Abstract
The morphology of latex particles is of interest because of the structural implications regarding growth mechanisms involved in emulsion polymerization and because of the practical expectation of certain beneficial effects obtained from structured particles. Since process and properties are so closely linked in the production of emulsion polymers, a variety of processes have been devised as efforts to design and control the microstructure of latex particles have intensified. The central issue is whether, as a general rule, particle growth is better represented in terms of a surface growth model or of a bulk polymerization model. Results obtained by a variety of methods developed to study particle and film morphology will be reviewed, and the special case of water-soluble monomers will be considered along with descriptions of process techniques designed to control particle structure.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Smith, W. V. and R. H. Ewart, J. Chem. Phys. 16 (1948) 592.
Fitch, R. M. “Emulsion Polymers and Emulsion Polymerization”, ACS Symposium Series, No. 165 (1981) 1.
Ugelstad, J., M. S. El-Aasser and J. W. Vanderhoff, J. Polymer. Sci., Polym. Letters Ed. 11 (1973) 503.
Grancio, M. R. and D. J. Williams, J. Polym. Sci., A-1, 8 (1970) 2617, 2733.
Keusch, P. and D. J. Williams, J. Polym. Sci., Polym. Chem. Ed. 11 (1973) 143.
Keusch, P., J. Prince and D. J. Williams, J. Macromol. Sci. -Chem. A7 (1973) 623.
Morton, M., S. Kaizermann and M. W. Altier, J. Colloid Sci. 9 (1954) 300.
Gardon, J. L. J. Polym. Sci., Polym. Chem. Ed. 11 (1973) 241.
Napper, D. H. J. Polym. Sci., A-1, 9 (1971) 2089.
Vanderhoff, J. W. Proc. Water-Borne-and High Solids Coatings Symp., New Orleans, 1976.
Chung -li, Y., J. W. Goodwin and R. H. Ottewill, Prog. Colloid Polym. Sci. 60 (1976) 163.
Fitch, R. M. and C. H. Tsai, “Polymer Colloids”, R. M. Fitch, ed., Plenum Press, New York (1971) 73.
Peppard, B. D. Dissertation, Iowa State Univ., 1974.
Yeliseyeva, V. I. “Emulsion Polymerization”, I. Piirma, ed., Academic Press, New York (1982) 247.
Vijayendran, B. R. “Polymer Colloids II”, R. M. Fitch, ed., Plenum Press, New York (1980) 209.
Okubo, M., A. Yamada and T. Matsumoto, J. Polym. Sci., Polym. Chem. Ed. 18 (1980) 3219.
Lee, D. I.“Emulsion Polymers and Emulsion Polymerization”, ACS Symposium Series, No. 165 (1981) 406.
Misra, S. C., C. Pichot, M. S. El-Aasser and J. W. Vanderhoff, J. Polym. Sci., Polym. Letters Ed. 17 (1979) 567.
Kanig. G. and H. Neff, Colloid and Polymer Sci. 253 (1975) 29.
See, for example, C. F. Ryan and R. J. Grochowski, US 3,448,178 (Rohm and Haas); D. R. Gehman, J. M. Owens and R. E. Zdanowski, US 4,150,005 (Rohm and Haas); R. A. Dickie and S. Newman, US 3,787,522 (Ford Motor Co.).
Bassett, D. R. and K. L. Hoy, US 3,804,881 (Union Carbide Corp.)
Bassett, D. R. and K. L. Hoy, “Emulsion Polymers andEmulsion Polymerization”, ACS Symposium Series, No. 165 (1981) 371.
Bassett, D. R. and K. L. Hoy, US 4,039,500 (Union Carbide Corp.)
Johnston, J. E., D. R. Bassett and T. B. MacRury, “Emulsion Polymers and Emulsion Polymerization”, ACS Symposium Series, No. 165 (1981) 389.
Pichot, C., M. F. Llauro and Q. T. Pham. J. Polym. Sci., Polym. Chem. Ed. 19 (1981) 2619.
Guyot, A., J. Guillot, C. Pichot and L. Rios Guerrero, “Emulsion Polymers and Emulsion Polymerization”, ACS Symposium Series, No. 165 (1981) 415.
Yeliseyeva, V. I., S. A. Petrova and A. V. Zuikov, J. Polym. Sci., Pt. C (1973) 63.
Yeliseyeva, V. I., Brit. Polym. J. 7 (1975) 33.
Yeliseyeva, V. I., S. S. Ivanchev, S. I. Kushanov and A. V. Lebedev, “Emulsion Polymerization and its Applications in Industry”, Consultants Bureau, New York (1981) 139.
Distler, D. and G. Kanig, Colloid and Polymer Sci., 256 (1978) 1052.
Bassett, D. R., E. J. Derderian, J. E. Johnston and T. B. MacRury, “Emulsion Polymers and Emulsion Polymerization”, ACS Symposium Series, No. 165 (1981) 263.
Bassett, D. R. and K. L. Hoy, “Polymer Colloids II”, R. M. Fitch, ed., Plenum Press, New York (1980) 1.
Ford, J. R., R. L. Rowell and D. R. Bassett, “Emulsion Polymers and Emulsion Polymerization”, ACS Symposium Series, No. 165 (1981) 279.
Van den Hul, H. J. and J. W. Vanderhoff, Brit. Polym. J. 2 (1970) 121.
Green, B. W., J. Colloid Interface Sci. 43 (1973) 449, 462.
Hern, J., J. Colloid Interface Sci. 49 (1974) 425.
Vijayendran, J. Appl. Polym. Sci. 23 (1979) 893.
Nishita, S., M. S. El-Aasser, A. Klein and J. W. Vanderhoff, “Emulsion Polymers and Emulsion Polymerization, ACS Symposium Series, No. 165 (1981) 291.
Bassett, D. R., unpublished results.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1983 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Bassett, D.R. (1983). Structure and Growth of Latex Particles. In: Poehlein, G.W., Ottewill, R.H., Goodwin, J.W. (eds) Science and Technology of Polymer Colloids. NATO ASI Series, vol 67-68. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-4797-4_10
Download citation
DOI: https://doi.org/10.1007/978-94-017-4797-4_10
Publisher Name: Springer, Dordrecht
Print ISBN: 978-90-247-2832-9
Online ISBN: 978-94-017-4797-4
eBook Packages: Springer Book Archive