ryan and R. J. Grochowski, US 3,448,178 (Rohm and Haas); D. R. Gehman, J. M. Owens and R. E. Zdanowski, US 4,150,005 (Rohm and Haas); R. A. Dickie and S. Newman, US 3,787,522 (Ford Motor Co.).

    Google Scholar 

  21. Bassett, D. R. and K. L. Hoy, US 3,804,881 (Union Carbide Corp.)

    Google Scholar 

  22. Bassett, D. R. and K. L. Hoy, “Emulsion Polymers andEmulsion Polymerization”, ACS Symposium Series, No. 165 (1981) 371.

    Article  CAS  Google Scholar 

  23. Bassett, D. R. and K. L. Hoy, US 4,039,500 (Union Carbide Corp.)

    Google Scholar 

  24. Johnston, J. E., D. R. Bassett and T. B. MacRury, “Emulsion Polymers and Emulsion Polymerization”, ACS Symposium Series, No. 165 (1981) 389.

    Article  CAS  Google Scholar 

  25. Pichot, C., M. F. Llauro and Q. T. Pham. J. Polym. Sci., Polym. Chem. Ed. 19 (1981) 2619.

    Google Scholar 

  26. Guyot, A., J. Guillot, C. Pichot and L. Rios Guerrero, “Emulsion Polymers and Emulsion Polymerization”, ACS Symposium Series, No. 165 (1981) 415.

    Article  CAS  Google Scholar 

  27. Yeliseyeva, V. I., S. A. Petrova and A. V. Zuikov, J. Polym. Sci., Pt. C (1973) 63.

    Google Scholar 

  28. Yeliseyeva, V. I., Brit. Polym. J. 7 (1975) 33.

    Article  Google Scholar 

  29. Yeliseyeva, V. I., S. S. Ivanchev, S. I. Kushanov and A. V. Lebedev, “Emulsion Polymerization and its Applications in Industry”, Consultants Bureau, New York (1981) 139.

    Book  Google Scholar 

  30. Distler, D. and G. Kanig, Colloid and Polymer Sci., 256 (1978) 1052.

    Article  CAS  Google Scholar 

  31. Bassett, D. R., E. J. Derderian, J. E. Johnston and T. B. MacRury, “Emulsion Polymers and Emulsion Polymerization”, ACS Symposium Series, No. 165 (1981) 263.

    Article  CAS  Google Scholar 

  32. Bassett, D. R. and K. L. Hoy, “Polymer Colloids II”, R. M. Fitch, ed., Plenum Press, New York (1980) 1.

    Google Scholar 

  33. Ford, J. R., R. L. Rowell and D. R. Bassett, “Emulsion Polymers and Emulsion Polymerization”, ACS Symposium Series, No. 165 (1981) 279.

    Article  CAS  Google Scholar 

  34. Van den Hul, H. J. and J. W. Vanderhoff, Brit. Polym. J. 2 (1970) 121.

    Article  Google Scholar 

  35. Green, B. W., J. Colloid Interface Sci. 43 (1973) 449, 462.

    Article  Google Scholar 

  36. Hern, J., J. Colloid Interface Sci. 49 (1974) 425.

    Article  Google Scholar 

  37. Vijayendran, J. Appl. Polym. Sci. 23 (1979) 893.

    CAS  Google Scholar 

  38. Nishita, S., M. S. El-Aasser, A. Klein and J. W. Vanderhoff, “Emulsion Polymers and Emulsion Polymerization, ACS Symposium Series, No. 165 (1981) 291.

    Article  Google Scholar 

  39. Bassett, D. R., unpublished results.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1983 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Bassett, D.R. (1983). Structure and Growth of Latex Particles. In: Poehlein, G.W., Ottewill, R.H., Goodwin, J.W. (eds) Science and Technology of Polymer Colloids. NATO ASI Series, vol 67-68. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-4797-4_10

Download citation

  • DOI: https://doi.org/10.1007/978-94-017-4797-4_10

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-247-2832-9

  • Online ISBN: 978-94-017-4797-4

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics