Skip to main content

Part of the book series: NATO ASI Series ((NSSE,volume 2))

Abstract

Cationic polymer colloids are a diverse group of materials. They have two common features: a particulate morphology in aqueous dispersion and a net positive charge on the dispersed particles. They represent only a small fraction of known polymer colloids (most of which are anionic), and have been of little commercial significance until quite recently (1–6). Accordingly, they have not drawn the attention of many colloid and polymer scientists.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. R. J. Noble, Latex in Industry 2nd Ed. (Rubber Age, New York, 1953).

    Google Scholar 

  2. G. S. Whitby (ed) Synthetic Rubber, (J. Wiley & Sons, New York, 1954).

    Google Scholar 

  3. F. A. Bovey, I. M. Kolthoff, A. I. Medalia, and E. J. Meehan, Emulsion Polymerization (Interscience Pub Co., New York, 1955).

    Google Scholar 

  4. D. C. Blackley, High Polymer Latexes, Vol. I and II, (Palmerton Pub. Co., New York, 1966).

    Google Scholar 

  5. M. Wismer et. al., J. Coat. Tech. 54(688) (1982) 35.

    CAS  Google Scholar 

  6. H. Warson, The Applications of Synthetic Resin Emulsions, (E. Benn, London, 1972).

    Google Scholar 

  7. L. Bateman (ed), The Chemistry and Physics of Rubberlike Substances, (J. Wiley & Sons, New York, 1963) Chapters 3, 4.

    Google Scholar 

  8. A. Southhorn, Chem. Ind., May 3 (1981), 363.

    Google Scholar 

  9. I. Kemp, and D. F. Twiss, Trans. Faraday Soc. 32 (1936) 890.

    Article  CAS  Google Scholar 

  10. D. F. Twiss, A. S. Carpenter, and P. H. Amphlett, Trans. Faraday Soc., 36 (1940) 264.

    Article  CAS  Google Scholar 

  11. J. Sarrut Rubber Chem. Tech. 20 (1947) 63.

    Google Scholar 

  12. B. Dales and F. B. Downing, U.S. 2,138,226 (1938).

    Google Scholar 

  13. C. F. Frying, in Ref. 2, Chap. 8.

    Google Scholar 

  14. C. E. Schildknecht, Vinyl and Related Polymers (J. Wiley & Sons, New York, 1952), p. 86.

    Google Scholar 

  15. J. H. Baxendale, M. G. Evans, and J. H. Killam, J. Polymer Sci 1 (1946) 466.

    Article  CAS  Google Scholar 

  16. E. V. Zabolotskaya, et. al., Colloid J.U.S.S.R., 18 (1956) 413.

    Google Scholar 

  17. A. P. Sheinker and S. S. Medvedev, Rubber Chem. Tech., 29 (1956) 121.

    Article  CAS  Google Scholar 

  18. F. A. Bovey and I. M. Kolthoff, J. Polymer Sci., 5 (1950) 487.

    Article  CAS  Google Scholar 

  19. F. A. Bovey and I. M. Kolthoff J. Polymer Sci., 5 (1950) 696.

    Google Scholar 

  20. I. M. Kolthoff and F. A. Bovey, J. Amer. Chem. Soc, 70 (1948) 791.

    Article  CAS  Google Scholar 

  21. J. W. Goodwin, R. H. Ottewill, and R. Pelton, Coll. Polymer Sci., 257 (1979) 61.

    Article  CAS  Google Scholar 

  22. B. W. Brooks and B. O. Makanjuola, J. Chem. Soc. Faraday Trans. I 77 (1981) 2659.

    Article  CAS  Google Scholar 

  23. A. R. M. Azad, et. al., in I. Pirrima and J. L. Gardon (eds) Emulsion Polymerization, ACS Symp. Ser. 24 (Washington, D.C., 1976), Chapter 1.

    Google Scholar 

  24. L. H. Howland et. al., Ind. Eng. Chem. 44 (1952) 762.

    Article  CAS  Google Scholar 

  25. A. F. Helin, et. al., Ind. Eng. Chem. 45 (1953) 1330.

    Article  CAS  Google Scholar 

  26. S. H. Maron and M. E. Elder, J. Coll. Sci. 9 (1954) 353.

    Article  CAS  Google Scholar 

  27. W. C. Mast and C. H. Fisher, Ind. Eng. Chem., 41 (1949) 790.

    Article  CAS  Google Scholar 

  28. D. R. Johnson, Rubber Chem. Tech., 49 (1976) 650.

    Article  CAS  Google Scholar 

  29. G. E. F. Brewer, J. Paint Tech., 45(587) (1973) 37.

    Google Scholar 

  30. F. Beck, Farbe Lack, 72 (1966) 218.

    CAS  Google Scholar 

  31. F. Beck, H. Pohleman and H. Spoor, Farbe Lack, 73 (1967) 298.

    CAS  Google Scholar 

  32. R. A. Wessling, D. S. Gibbs, W. J. Settineri, and E. H. Wagener in G. E. F. Brewer (ed), Electrodeposition of Coating, ACS #119, (ACS, Washington, D.C., 1973), Chapter 8.

    Google Scholar 

  33. M. Wismer and J. F. Bosso, Chem. Eng. 78(13) (1971) 115.

    Google Scholar 

  34. H. V. Schenk, H. Spoor, and M. Marx, Prog. Org. Coatings, 7 (1979) 1.

    Article  Google Scholar 

  35. F. Beck, Prog. Org. Coatings, 4 (1976) 1.

    Article  CAS  Google Scholar 

  36. E. H. Wagener, S. F. Kurowsky, D. S. Gibbs, and R. A. Wessling in J. L. Gardon and J. Piirma (eds), Emulsion Polymerization ACS #24 (ACS, Washington, D.C., 1976), Chapter 18.

    Google Scholar 

  37. D. G. Anderson, E. J. Murphy, and J. Tucci, J. Coat. Tech., 50(646) (1978) 38.

    Google Scholar 

  38. P. E. Pierce, J. Coat. Tech., 53(672), (1981) 52.

    CAS  Google Scholar 

  39. J. P. Vollmer, Surfaces, 16 (1977) 33.

    CAS  Google Scholar 

  40. H. V. Schenk and J. Stoelting, J. Oil Col. Chem. Assoc. 63 (1980) 482.

    Google Scholar 

  41. R. A. Wessling, in 6th International Conference in Organic Coatings Science and Technology, Technomic Pub Co., Westport, CT (1982).

    Google Scholar 

  42. D. Dieterich, Prog. Org. Coatings 9 (1981) 281.

    Article  CAS  Google Scholar 

  43. G. D. Jones in K. C. Frisch, D. Klempner and A. V. Patsis (eds), Polyelectrolytes, (Technomic Pub. Co., Westport, CT, 1976) pp 144–176.

