Abstract
A reconnaissance of the influence of hydrodynamics and supersaturation ratio on agglomeration of aluminum hydroxide was made. In this experimental study two important observations were made: the agglomeration rate constant is directly proportional to the growth rate, and can be related to the power input in the reactor system. These observations resulted in an empirical relation for the agglomeration rate constant as a function of the power input and the growth rate that has been validated against batch agglomeration experiments with three different type of impellers (Rushton, pitched blade, and flat blade) and with initial supersaturation ratios in the range [1.3, 1.8].
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Smoluchowski, M. von, Versuch einer mathematischen theorie der Koagulationskinetik Koloider Losungen, Z Phys. Chem., 1917, 92, 156.
Saffinan, P.G., and Turner, J.S., On the collision of drops in turbulent clouds, J.Fluid. Mech., 1956, 1, 16–30.
Mumtaz H.S., M.J. Hounslow, N.A. Seaton, and W.R. Paterson, Orthokinetic aggregation during precipitation: A computational model for calcium oxalate monohydrate, Trans IchemE, 1997, 75, 152–159.
Misra C., Solubility of aluminum Trihydroxide (hydrargillite) in sodium hydroxide solutions, Chem. Ind., 1970, 20, 619.
Hounslow M.J., R.L. Ryall, and V.R. Marshall, A discretized population balance for nucleation, growth, and agglomeration, AIChE Journal, 1988, 34, 1821–1832.
Veesler S., and R. Boistelle, About supersaturation and growth rates of hydrargillite Al(OH)3 in aluminum solutions, J. of Crystal Growth, 1993, 130, 411–415.
Veesler S., and R. Boistelle, Growth kinetics of hydrargillite Al(OH)3 from caustic soda solutions, J. Of Crystal Growth, 1994, 142, 177–183.
Bramley A.S., M.J. Hounslow, and R.L. Ryall, Agglomeration during precipitation from solution: A method for extracting rates from experimental data, J. Colloid and Interface Sci., 1996, 183, 155–165.
Bramley A.S., M.J. Hounslow, and R.L. Ryall, Agglomeration during precipitation from solution. Kinetics for calcium oxalate monohydrate, Chem. Eng. Sci., 1997, 52, 747–757.
Wojcik J.A., and A.G. Jones, Experimental investigation into dynamics and stability of continuous MSMPR agglomerative precipitation of CaCO3 crystals, Trans IchemE, 1997, 75, 113–118.
Kusters K.A., The influence of turbulence on aggregation of small particles in agitated vessels, Ph.D. Dissertation, Technical University of Eindhoven, The Netherlands, 1991.
Tatterson, G.B., Fluid mixing and gas dispersion in agitated tanks, MacGraw–Hill Inc., New York, ISBN 0–07–062922–1, 1991.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2000 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Van Leeuwen, M.L.J., Bruinsma, D.S.L., Van Rosmalen, G.M., Hounslow, M.J., Seckler, M.M. (2000). An Experimental Study to the Effects of Super-Saturation Ratio, Impeller Design and Impeller Speed on Agglomeration of Aluminum Trihydroxide. In: Gupta, B.S., Ibrahim, S. (eds) Mixing and Crystallization. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-2290-2_14
Download citation
DOI: https://doi.org/10.1007/978-94-017-2290-2_14
Publisher Name: Springer, Dordrecht
Print ISBN: 978-90-481-5410-4
Online ISBN: 978-94-017-2290-2
eBook Packages: Springer Book Archive