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Electron Donor-Acceptor Interactions and Photo-Induced Electron Transfer of Organometallic Compounds

  • Chapter
Book cover Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds

Part of the book series: Catalysis by Metal Complexes ((CMCO,volume 14))

Abstract

An electron-transfer process is represented in its simplest form as

$$D\, + \,\,A\, \to \,D{ \cdot ^{ + \,\,}} + \,A{ \cdot ^ - }$$
(1)

in which an electron is transferred from the HOMO of the electron donor (D) to the LUMO of the electron acceptor (A) in one single (overall) process. [For simplicity, the electron donor and acceptor are written here as uncharged and diamagnetic, which is not always the case.] The formulation described in equation (1) does not, however, take into account the interaction between A and D over the diminished intermolecular distance in which the electron is transferred. The corresponding interactions between the products (A·− and D·+) must also be considered in a more comprehensive account of the electron-transfer process. Accordingly, Scheme I depicts the interactions between donor and acceptor in terms of the precursor (electron donor-acceptor or EDA)

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Bockman, T.M., Kochi, J.K. (1993). Electron Donor-Acceptor Interactions and Photo-Induced Electron Transfer of Organometallic Compounds. In: Kalyanasundaram, K., Grätzel, M. (eds) Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds. Catalysis by Metal Complexes, vol 14. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-2626-9_14

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