    Google Scholar 

  44. M. J. Hatch, Prog. Org. Coatings, 4 (1976) 73.

    Article  Google Scholar 

  45. M. F. Hoover and G. B. Butler, J. Polymer Sci. Symp. 45 (1974) 1.

    Article  CAS  Google Scholar 

  46. M. F. Hoover, J. Macromol. Sci. Chem., 4 (1970) 1327.

    Article  CAS  Google Scholar 

  47. D. S. Gibbs, E. H. Wagener, and R. A. Wessling, U.S. 4,056,501 (1977).

    Google Scholar 

  48. L. A. Gugliemelli et. al., J.Polymer Sci. Chem., 12 (1974) 2683.

    Article  CAS  Google Scholar 

  49. M. S. El-Aasser et. al., Org. Coat. Plast. Chem., 43 (1980) 136.

    CAS  Google Scholar 

  50. R. A. Wessling, W. O. Perry, and L. D. Yats, Paper Presented at 14th Regional ACS Meeting, Midland, MI (1982).

    Google Scholar 

  51. J. Selb and Y. Gallot, Makromol. Chem. 182 (1981) 1491.

    Article  CAS  Google Scholar 

  52. R. A. Wessling and D. M. Pickelman, J.Dispersion Sci. Tech., 2 (1981) 281.

    Article  CAS  Google Scholar 

  53. S. L. Regen, B. Czeck and A. Singh, J.Amer. Chem. Soc., 102 (1980) 6638.

    Article  CAS  Google Scholar 

  54. W. G. Lloyd and J. F. Vitkuske, J. Appl. Polymer Sci., 6 (1962) S57.

    Article  CAS  Google Scholar 

  55. R. A. Wessling, A Review of Cationic Latex Technology in Advances in Emulsion Polymerization and Latex Technology, Vol. II (Emulsion Polymers Institute, Lehigh Univ., Bethlehem, PA, 1979).

    Google Scholar 

  56. A. Albert, Ionization Constants of Acids and Bases, (J. Wiley & Sons, New York, 1962) Chapter 8.

    Google Scholar 

  57. S. Siggia and J. G. Hanna, Organic Quantitative Analysis Via Functional Groups, 4th ed., (J. Wiley & Sons, New York 1979), Chapter 11.

    Google Scholar 

  58. L. J. Liu and I. M. Krieger in P. Becher and M. N. Yudenfreund (eds), Emulsions, Latexes, and Dispersions, (M. Dekker, New York, 1978) pp 41–69.

    Google Scholar 

  59. L. J. Liu and I. M. Krieger, J.Polymer Science, 19 (1981) 3013.

    CAS  Google Scholar 

  60. K. Sakota and T. Okaya, J.Appl. Polymer Sci., 20 (1976) 1725.

    Article  CAS  Google Scholar 

  61. K. Sakota and T. Okaya J.Appl. Polymer Sci., 20 (1976) 3133.

    Article  CAS  Google Scholar 

  62. K. Sakota and T. Okaya J.Appl. Polymer Sci., 21 (1977) 1009.

    Article  CAS  Google Scholar 

  63. H. Morawetz, Macromolecules in Solutions, (J. Wiley & Sons, New York 1375), Chapter 7.

    Google Scholar 

  64. G. W. Burton and C. P. O’Farrell, J.Elast. Plast. 9 (1977) 94.

    CAS  Google Scholar 

  65. R. F. Harris and E. G. Wagener, U.S. 4,039,663 (1978).

    Google Scholar 

  66. V. J. Webers, U.S. 2,676,166 (1954).

    Google Scholar 

  67. L. A. Gugliemelli, W. M. Doane, and C. R. Russell, J.Appl. Poly. Sci., 23 (1979) 635.

    Article  CAS  Google Scholar 

  68. L. A. Gugliemelli et. al., J.Appl. Poly. Sci., 20 (1975) 3175.

    Article  Google Scholar 

  69. L. A. Gugliemelli et. al., J.Polymer Sci. B, 14 (1976) 215.

    CAS  Google Scholar 

  70. S. Selb and Y. Gallot, Makromol. Chem. 182 (1981) 1175.

    Google Scholar 

  71. S. Selb and Y. Gallot, Makromol. Chem. 182 (1980) 809.

    Article  Google Scholar 

  72. S. Selb and Y. Gallot, in E. Goethals (ed) Polymeric Amines and Ammonium Salts, (Pergammon Press, New York, 1980), page 205.

