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Transition Metal Sulphides pp 57–87Cite as

The Chemistry of the Dihydrogen Ligand in Transition Metal Compounds with Sulphur-Donor Ligands

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Part of the book series: NATO ASI Series ((ASHT,volume 60))

Abstract

Transition metal hydride species have been implicated in the mechanism of action of the industrial catalysts used for hydrodesulphurization (HDS) and the natural enzymes nitrogenase and iron- and iron-nickel hydrogenases. Common features of these mechanisms are that the hydride reactions occur at a metal centre coordinated by at least two sulphur ligands, that dihydrogen gas is formed or activated and that various H/D exchange processes involving D2(g) are catalysed by the metal centres. The topic of this paper is another possible common feature — the presence of the η2-dihydrogen ligand; that is H2 coordinated side-on to the metal with the H-H bond intact.

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  1. Department of Chemistry, University of Toronto, 80 St. George St., Toronto, Ont., M5S 3H6, Canada

    R. H. Morris

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  1. Laboratory for Technical Chemistry, Swiss Federal Institute of Technology (ETH), Zurich, Switzerland

    Thomas Weber  & Roel Prins  & 

  2. Schuit Institute of Catalysis, Eindhoven University of Technology, Eindhoven, The Netherlands

    Rutger A. van Santen

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Morris, R.H. (1998). The Chemistry of the Dihydrogen Ligand in Transition Metal Compounds with Sulphur-Donor Ligands. In: Weber, T., Prins, R., van Santen, R.A. (eds) Transition Metal Sulphides. NATO ASI Series, vol 60. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-3577-3_3

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  • DOI: https://doi.org/10.1007/978-94-017-3577-3_3

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-481-5100-4

  • Online ISBN: 978-94-017-3577-3

  • eBook Packages: Springer Book Archive

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