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Oxygenation Reactions under Two-Phase Conditions

  • Chapter
Metalloporphyrins Catalyzed Oxidations

Part of the book series: Catalysis by Metal Complexes ((CMCO,volume 17))

Abstract

In living organisms the introduction of an oxygen atom into a substrate (oxygenation reaction) is performed by enzymes of the cytochrome P-450 family. Such enzymes feature a Fe(III)-protoporphyrin IX at the active site where, after reduction, molecular oxygen is coordinated and activated through a very complicated mechanism, “reductive oxygen activation” (Scheme 1). High valent Fe-oxo species formation is favoured by the electron donation from a thiolate of a cysteine residue of the protein chain, which occupies an axial coordination site of the metal.1

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  1. C.N.R. Center and Department of Industrial and Organic Chemistry, University of Milano, Via C. Golgi, 19, I-20133, Milano, Italy

    Fernando Montanari, Stefano Banfi, Gianluca Pozzi & Silvio Quici

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  1. University of Milan, Italy

    Fernando Montanari

  2. University of Pavia, Italy

    Luigi Casella

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Montanari, F., Banfi, S., Pozzi, G., Quici, S. (1994). Oxygenation Reactions under Two-Phase Conditions. In: Montanari, F., Casella, L. (eds) Metalloporphyrins Catalyzed Oxidations. Catalysis by Metal Complexes, vol 17. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-2247-6_5

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