    Google Scholar 

  73. U. P. Strauss and E. G. Jackson, J.Polymer Sci., 6 (1951) 619.

    Google Scholar 

  74. U. P. Strauss and E. G. Jackson, J.Polymer Sci., 7 (1951) 743.

    Google Scholar 

  75. U. P. Strauss et. al., J.Polymer Sci., 9 (1952) 509.

    Article  CAS  Google Scholar 

  76. U. P. Strauss et. al., J.Polymer Sci., 9 (1952) 295.

    Article  Google Scholar 

  77. A. Chernikhov, Chim e Ind. 52 (1970) 659.

    CAS  Google Scholar 

  78. J. C. Salamone, S. C. Israel, P. Tayler, and B. Snider, J.Polymer Sei. Symp. 45 (1974) 65.

    Article  CAS  Google Scholar 

  79. C. M. Paleos et. al., J.Polymer Sci. Chem., 18 (1980) 3463.

    Article  CAS  Google Scholar 

  80. W. G. Lloyd and T. E. Durocher, J.Appl. Polymer Sci., 7 (1963) 2025.

    Article  CAS  Google Scholar 

  81. C. M. Blow, Soc. Chem. Ind. J. 57 (1938) 116.

    Article  CAS  Google Scholar 

  82. C. M. Blow, Rubber Chem. Tech., 57 (1938) 545.

    Article  Google Scholar 

  83. R. H. Ottewill in D. R. Bassett and A. E. Hamielec (eds), Emulsion Polymers and Emulsion Polymerization, ACS #165, (ACS Washington, D.C., 1981), Chapter 2.

