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Biological Oxidations: Stereochemical Aspects

  • Chapter
Metalloporphyrins Catalyzed Oxidations

Part of the book series: Catalysis by Metal Complexes ((CMCO,volume 17))

Abstract

Correlation of the structure of enzymes with their catalytic activity is one of the most fundamental challenges of structural biology. Ultimately, the various features that characterize the action of enzymes may be understood at a molecular level. These include physical factors, i.e. how the substrates are bound, and chemical factors, i.e. the chemical mechanism of the enzymatic reaction. Our concern here is mostly with the first of these points, since all current evidence shows that binding of the substrates to the active site of heme proteins involved in biological oxidations is the main source of chemoselectivity associated with the enzyme catalyzed reactions, including stereoselectivity and enantioselectivity.

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Authors and Affiliations

  1. Department of General Chemistry, University of Pavia, Via Taramelli 12, 27100, Pavia, Italy

    L. Casella

  2. Department of Organic and Industrial Chemistry, University of Milano, Via Golgi 19, 20133, Milano, Italy

    S. Colonna

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  1. L. Casella
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  2. S. Colonna
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Editors and Affiliations

  1. University of Milan, Italy

    Fernando Montanari

  2. University of Pavia, Italy

    Luigi Casella

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Casella, L., Colonna, S. (1994). Biological Oxidations: Stereochemical Aspects. In: Montanari, F., Casella, L. (eds) Metalloporphyrins Catalyzed Oxidations. Catalysis by Metal Complexes, vol 17. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-2247-6_10

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  • DOI: https://doi.org/10.1007/978-94-017-2247-6_10

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