Abstract
Interference enhanced Raman spectra of Al adsorbed on Ge clusters reveal an Al induced vibrational band. The resulting effective force constant implies a significantly weaker interaction than that of the similar reduced mass Si-Ge system. Consistent XPS core line shifts of Al and Ge (0.6eV) suggest the formation of a weak covalent bond between the metal adsorbate and semiconductor clusters.
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© 1992 Springer Science+Business Media Dordrecht
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Bacsa, W.S., Lannin, J.S. (1992). Vibrational States of Al Adsorbed on Ge Clusters. In: Jena, P., Khanna, S.N., Rao, B.K. (eds) Physics and Chemistry of Finite Systems: From Clusters to Crystals. NATO ASI Series, vol 374. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-2645-0_41
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DOI: https://doi.org/10.1007/978-94-017-2645-0_41
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