    Google Scholar 

  84. P. Conner and R. H. Ottewill, J.Coll. Interf. Sci. 37 (1969) 642.

    Article  Google Scholar 

  85. J. B. Kayes, J.Coll. Interf. Sci., 56 (1976) 426.

    Article  CAS  Google Scholar 

  86. N. M. Bikales (ed), Water Soluble Polymers, (Plenum Press, New York 1973), Part I Applications.

    Google Scholar 

  87. J. Gregory, Trans. Faraday Soc. 65 (1969) 2260.

    Article  CAS  Google Scholar 

  88. J. Gregory, J.Coll. Interf. Sci, 42 (1973) 448.

    Article  CAS  Google Scholar 

  89. J. Gregory, Brit. Polymer J., 6 (1974) 47.

    Article  CAS  Google Scholar 

  90. J. Gregory, J.Coll. Interf. Sci., 55 (1976) 35.

    Article  CAS  Google Scholar 

  91. E. T. Andreikovich, O. G. Kiseleva and R. E. Neiman, Colloid J.U.S.S.R., 38 (1976) 695.

    Google Scholar 

  92. D. Horn in E. J. Goethals (ed), Polymeric Amines and Ammonium Salts (Pergammon Press, New York 1980), page 333.

    Google Scholar 

  93. J. W. Vanderhoff, U.S. 3,205,187 (1965).

    Google Scholar 

  94. D. P. Sheetz, U.S. 3,637,565 (1972).

    Google Scholar 

  95. C. M. Samour and P. A. Mitchell, U.S. 3,795,648 (1974).

    Google Scholar 

  96. A. Homola and R. O. James, J.Coll. Interf. Sci., 59 (1977) 123.

    Article  CAS  Google Scholar 

  97. H. Kawaguchi, H. Hoshino, and Y. Ohtsuka, J.Appl. Polymer Sci., 26 (1981) 2015.

    Article  CAS  Google Scholar 

  98. J. F. Vitkuske and F. C. Rutledge, U.S. 3,072,588 (1963).

    Google Scholar 

  99. W. G. Lloyd and T. E. Durocher, J.Appl. Polymer Sci., 8 (1964) 953.

    Article  Google Scholar 

  100. G. A. Campbell, H. Cohen, and L. R. Hamilton, U.S. 3,958,995 (1976).

    Google Scholar 

  101. W. T. Hanson, Jr., Photo Sci. Eng., 20 (1978) 155.

    Google Scholar 

  102. J. W. Breitenbach, K. Kuchner, H. Fritze, and H. Tarnowiecki, Brit. Polymer J., 2 (1970) 13.

    Article  CAS  Google Scholar 

  103. W. J. LeFevre and D. P. Sheetz, U.S. 3,108,979 (1963).

    Google Scholar 

  104. E. L. Buhle, U.S. 3,102,867 (1963).

    Google Scholar 

  105. D. A. Kangas, U.S. 3,322,737 (1967).

    Google Scholar 

  106. H. J. Wright, J. F. Bremmer, N. Bhrimani and R. M. Fitch, U.S. 3,501,432 (1970).

    Google Scholar 

  107. D. S. Gibbs, R. A. Wessling, and E. H. Wagener, U.S. 3,637,432 (1972).

    Google Scholar 

  108. R. W. Upson, U.S. 2,599,299 (1952).

    Google Scholar 

  109. McCutchean’s Detergents and Emulsifiers, (North American Ed., (MC Publishing Co., New Jersey 1977).

    Google Scholar 

  110. E. Jungerman, Cationic Surfactants, (Marcel Dekker, New York 1970).

    Google Scholar 

  111. V. I. Eliseeva, S. S. Ivanchev, S. I. Kuchanov, and A. V. Lebedev, Emulsion Polymerization and Its Applications in Industry, (Consultants Bureau, New York 1981).

