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Photosensitization by [Metallo]Porphyrins. Formation and Photophysical Properties of Porphyrin Assemblies

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Book cover Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds

Part of the book series: Catalysis by Metal Complexes ((CMCO,volume 14))

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Abstract

Stemming from their multifarious roles in natural processes, [metallo]porphyrins have found numerous applications in artificial systems aimed at mimicking important biological functions. Many different metalloporphyrins have been designed in order to accomplish specific tasks and, in particular, novel approaches have been used to assemble several porphyrins into a cluster. This ability to concentrate metalloporphyrins into a supramolecular assembly is of special relevance in that it takes us one step closer to constructing practical devices. This chapter will attempt to review the progress made in the assembly of porphyrin derivatives into supramolecular systems and will describe the aptitude of such assemblies to photosensitize particular reactions. The work described here is primarily concerned with trying to reproduce, under controlled conditions, some of the important features of photosynthetic reaction center complexes.

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  1. Center for Fast Kinetics Research, The University of Texas at Austin, Austin, Texas, 78712, USA

    A. Harriman

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  1. Institute of Physical Chemistry, Swiss Federal Institute of Technology, Lausanne, Switzerland

    K. Kalyanasundaram  & M. Grätzel  & 

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Harriman, A. (1993). Photosensitization by [Metallo]Porphyrins. Formation and Photophysical Properties of Porphyrin Assemblies. In: Kalyanasundaram, K., Grätzel, M. (eds) Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds. Catalysis by Metal Complexes, vol 14. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-2626-9_9

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