    Book  Google Scholar 

  112. A. E. Alexander, J.Oil. Col. Chem. Assoc., 45 (1962) 12.

    CAS  Google Scholar 

  113. D. H. Napper and A. E. Alexander, J.Polymer Sci., 61 (1962) 127.

    Article  CAS  Google Scholar 

  114. C. E. M. Morris, A. E. Alexander, and A. G. Parts, J.Polymer Sci. A-1 4 (1966) 985.

    Article  CAS  Google Scholar 

  115. A. E. Alexander and D. H. Napper, Chem. Ind., Nov. 18 (1967) 1936.

    Google Scholar 

  116. J. P. Friend and A. E. Alexander, J.Polymer Sci., A-1 6 (1968) 1833.

    Article  CAS  Google Scholar 

  117. C. E. M. Morris and A. G. Parts, Makrom. Chem., 165 (1973) 193.

    Article  CAS  Google Scholar 

  118. R. M. Fitch in Ref. 82, Chapter 1.

    Google Scholar 

  119. F. A. Bovey, et. al., Ref. 3, page 78.

    Google Scholar 

  120. Y. Ohtsuka, H. Kawaguchi, and S. Watanabe, Polymer 21 (1980) 1073.

    Article  CAS  Google Scholar 

  121. Y. Ohtsuka, H. Kawaguchi and S. Hayashi, Polymer 22 (1981) 658.

    Article  CAS  Google Scholar 

  122. R. Mertens, J. Coat. Tech., 53(677) (1981) 45.

    CAS  Google Scholar 

  123. J. W. Goodwin, et. al., Brit. Polymer J. 10 (1978) 173.

    Article  CAS  Google Scholar 

  124. T. J. Dougherty, J.Amer. Chem. Soc, 83 (1961) 4849.

    Article  CAS  Google Scholar 

  125. G. S. Hammond and R. C. Neuman, J.Amer. Chem. Soc, 85 (1963) 1501.

    Article  CAS  Google Scholar 

  126. W. G. Lloyd and W. L. Roelofs, U.S. 3,283,010 (1966).

    Google Scholar 

  127. J. E. Pritchard, M. H. Ophein and P. H. Moyer, Ind. Eng. Chem., 47 (1955) 863.

    Article  CAS  Google Scholar 

  128. W. T. Driscoll, U.S. 2,887,380 (1959).

    Google Scholar 

  129. F. A. Maeder, U.S. 3,287,305 (1966).

    Google Scholar 

  130. O. van Schickh, G. Winter, K. Herrle and J. G. Reich, U.S. 3,329,560 (1967).

    Google Scholar 

  131. D. Glabisch, U.S. 3,308,081 (1967).

    Google Scholar 

  132. M. E. Scheffler and F. L. Brown, U.S. 3,419,507 (1968).

    Google Scholar 

  133. V. I. Eliseva, L. V. Kozlov, S. S. Drezel’s, Dokl. Akad. Nauk. S.S.S.R. 186 (1969) 128 CA 71:39498.

    Google Scholar 

  134. D. P. Sheetz, U.S. 3,642,879 (1972).

    Google Scholar 

  135. D. S. Gibbs, R. A. Wessling and E. H. Wagener, U.S. 3,873,488 (1975).

    Google Scholar 

  136. D. G. Gibbs, et. al., U.S. 3,998,776 (1977).

    Google Scholar 

  137. B. Alince, M. Inoue and A. A. Robertson, J.Amer. Chem. Soc, 20 (1976) 2209.

    CAS  Google Scholar 

  138. N. Takashina, T. Nishmura, T. Takaoka, Jap. 77, 21409 (1977); C.A. 86: 17375.

    Google Scholar 

  139. H. Warson, Ref. 6, page 43.

    Google Scholar 

  140. L. S. Luskin in R. H. Yocum and E. B. Nyquist (eds), Functional Monomers, Vol. 2 (M. Dekker, New York, 1973), Chapter 3.

    Google Scholar 

  141. Polysciences 1982–83 Catalog, Warrington, PA.

    Google Scholar 

  142. C. F. Raley and R. J. Dolinski in R. H. Yocum and E. B. Nyquist (eds), Functional Monomers, Vol. 1 (M. Dekker, New York, 1973), Chapter 2.

    Google Scholar 

  143. L. R. Morris, U.S. 2,772,310 (1956).

    Google Scholar 

  144. D. P. Sheetz, U.S. 3,640,922 (1972).

    Google Scholar 

  145. C. M. Samour and M. C. Richards, U.S. 3,714,256 (1973).

    Google Scholar 

  146. C. M. Samour and M. C. Richards, U.S. 3,718,693 (1973).

    Google Scholar 

  147. C. M. Samour and M. C. Richards, U.S. 3,780,092 (1973).

    Google Scholar 

  148. C. M. Samour, U.S. 3,925,442 (1975).

    Google Scholar 

  149. C. M. Samour, U.S. 3,983,166 (1976).

    Google Scholar 

  150. C. M. Samour and M. C. Richards, U.S. 4,051,158 (1977).

    Google Scholar 

  151. H. S. Killain, U.S. 4,017,440 (1977).

    Google Scholar 

  152. C. M. Samour, U.S. 3,399,159 (1968).

    Google Scholar 

  153. D. S. Gibbs, R. D. Van Dell and R. A. Wessling, U.S. 3,965,032 (1976).

    Google Scholar 

  154. Jap. 81, 55,412 (1981); CA 95:116237.

    Google Scholar 

  155. Jap. 81, 141825 (1981); CA 96:143914.

    Google Scholar 

  156. S. K. Das, U.S. 4,304,703 (1981).

    Google Scholar 

  157. B. W. Greene, D. P. Sheetz and T. D. Filer, J.Coll. Interf. Sci., 32 (1970) 90.

    Article  CAS  Google Scholar 

  158. B. W. Greene and D. P. Sheetz, J.Coll. Interf. Sci., 32 (1970) 96.

    Article  CAS  Google Scholar 

  159. B. W. Greene and F. L. Saunders, J.Coll. Interf. Sci., 33 (1970) 393.

    Article  CAS  Google Scholar 

  160. C. H. Huang, S. Shimizer, and H. Adachi, Ger. 2,008,643 (1970); [also Brit. 1,299,012 (1972)].

    Google Scholar 

  161. C. H. Huang, et. al., U.S. 3,926,890 (1975).

    Google Scholar 

  162. R. A. Wessling, T. C. Klingler and V. E. Meyer, U.S. 4,002,586 (1970).

    Google Scholar 

  163. R. A. Wessling, L. D. Yats, and V. E. Meyer, Org. Coat. Plast. Chem., 42 (1980) 156.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1983 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Wessling, R.A. (1983). Cationic Polymer Colloids. In: Poehlein, G.W., Ottewill, R.H., Goodwin, J.W. (eds) Science and Technology of Polymer Colloids. NATO ASI Series, vol 2. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-4795-0_8

Download citation

  • DOI: https://doi.org/10.1007/978-94-017-4795-0_8

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-247-2833-6

  • Online ISBN: 978-94-017-4795-0

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics